A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles.
S. Zhang, N. Rotta-Loria, F. Weniger, J. Rabeah, H. Neumann, C. Taeschler and M. Beller, Chem. Commun., 2019, 55, 6723 DOI: 10.1039/C9CC01971E
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