Cyclodextrin-adamantane conjugates, self-inclusion and aggregation versus supramolecular polymer formation

Diem Ngan Tran; Dmitri Colesnic; Ségolène Adam de Beaumais; Gaëlle Pembouong; François Portier; Álvaro Antelo Queijo; José Vázquez Tato; Yongmin Zhang; Mickaël Ménand; Laurent Bouteiller; Matthieu Sollogoub

doi:10.1039/C4QO00104D

Cyclodextrin-adamantane conjugates, self-inclusion and aggregation versus supramolecular polymer formation†‡

Diem Ngan Tran,^ab Dmitri Colesnic,^ab Ségolène Adam de Beaumais,^ab Gaëlle Pembouong,^ab François Portier,^ab Álvaro Antelo Queijo,^c José Vázquez Tato,^c Yongmin Zhang,^ab Mickaël Ménand,^ab Laurent Bouteiller*^ab and Matthieu Sollogoub*^ab

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^a Sorbonne Universités, UPMC Univ Paris 06, Institut Universitaire de France, UMR CNRS 8232, IPCM, F-75005 Paris, France
E-mail: laurent.bouteiller@upmc.fr, matthieu.sollogoub@upmc.fr

^b CNRS, UMR 8232, Institut Parisien de Chimie Moléculaire (IPCM), F-75005 Paris, France

^c Universidad de Santiago de Compostela, Campus de Lugo, Facultad de Ciencias, Avda Alfonso X el Sabio s/n, 27002 Lugo, Spain

Abstract

Cyclodextrin-adamantane conjugates have been prepared and their ability to form supramolecular polymers was tested. It appears that they are either insoluble when the link is too rigid or they form self-included derivatives inhibiting the formation of the polymer.

This article is part of the themed collection: In Celebration of Max Malacria’s 65th Birthday

Organic Chemistry Frontiers

Cyclodextrin-adamantane conjugates, self-inclusion and aggregation versus supramolecular polymer formation†‡

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