Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations

Masaki Fujita; Yohei Haketa; Shu Seki; Hiromitsu Maeda

doi:10.1039/D4CC00806E

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Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations†

Masaki Fujita,^a Yohei Haketa,

^a Shu Seki

^b and Hiromitsu Maeda

*^a

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* Corresponding authors

^a Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525–8577, Japan
E-mail: maedahir@ph.ritsumei.ac.jp

^b Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615–8510, Japan

Abstract

Metal complexation and peripheral modifications of thiaporphyrins have been investigated for preparing polarized π-electronic cations with anion-dependent ion-pairing assembling modes, including charge-segregated structures exhibiting electric conductive properties.

This article is part of the themed collection: ChemComm 60th Anniversary Board Member Collection

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DOI: https://doi.org/10.1039/D4CC00806E
Article type: Communication
Submitted: 19 fev 2024
Accepted: 11 mar 2024
First published: 12 mar 2024

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Chem. Commun., 2024,60, 4190-4193

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Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations

M. Fujita, Y. Haketa, S. Seki and H. Maeda, Chem. Commun., 2024, 60, 4190 DOI: 10.1039/D4CC00806E

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Chemical Communications

Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations†

Abstract

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Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations

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