Issue 67, 2012

Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

Abstract

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

Graphical abstract: Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

Supplementary files

Article information

Article type
Communication
Submitted
13 jun 2012
Accepted
04 jul 2012
First published
06 jul 2012

Chem. Commun., 2012,48, 8407-8409

Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

V. Bon, V. Senkovskyy, I. Senkovska and S. Kaskel, Chem. Commun., 2012, 48, 8407 DOI: 10.1039/C2CC34246D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements