Issue 24, 2009

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Abstract

Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a σ-donor and a π-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.

Graphical abstract: Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Supplementary files

Article information

Article type
Communication
Submitted
23 abr 2009
Accepted
11 mai 2009
First published
21 mai 2009

Chem. Commun., 2009, 3539-3541

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

L. Pignataro, B. Lynikaite, R. Colombo, S. Carboni, M. Krupička, U. Piarulli and C. Gennari, Chem. Commun., 2009, 3539 DOI: 10.1039/B908167D

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