Issue 5, 2013

Where is Cu(0) generated by disproportionation during SET-LRP?

Abstract

The nucleation and growth of nascent Cu(0) nanoparticles formed by disproportionation during SET-LRP on the surface of Cu(0) wire was demonstrated by Scanning Electron Microscopy analysis of the surface of Cu(0) wire before and after disproportionation and polymerization. The dynamics of nascent Cu(0) formation, activation of dormant species and their nucleation and growth on the existing Cu(0) surface determines the Cu(0) consumption during polymerization.

Graphical abstract: Where is Cu(0) generated by disproportionation during SET-LRP?

Supplementary files

Article information

Article type
Communication
Submitted
20 dez 2012
Accepted
10 jan 2013
First published
11 jan 2013

Polym. Chem., 2013,4, 1328-1332

Where is Cu(0) generated by disproportionation during SET-LRP?

N. H. Nguyen, H. Sun, M. E. Levere, S. Fleischmann and V. Percec, Polym. Chem., 2013, 4, 1328 DOI: 10.1039/C3PY21133A

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