Issue 6, 2017
From the journal:

Materials Chemistry Frontiers

Towards hydroxamic acid linked zirconium metal–organic frameworks†

Carla F. Pereira,abc   Ashlee J. Howarth,c   Nicolaas A. Vermeulen,c   Filipe A. Almeida Paz,b   João P. C. Tomé,ad   Joseph T. Hupp*c  and  Omar K. Farha*ce  

* Corresponding authors

a Department of Chemistry & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal

b Department of Chemistry & CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

c Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail: j-hupp@northwestern.edu, o-farha@northwestern.edu

d CQE, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

e Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

Abstract

Solvent-assisted linker exchange (SALE) is performed on the Zr-based metal–organic framework (MOF), UiO-66, to exchange benzene-1,4-dicarboxylate with benzene-1,4-dihydroxamate linkers. Characterization of the material before and after SALE is performed using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), nitrogen adsorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The stability of the parent and daughter material is evaluated at pH 1 and 12 and the structural integrity evaluated by PXRD, mass balance and porosity measurements.

Graphical abstract: Towards hydroxamic acid linked zirconium metal–organic frameworks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6QM00364H
Article type
Research Article
Submitted
15 dez 2016
Accepted
23 jan 2017
First published
30 jan 2017

Mater. Chem. Front., 2017,1, 1194-1199

Permissions

Request permissions

Towards hydroxamic acid linked zirconium metal–organic frameworks

C. F. Pereira, A. J. Howarth, N. A. Vermeulen, F. A. Almeida Paz, J. P. C. Tomé, J. T. Hupp and O. K. Farha, Mater. Chem. Front., 2017, 1, 1194 DOI: 10.1039/C6QM00364H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements