Issue 24, 2016

Electrochemical and chemical routes to hydride loss from an iridium dihydride

Abstract

With a view towards replacing sacrificial hydrogen acceptors in alkane dehydrogenation catalysis, electrochemical methods for oxidative activation of a pincer-ligated iridium hydride intermediate were explored. A 1H+/2eāˆ’ oxidation process was observed in THF solvent, with net hydride loss leading to a reactive cationic intermediate that can be trapped by chloride. Analogous reactivity was observed with the concerted hydride transfer reagent Ph3C+, connecting chemical and electrochemical hydride loss pathways.

Graphical abstract: Electrochemical and chemical routes to hydride loss from an iridium dihydride

Supplementary files

Article information

Article type
Communication
Submitted
05 fev 2016
Accepted
04 mar 2016
First published
16 mar 2016
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 9766-9769

Electrochemical and chemical routes to hydride loss from an iridium dihydride

A. G. Walden, A. Kumar, N. Lease, A. S. Goldman and A. J. M. Miller, Dalton Trans., 2016, 45, 9766 DOI: 10.1039/C6DT00522E

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