Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Luca Pignataro; Benita Lynikaite; Raffaele Colombo; Stefano Carboni; Martin Krupička; Umberto Piarulli; Cesare Gennari

doi:10.1039/B908167D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Combination of a binaphthol-derived phosphite and a C₁-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions†‡

Luca Pignataro,^ab Benita Lynikaite,^a Raffaele Colombo,^a Stefano Carboni,^b Martin Krupička,^c Umberto Piarulli*^b and Cesare Gennari*^a

Author affiliations

* Corresponding authors

^a Dipartimento di Chimica Organica e Industriale, Centro Interdipartimentale C.I.S.I., Università degli Studi di Milano, Via G. Venezian 21, 20133 Milano, Italy
E-mail: cesare.gennari@unimi.it
Fax: +39 02 5031 4072
Tel: +39 02 5031 4091

^b Dipartimento di Scienze Chimiche e Ambientali, Università dell’Insubria, via Valleggio 11, 22100 Como, Italy
E-mail: umberto.piarulli@uninsubria.it
Fax: +39 031 238 6444
Tel: +39 031 238 6449

^c Laboratory of Computational Chemistry, Institute of Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, 84538 Bratislava, Slovakia

Abstract

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a σ-donor and a π-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.

This article is part of the themed collection: Selective Catalysis for Organic Synthesis

Download options Please wait...

Supplementary files

Experimental procedures, characterisation data for all newcompounds, complexation experiments (along with copies of ³¹P- and ¹H-NMR spectra), full screening of the ligands in theRh- and Pd-catalysed reactions, and details of the DFTcalculations PDF (784K)

Article information

DOI: https://doi.org/10.1039/B908167D
Article type: Communication
Submitted: 23 abr 2009
Accepted: 11 mai 2009
First published: 21 mai 2009

Download Citation

Chem. Commun., 2009, 3539-3541

Permissions

Request permissions

Combination of a binaphthol-derived phosphite and a C₁-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

L. Pignataro, B. Lynikaite, R. Colombo, S. Carboni, M. Krupička, U. Piarulli and C. Gennari, Chem. Commun., 2009, 3539 DOI: 10.1039/B908167D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications