Racemic dihydroxylation of alkenes is efficiently accomplished with catalytic osmium (added as OsCl3), stoichiometric K3Fe(CN)6 and quinuclidine under conditions similar to those of the Sharpless asymmetric hydroxylation.
J. Eames, H. J. Mitchell, A. Nelson, P. O’Brien, S. Warren and P. Wyatt, J. Chem. Soc., Perkin Trans. 1, 1999, 1095 DOI: 10.1039/A900277D
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