Issue 12, 2017

From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

Graphical abstract: From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Supplementary files

Article information

Article type
Communication
Submitted
07 nov 2016
Accepted
20 jan 2017
First published
20 jan 2017

Chem. Commun., 2017,53, 2028-2031

From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

M. Erkartal, U. Erkilic, B. Tam, H. Usta, O. Yazaydin, J. T. Hupp, O. K. Farha and U. Sen, Chem. Commun., 2017, 53, 2028 DOI: 10.1039/C6CC08746A

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