Issue 52, 2013

Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions

Abstract

We describe here the use of disulfide exchange reactions to generate distinct supramolecular topologies within a dynamic combinatorial library (DCL) derived from tri- and mono-functionalised thiol components in water. This approach allows for the effective expansion of structural diversity within a DCL, and also provides a sensitive probe for weak supramolecular interactions.

Graphical abstract: Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions

Supplementary files

Article information

Article type
Communication
Submitted
12 fev 2013
Accepted
05 mar 2013
First published
14 mar 2013

Chem. Commun., 2013,49, 5820-5822

Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions

A. R. Stefankiewicz and J. K. M. Sanders, Chem. Commun., 2013, 49, 5820 DOI: 10.1039/C3CC41158C

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