Issue 17, 2019
From the journal:

Dalton Transactions

Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes†

Subhi A. Al-Jibori,*a   Samer Hussein Ali,a   Ahmed S. Al-Janabi, ORCID logo b   Christoph Wagnerc  and  Graeme Hogarth ORCID logo *d  

* Corresponding authors

a Department of Chemistry, College of Science, University of Tikrit, Tikrit, Iraq
E-mail: subhi_aljibori@yahoo.com

b Department of Biochemistry, College of Veterinary Medicine, University of Tikrit, Tikrit, Iraq

c Institut für Chemie, Martin-Luther-Universität, Halle-Wittenberg, Kurt-Mothes-Str. 2, D-06120 Halle, Germany

d Department of Chemistry, King's College London, Britannia House, 7 Trinity Street, London SE1 IDB, UK
E-mail: graeme.hogarth@kcl.ac.uk

Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni2(μ-bit)4·2H2O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(II) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

Graphical abstract: Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9DT00953A
Article type
Communication
Submitted
04 mar 2019
Accepted
28 mar 2019
First published
28 mar 2019

Dalton Trans., 2019,48, 5520-5522

Permissions

Request permissions

Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(II) centre: a convenient synthesis of Ni(II)-thiolate complexes

S. A. Al-Jibori, S. H. Ali, A. S. Al-Janabi, C. Wagner and G. Hogarth, Dalton Trans., 2019, 48, 5520 DOI: 10.1039/C9DT00953A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements