Issue 41, 2019
From the journal:

Dalton Transactions

New examples of triangular terbium(iii) and holmium(iii) and hexagonal dysprosium(iii) single molecule toroics†‡

Stuart K. Langley,*a   Kuduva R. Vignesh, ORCID logo b   Tulika Gupta,b   Christopher J. Gartshore,c   Gopalan Rajaraman, ORCID logo *b   Craig M. Forsyth ORCID logo c  and  Keith S. Murray ORCID logo *c  

* Corresponding authors

a School of science and the environment, Division of Chemistry, Manchester Metropolitan University, Manchester, UK
E-mail: s.langley@mmu.ac.uk

b Department of Chemistry, Indian Institute of Technology Bombay, Mumbai-400076, India
E-mail: rajaraman@chem.iitb.ac.in

c School of Chemistry, Monash University, Clayton, Victoria 3800, Australia
E-mail: keith.murray@monash.edu

Abstract

The structural, magnetic and theoretical aspects are described for three triangular lanthanide complexes, [TbIII3(OH)(teaH2)3(paa)3]Cl2 (1), [DyIII3(OH)(teaH2)3(paa)3]Cl2 (2) and [HoIII3(OH)(teaH2)3(paa)3]Cl2 (3), and a hexanuclear wheel of formula [DyIII6(pdeaH)6(NO3)6] (4) [teaH3 = triethanolamine, paaH = N-(2-pyridyl)-acetoacetamide and pdeaH3 = 3-[bis(2-hydroxyethyl)amino]propan-1-ol]. Each complex displays single molecule toroidal behaviour as rationalised using high-level ab initio calculations. Complexes 2 and 3 are the first examples of mixed moment single molecule toroidal complexes featuring non-Kramers ions.

Graphical abstract: New examples of triangular terbium(iii) and holmium(iii) and hexagonal dysprosium(iii) single molecule toroics

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Article information

DOI
https://doi.org/10.1039/C9DT02419K
Article type
Paper
Submitted
07 jun 2019
Accepted
27 ago 2019
First published
27 ago 2019

Dalton Trans., 2019,48, 15657-15667

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New examples of triangular terbium(III) and holmium(III) and hexagonal dysprosium(III) single molecule toroics

S. K. Langley, K. R. Vignesh, T. Gupta, C. J. Gartshore, G. Rajaraman, C. M. Forsyth and K. S. Murray, Dalton Trans., 2019, 48, 15657 DOI: 10.1039/C9DT02419K

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