Issue 46, 2016

Can chiral P(iii) coordinate Eu(iii)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(iii)(hfa)3 in chloroform and acetone

Abstract

The coordination of Eu(III) (from Eu(III)(hfa)3) by chiral P(III) (from BINAP) led to circularly polarised luminescence in dilute solutions on the order of |gem| ≈ 10−2 at 5D07F1 and |gem| ≈ 10−3 at 5D07F2 transitions regardless of the coordinating ability of the solvent (i.e., in non-coordinating ethanol-free chloroform and coordinating acetone).

Graphical abstract: Can chiral P(iii) coordinate Eu(iii)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(iii)(hfa)3 in chloroform and acetone

Supplementary files

Article information

Article type
Paper
Submitted
05 mar 2016
Accepted
04 abr 2016
First published
05 abr 2016

RSC Adv., 2016,6, 40219-40224

Can chiral P(III) coordinate Eu(III)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(III)(hfa)3 in chloroform and acetone

Y. Kono, K. Nakabayashi, S. Kitamura, M. Shizuma, M. Fujiki and Y. Imai, RSC Adv., 2016, 6, 40219 DOI: 10.1039/C6RA05856F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements