The path towards type V deep eutectic solvents: inductive effects and steric hindrance in the system tert-butanol + perfluoro tert-butanol

Inês C. M. Vaz, Ana I. M. C. Lobo Ferreira, Gonçalo M. C. Silva, Pedro Morgado, Dinis O. Abranches, Margarida Bastos, Luís M. N. B. F. Santos, Eduardo J. M. Filipe and João A. P. Coutinho

Phys. Chem. Chem. Phys., 2023, 25, 11227
DOI: 10.1039/D3CP00701D

Mechanism of NO reduction by NH3over CuMnOxcatalysts and the influence mechanism of CO

Chengbo Xuan, Shiwang Han, Luyuan Wang, Xingyu Zhang, Rongfeng Sun, Xingxing Cheng, Zhiqiang Wang, Chunyuan Ma, Tiantian Zhao and Xukai Hou

Catal. Sci. Technol., 2023, 13, 3106
DOI: 10.1039/D3CY00403A

Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

Adriaan van den Bruinhorst, Chiara Corsini, Guillaume Depraetère, Nithavong Cam, Agílio Pádua and Margarida Costa Gomes

Faraday Discuss., 2024, 253, 273
DOI: 10.1039/D4FD00048J

Good vibrations: understanding deep eutectic solvents through the lens of vibrational spectroscopy

Catarina F. Araújo, Dinis O. Abranches, João A. P. Coutinho, Pedro D. Vaz, Paulo Ribeiro-Claro and Mariela M. Nolasco

Applied Spectroscopy Reviews, 2025, 60, 137
DOI: 10.1080/05704928.2024.2390962

Deciphering hydrogen bonds and liquid structures in the N-methylurea/choline chloride deep eutectic solvent through ab initio molecular dynamics simulations and Raman spectroscopy

Shih-Huang Pan, Hsu-Ting Yeh, Eugene C. Lin, Jyh-Chiang Jiang and Tzyy-Schiuan Yang

Journal of Molecular Liquids, 2025, 436, 128229
DOI: 10.1016/j.molliq.2025.128229

Affinity of deep eutectic solvents with aromatic molecules and aromatic nanostructures in chemical transformations

Salvatore V. Giofrè, Consuelo Celesti, Giuseppe Mistretta and Matteo Tiecco

Current Opinion in Green and Sustainable Chemistry, 2023, 40, 100779
DOI: 10.1016/j.cogsc.2023.100779

Solubility enhancement of metronidazole using natural deep eutectic solvents: Physicochemical and thermodynamic studies

Adrian Szewczyk, Dorota Warmińska, Jakub Ruszkowski, Michał Szymankiewicz and Magdalena Prokopowicz

Journal of Molecular Liquids, 2024, 410, 125604
DOI: 10.1016/j.molliq.2024.125604

The polylysine-based ionic liquid non-aqueous phase change system for CO2 capture performance and mechanism

Bilian Jiang, Shanshan Dai, Wei Fan, Jialong Yang, Ruiyao Wang and Yuanqiang Zhu

Journal of Environmental Chemical Engineering, 2025, 13, 118947
DOI: 10.1016/j.jece.2025.118947

Room-Temperature Decomposition of the Ethaline Deep Eutectic Solvent

Julia H. Yang, Amanda Whai Shin Ooi, Zachary A. H. Goodwin, Yu Xie, Jingxuan Ding, Stefano Falletta, Ah-Hyung Alissa Park and Boris Kozinsky

J. Phys. Chem. Lett., 2025, 16, 3039
DOI: 10.1021/acs.jpclett.4c03645

Liquid structure of a water-based, hydrophobic and natural deep eutectic solvent: The case of thymol-water. A Molecular Dynamics study

Alessandro Triolo, Fabrizio Lo Celso and Olga Russina

Journal of Molecular Liquids, 2023, 372, 121151
DOI: 10.1016/j.molliq.2022.121151

Thermodynamic Approach for Estimating the Melting Enthalpy of Cocrystals

Ahmad Alhadid, Lea Kefalianakis, Alexander Wendler, Sahar Nasrallah, Christian Jandl, Silva M. Kronawitter, Gregor Kieslich and Mirjana Minceva

Crystal Growth & Design, 2024, 24, 4770
DOI: 10.1021/acs.cgd.4c00393

Cluster aggregation of water-based deep eutectic solvents in water and evaluation of their cytotoxicity

Elison Lepore, Gianluca Ciancaleoni, Diego Romano Perinelli, Giulia Bonacucina, Serena Gabrielli, Gaia de Simone, Rosita Gabbianelli, Laura Bordoni and Matteo Tiecco

Journal of Molecular Liquids, 2024, 415, 126427
DOI: 10.1016/j.molliq.2024.126427

Choline chloride-water mixtures as new generation of green solvents: A comprehensive physico-chemical study

Emanuela Mangiacapre, Franca Castiglione, Matteo D'Aristotile, Valerio Di Lisio, Alessandro Triolo and Olga Russina

Journal of Molecular Liquids, 2023, 383, 122120
DOI: 10.1016/j.molliq.2023.122120

Fine-tuning the Basicity of Deep Eutectic Solvents by Substituting Guanidine for Urea in Reline

Tatsuya Umecky, Akihiro Goto, Naoki Hayashi and Kazuki Eguchi

ACS Omega, 2023, 8, 14694
DOI: 10.1021/acsomega.3c00706

Evaluation of physicochemical properties of Type-II deep eutectic solvents/Water mixtures based on choline chloride and calcium/magnesium chloride hexahydrate

Chiara Pelosi, José Gonzalez-Rivera, Maria Rosaria Tiné, Gianluca Ciancaleoni, Luca Bernazzani and Celia Duce

Journal of Molecular Liquids, 2023, 392, 123459
DOI: 10.1016/j.molliq.2023.123459

Comparative Assessment & Environmental Impacts of Lixiviants for Hydrometallurgical Lithium‐Ion Battery Recycling

Sohini Bhattacharyya, Rosario Vidal, Salma H. Alhashim, Xi Chen and P. M. Ajayan

Advanced Energy Materials, 2025, 15
DOI: 10.1002/aenm.202405348

aquo-DESs: Water-based binary natural deep eutectic solvents

Eduardo Picciolini, Genny Pastore, Tiziana Del Giacco, Gianluca Ciancaleoni, Matteo Tiecco and Raimondo Germani

Journal of Molecular Liquids, 2023, 383, 122057
DOI: 10.1016/j.molliq.2023.122057

Everything You Wanted to Know about Deep Eutectic Solvents but Were Afraid to Be Told

Dinis O. Abranches and João A.P. Coutinho

Annual Review of Chemical and Biomolecular Engineering, 2023, 14, 141
DOI: 10.1146/annurev-chembioeng-101121-085323

Exploring the potential of deep eutectic solvents in pharmaceuticals: Challenges and opportunities

Priyanka A. Shah, Vishwajit Chavda, Darshna Hirpara, Vinay S. Sharma, Pranav S. Shrivastav and Sanjeev Kumar

Journal of Molecular Liquids, 2023, 390, 123171
DOI: 10.1016/j.molliq.2023.123171

Exploring the potential for recycling sewage sludge in biodiesel using deep eutectic solvents: A proposal of circular economy based on life cycle assessment approach

Brayan S. Moreno-Caballero, Pasiano Rivas-García, Alejandro Estrada-Baltazar, Juan P. Paniagua-Martínez, Jean-Marc Leveque and José J. Cano-Gómez

Biomass and Bioenergy, 2025, 201, 107845
DOI: 10.1016/j.biombioe.2025.107845

Defying decomposition: the curious case of choline chloride

Adriaan van den Bruinhorst, Jocasta Avila, Martin Rosenthal, Ange Pellegrino, Manfred Burghammer and Margarida Costa Gomes

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-42267-6

Experimental and predictive analysis of deep eutectic solvent gel membranes for efficient CO2 separation

Remya Ranjith, Bharti Saini, Swapnil Dharaskar, Tushar Patil, Grishma Pindolia, Satyam Shinde and Rama Rao Karri

Sci Rep, 2025, 15
DOI: 10.1038/s41598-025-14520-z

Comparison of liquid–liquid phase equilibrium behavior of acetonitrile–water system using choline chloride salt and water-based deep eutectic solvent

Safie Farahi, Hamid Reza Mortaheb, Babak Mokhtarani and Kourosh Tabar Heydar

Journal of Molecular Liquids, 2024, 415, 126330
DOI: 10.1016/j.molliq.2024.126330

High photothermal conversion deep eutectic solvent nanofluids combined with high reflectivity film for atmospheric water gathering

Jingqiong Gao, Zhuohan Wang, Xueling Zhao, Omid Mahian, Huaqing Xie and Wei Yu

Energy Conversion and Management, 2023, 297, 117750
DOI: 10.1016/j.enconman.2023.117750

Rhenium volatilization in SiO2-KNO3-KReO4 mixtures at elevated temperatures

Chenchen Niu, Aiqing Chen, Kaiwen Hu and Kai Xu

Nuclear Engineering and Design, 2025, 432, 113758
DOI: 10.1016/j.nucengdes.2024.113758

Low-frequency Raman spectra of choline chloride-water mixtures

Koshi Ozama, Yuko Amo, Yasuo Kameda and Takeshi Usuki

Chemical Physics Letters, 2025, 861, 141829
DOI: 10.1016/j.cplett.2024.141829