Issue 44, 2022

Meta-stability through intermolecular interactions protecting the identity of atomic metal clusters: ab initio evidences in (Cu5–Cu5)n (n < 3) cases

Abstract

Recent developments in new synthesis techniques have allowed the production of precise monodisperse metal clusters composed of a few atoms. These atomic metal clusters (AMCs) often feature a molecule-like electronic structure, which makes their physical and chemical properties particularly interesting in nanotechnology. Regarding potential applications, there is a major concern about the sintering of AMCs in nanoparticles due to the loss of their special properties. In this work, multireference ab initio theory is applied to demonstrate the formation of coupled AMC–AMC clusters in which the AMC partners maintain their ‘identity’ to a large extent in terms of their initial structures and atomic Mulliken charges, and their further oligomerization.

Graphical abstract: Meta-stability through intermolecular interactions protecting the identity of atomic metal clusters: ab initio evidences in (Cu5–Cu5)n (n < 3) cases

Supplementary files

Article information

Article type
Communication
Submitted
01 ago 2022
Accepted
20 out 2022
First published
21 out 2022
This article is Open Access
Creative Commons BY-NC license

Phys. Chem. Chem. Phys., 2022,24, 26992-26997

Meta-stability through intermolecular interactions protecting the identity of atomic metal clusters: ab initio evidences in (Cu5–Cu5)n (n < 3) cases

B. Fernández and M. P. de Lara-Castells, Phys. Chem. Chem. Phys., 2022, 24, 26992 DOI: 10.1039/D2CP03537E

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