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Electron Tunneling in Biology: When Does it Matter?

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Photochemical Oxidation of Substrate Water Analogs and Halides by Photosystem II

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Ligand Radicals Tune LPMO Activity in Model Complex

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Exploring the fascination of metal-sulfur bonds, vivid colors, and electron transfer through proteins: A tribute to Harry B. Gray

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Empowering Precision C–H Functionalization: Advances in Peroxygenase Engineering

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Tryptophan‐96 in cytochrome P450 BM3 plays a key role in enzyme survival

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Detection of a Kinetically Competent Compound-I Intermediate in the Vancomycin Biosynthetic Enzyme OxyB

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Understanding the Key Roles of pH Buffer in Accelerating Lignin Degradation by Lignin Peroxidase

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Discovery of a Copper-Binding Carbohydrate-Binding Module Regulating the Activity of Lytic Polysaccharide Monooxygenases

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Emerging Trends of Bilirubin Oxidases at the Bioelectrochemical Interface: Paving the Way for Self-Powered Electrochemical Devices and Biosensors

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Understanding the Multifaceted Mechanism of Compound I Formation in Unspecific Peroxygenases through Multiscale Simulations

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Inorganic Fe-O and Fe-S oxidoreductases: paradigms for prebiotic chemistry and the evolution of enzymatic activity in biology

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Unveiling the role of inorganic nanoparticles in Earth’s biochemical evolution through electron transfer dynamics

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Theory of Protein Charge Transfer: Electron Transfer between Tryptophan Residue and Active Site of Azurin

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Electron Transport through a Tryptophan Quadruplex in a Dimeric Azurin Construct

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Mapping the Initial Stages of a Protective Pathway that Enhances Catalytic Turnover by a Lytic Polysaccharide Monooxygenase

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Biological mechanisms of sodium nitroprusside in enhancing quality of Radix Paeoniae Rubra and Radix Paeoniae Alba

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The crystal structure of CbpD clarifies substrate-specificity motifs in chitin-active lytic polysaccharide monooxygenases

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Signatures of Electron–Hole Hopping in Myoglobin Peroxidase Activity Revealed by Deep Mutational Learning

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Flavodiiron proteins in Physcomitrium patens: navigating the edge between photoprotection and efficiency

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One-step electrochemical approach of enzyme immobilization for bioelectrochemical applications

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Following the Fate of Lytic Polysaccharide Monooxygenases under Oxidative Conditions by NMR Spectroscopy

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Effect of Water Deuteration on Protein Electron Transfer

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Non-covalent interactions in the structure and function of metalloenzymes and related systems

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Empowering Precision C–H Functionalization: Advances in Peroxygenase Engineering

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π-π interactions in structural stability: Role in superoxide dismutases

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Protein Electron Transfer in Solution, Protein Powders, and Electrode Confinement

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ACS Omega, 2026
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On the Non‐Catalytic Role of Lytic Polysaccharide Monooxygenases in Boosting the Action of PETases on PET Polymers

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Probing the Role of Cysteine Thiyl Radicals in Biology: Eminently Dangerous, Difficult to Scavenge

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Structure–Function Analysis of an Understudied Type of LPMO with Unique Redox Properties and Substrate Specificity

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On the importance of π-π interactions in the structural stability of phycocyanins

Luka Breberina, Milan Nikolic, Srdjan Stojanovic and Mario Zlatovic

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Lactoperoxidase: Identification of the two Tyr radical sites for the stabilization of the pH-dependent [Fe(IV) = O Tyr•] catalytic intermediates by resonance Raman and multifrequency Electron Paramagnetic Resonance spectroscopies

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Mono-fluorotryptophans as probes of proton-coupled electron transfer in biology

Jane Fu, Nejc Nagelj, Matthew C. Drummer, Kristopher G. Reynolds, Dave Y. Song, JoAnne Stubbe and Daniel G. Nocera

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Conformational triggering in voltammetry and single-molecule conductivity of two-centre redox metalloproteins: Cytochrome c4 and copper nitrite reductase

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Antioxidant and prooxidant modulation of lipid peroxidation by integral membrane proteins

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Protein Medium Facilitates Electron Transfer in Photosynthetic Heliobacterial Reaction Center

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Functional and Structural Characterizations of Lytic Polysaccharide Monooxygenase, Which Cooperates Synergistically with Cellulases, from Ceriporiopsis subvermispora

Huyen Nguyen, Keiko Kondo, Yusei Yagi, Yu Iseki, Nagi Okuoka, Takashi Watanabe, Bunzo Mikami, Takashi Nagata and Masato Katahira

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Cleavage of a Peroxide Bond via a Dual Attack by Functional Mimics of Glutathione Peroxidase

Rakesh Kumar Rai, Amirul Islam, Rudra Shankar Pati and Gouriprasanna Roy

Chemistry A European J, 2025, 31
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