Issue 16, 2016

Adjusting the thermoelectric properties of copper(i) oxide–graphite–polymer pastes and the applications of such flexible composites

Abstract

We present a facile alternative to other well known strategies for synthesizing flexible thermoelectric materials. Instead of printing thin active layers on flexible substrates or doping conductive polymers, we produce thermoelectric pastes, using a mixture of graphite, copper(I) oxide and polychlorotrifluoroethene. The Seebeck coefficient of the investigated pastes varies between 10 and 600 μV K−1, while the electrical conductivity spans over an even wider range of 10−4 to 102 S m−1. Here, the influence of phenomena such as percolation on the electrical transport is revealed. The resulting power factor reaches 5.69 × 10−4 ± 0.70 × 10−4 μW m−1 K−2 for the graphite–polymer paste, with an unexpected minimum at a graphite molar fraction of approximately 0.4. The values are comparable to those of the powder mixtures, which are slightly higher, but less precisely tunable. Such compounds are further evaluated for practical applications. The graphite–polymer paste is used to exemplify, how a flexible thermoelectric sensor can be easily manufactured, step by step. Our results represent a proof of principle, that thermoelectric pastes are viable alternatives to current solutions. A further expansion of the scope for the composites can be achieved by using high performance thermoelectric materials and conductive polymers.

Graphical abstract: Adjusting the thermoelectric properties of copper(i) oxide–graphite–polymer pastes and the applications of such flexible composites

Supplementary files

Article information

Article type
Paper
Submitted
08 nov 2015
Accepted
15 fev 2016
First published
16 fev 2016

Phys. Chem. Chem. Phys., 2016,18, 10700-10707

Adjusting the thermoelectric properties of copper(I) oxide–graphite–polymer pastes and the applications of such flexible composites

V. Andrei, K. Bethke and K. Rademann, Phys. Chem. Chem. Phys., 2016, 18, 10700 DOI: 10.1039/C5CP06828B

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