Different reactivity of the heavier group 14 element alkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2) with R2NO

Geoffrey H. Spikes; Yang Peng; James C. Fettinger; Jochen Steiner; Philip P. Power

doi:10.1039/B513189H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Different reactivity of the heavier group 14 elementalkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂) with R₂NO†

Geoffrey H. Spikes,^a Yang Peng,^a James C. Fettinger,^a Jochen Steiner^a and Philip P. Power*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California Davis, One Shields Ave., Davis, CA 95616, USA
E-mail: pppower@ucdavis.edu
Fax: 001 530 752 8995
Tel: 001 530 752 6913

Abstract

The reactions of the digermanium and ditin alkyne analogues Ar′MMAr′ (M = Ge or Sn) with R₂NO, (R₂NO = Me₂C [upper bond 1 start] (CH₂)₃CMe₂N [upper bond 1 end] O or N₂O), result in complete MM bond cleavage to afford the germylene :Ge(Ar′)ONR₂ or the germanium(II) or tin(II) hydroxides {M(Ar′)(μ–OH)}₂.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

Download options Please wait...

Supplementary files

Crystal structure data TXT (66K)

Article information

DOI: https://doi.org/10.1039/B513189H
Article type: Communication
Submitted: 16 Sep 2005
Accepted: 06 Oct 2005
First published: 09 Nov 2005

Download Citation

Chem. Commun., 2005, 6041-6043

Permissions

Request permissions

Different reactivity of the heavier group 14 element alkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂) with R₂NO

G. H. Spikes, Y. Peng, J. C. Fettinger, J. Steiner and P. P. Power, Chem. Commun., 2005, 6041 DOI: 10.1039/B513189H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications