Issue 39, 2021

Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

Abstract

A new twisted donor–acceptor–donor (D–A–D) multi-photofunctional organic molecule comprising phenoselenazine as the electron donor (Ds) and dibenzo[a,j]phenazine (DBPHZ) as the electron acceptor (A) has been developed. The developed selenium-incorporated D–A–D compound features multi-color polymorphism, distinct mechanochromic luminescence, chemically-stimulated luminochromism, thermally-activated delayed fluorescence, and room-temperature phosphorescence. The internal heavy atom effect on the photophysical properties of the D–A–D system has been investigated through a comparison with the physicochemical properties of a previously developed sulfur analogue and a tellurium analogue.

Graphical abstract: Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

Supplementary files

Article information

Article type
Paper
Submitted
08 jun 2021
Accepted
20 ago 2021
First published
24 ago 2021

J. Mater. Chem. C, 2021,9, 13942-13953

Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

S. Goto, Y. Nitta, N. O. Decarli, L. E. de Sousa, P. Stachelek, N. Tohnai, S. Minakata, P. de Silva, P. Data and Y. Takeda, J. Mater. Chem. C, 2021, 9, 13942 DOI: 10.1039/D1TC02635F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements