Issue 30, 2022
From the journal:

Organic & Biomolecular Chemistry

Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy†

Boseok Honga  and  Anna Lee ORCID logo *b  

* Corresponding authors

a Department of Chemistry, Myongji University, Yongin 17058, Republic of Korea

b Department of Chemistry, Jeonbuk National University, Jeonju 54896, Republic of Korea
E-mail: annalee@jbnu.ac.kr

Abstract

A novel method for the oxidative C–S bond cleavage of benzyl thiols was developed. In situ-activated silver species enabled the controlled bond cleavage of benzyl thiols to afford aldehydes and ketones in the absence of a photocatalyst. The desired carbonyl compounds were obtained under mild reaction conditions via two different reaction pathways.

Graphical abstract: Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

  • This article is part of the themed collection: New Talent
About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2OB00089J
Article type
Communication
Submitted
14 jan 2022
Accepted
15 fev 2022
First published
15 fev 2022

Org. Biomol. Chem., 2022,20, 5938-5942

Permissions

Request permissions

Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

B. Hong and A. Lee, Org. Biomol. Chem., 2022, 20, 5938 DOI: 10.1039/D2OB00089J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements