Issue 16, 2025

Sub-5 nm monolayer KMgX (X = P, As, Sb)-based homogeneous CMOS devices for high-performance applications

Abstract

For CMOS electronics, the channel materials – which can offer symmetrical performance for n- and p-type devices, along with the ability to scale transistors down to the ultra-scale limit – are crucial in the next era beyond silicon. Monolayer KMgX (X = P, As, Sb) not only possesses an atomically thin structure, but also exhibits high mobility for both electrons and holes; being advantageous for symmetrical performance and shrinking a device’s size. Based on first-principles calculations, the device performance limit of sub-5 nm monolayer KMgX (X = P, As, Sb) metal–oxide semiconductor field-effect transistors (MOSFETs) with a double-gated setup are investigated. The results show that, for all three KMgX configurations (X = P, As, Sb), both n- and p-type MOSFETs can meet the ITRS 2013 requirements for 2028 horizon in high-performance applications, even as Lg reduces to 3 nm. The ON-state currents of those systems exceed the performance of most previously reported monolayer MOSFETs. In particular, the 5 nm-Lg n-type KMgSb and KMgAs MOSFETs exhibit ultra-high ON-state currents of 3463 and 3248 μA μm−1, respectively. Furthermore, the ratios of subthreshold swing, ON-state current, fringe capacitance, delay time, and power-delay product between n- and p-type devices, demonstrate a high degree of symmetry. Our results suggest that the use of monolayer KMgX (X = P, As, Sb) MOSFETs would be highly advantageous for the development of sub-5 nm homogeneous CMOS electronics.

Graphical abstract: Sub-5 nm monolayer KMgX (X = P, As, Sb)-based homogeneous CMOS devices for high-performance applications

Supplementary files

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Article information

Article type
Paper
Submitted
19 sty 2025
Accepted
10 mar 2025
First published
15 mar 2025

Nanoscale, 2025,17, 10165-10176

Sub-5 nm monolayer KMgX (X = P, As, Sb)-based homogeneous CMOS devices for high-performance applications

Y. Guo, Y. Guo, Z. Huan, Y. Jiang, D. Wang, X. Gao, K. Bian, Z. Gu, S. Zhao, X. Duan, L. Lin, H. Zeng and X. Yan, Nanoscale, 2025, 17, 10165 DOI: 10.1039/D5NR00264H

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