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An nanoporous nickel oxyhydroxide-borate (NiBi) thin film, consisting of an aggregate of spherical particles self-assembled from NiBi nanopetals, has been synthesized using a simple and cost-effective pulse electrodeposition method without the addition of any surfactant, and demonstrated as an efficient, selective, and robust electrocatalyst in the electrochemical and photoelectrochemical reforming of methanol into formate.

Graphical abstract: A pulse electrosynthesized nanoporous nickel oxyhydroxide-borate thin film in electro- and photoelectro-reforming of methanol for selective production of formate

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