Cyrene™ blends: a greener solvent system for organic syntheses

Caren Sullivan, Yuanzhe Zhang, Guolin Xu, Lyra Christianson, Fernando Luengo, Todd Halkoski and Peng Gao

Green Chem., 2022, 24, 7184
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Recent advancement in the synthesis of isothiocyanates

Bumpei Maeda and Kei Murakami

Chem. Commun., 2024, 60, 2839
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Dihydrolevoglucosenone (Cyrene™), a new possibility of an environmentally compatible solvent in synthetic organic electrochemistry

Jose Manuel Ramos-Villaseñor, Jessica Sotelo-Gil, Sandra E. Rodil and Bernardo Antonio Frontana-Uribe

Faraday Discuss., 2023, 247, 182
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Cyrene: a bio-based solvent for the Mizoroki–Heck reaction of aryl iodides

Naya A. Stini, Petros L. Gkizis and Christoforos G. Kokotos

Org. Biomol. Chem., 2023, 21, 351
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Na2CO3-promoted synthesis of thiocarbamates from isocyanates and thiols under mild conditions

Yingbin Gong, Leilei Yan and Zhiqiang Guo

Org. Biomol. Chem., 2024, 22, 6277
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Towards greener-by-design fine chemicals. Part 1: synthetic frontiers

Theodore A. Gazis, Jonas Wuyts, Areti Moutsiou, Giulio Volpin, Mark J. Ford, Rodolfo I. Teixeira, Katherine M. P. Wheelhouse, Philipp Natho, Polona Žnidaršič-Plazl, Sonja Jost, Renzo Luisi, Brahim Benyahia, Bert U. W. Maes and Gianvito Vilé

Chem. Soc. Rev., 2026, 55, 619
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Cationic ring-opening polymerization of 2-oxazolines in γ-butyrolactones using various initiators

Tingwei Chen, Chenke Zhao, Tao Lai and Junpeng Zhao

Polym. Chem., 2025, 16, 903
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Electro-oxidative three-component cascade coupling of isocyanides with elemental sulfur and amines for the synthesis of 2-aminobenzothiazoles

Peng-Fei Huang, Jia-Le Fu, Ying Peng, Jian-Hong Fan, Long-Jin Zhong, Ke-Wen Tang and Yu Liu

Org. Biomol. Chem., 2024, 22, 3752
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Carborane isothiocyanates: synthesis, characterization and conjugation with N-nucleophiles

Victoria M. Alpatova, Evgeny G. Rys, Alexander F. Smol’yakov, Elena G. Kononova and Valentina A. Ol'shevskaya

New J. Chem., 2026, 50, 6197
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Cyrene: a bio-based novel and sustainable solvent for organic synthesis

Naya A. Stini, Petros L. Gkizis and Christoforos G. Kokotos

Green Chem., 2022, 24, 6435
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Polythiourethanes: Synthesis, applications, and opportunities

Xabier Lopez de Pariza, Paula Fanlo, Lucas Polo Fonseca, Alaitz Ruiz de Luzuriaga and Haritz Sardon

Progress in Polymer Science, 2023, 145, 101735
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Cyrene: A Green Solvent for the Synthesis of Bioactive Molecules and Functional Biomaterials

Andrea Citarella, Arianna Amenta, Daniele Passarella and Nicola Micale

IJMS, 2022, 23, 15960
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Probing the remarkable vitrimeric performance of Poly(dithiourethanes): A comprehensive investigation into the dynamic behavior

Federico Guerrero-Ruiz, Sebastian Bonardd, Itziar Otaegi, Ester Verde-Sesto and Jon Maiz

European Polymer Journal, 2024, 217, 113305
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Aqueous microwave assisted novel synthesis of isothiocyanates by amine catalyzed thionation of isocyanides with Lawesson's reagent

Sodeeq Aderotimi Salami, Vincent J. Smith and Rui W. M. Krause

Journal of Sulfur Chemistry, 2023, 44, 269
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Reactivities and mechanisms in organic reactions involving activation of elemental sulfur under basic conditions

Peter Conen and Michael A.R. Meier

Tetrahedron Chem, 2024, 11, 100086
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Polythionourethane Thermoset Synthesis via Activation of Elemental Sulfur in an Efficient Multicomponent Reaction Approach

Jonas Wolfs, Iuliana Ribca, Michael A. R. Meier and Mats Johansson

ACS Sustainable Chem. Eng., 2023, 11, 3952
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Preparation and Application of Green Sustainable Solvent Cyrene

Yadong Wang, Mingfei Dai, Gang Luo, Jiajun Fan, James H. Clark and Shicheng Zhang

Chemistry, 2023, 5, 2322
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Visible‐Light‐Promoted Cascade Coupling of 2‐Isocyanonaphthalenes with Elemental Sulfur and Amines to Construct Naphtho[2,1‐d]thiazol‐2‐Amines

Hongyu Ding, Siyu Shi, Yanan Hou, Wenxiu Cui, Rong Sun, Yufen Lv, Huilan Yue, Wei Wei and Dong Yi

Chemistry A European J, 2024, 30
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Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context

Ainaa Nadiah Abd Halim and Zainab Ngaini

Phosphorus, Sulfur, and Silicon and the Related Elements, 2025, 200, 109
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Comprehensive review on the synthesis of isothiocyanates via desulfurization

Mohammed Akram, Malleboina Prasad, Nandigam Meghana, R. Ramesh Naidu, S. N. Murthy Boddapati and Ramana Tamminana

Journal of Sulfur Chemistry, 2026, 1
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Transition-Metal-Free Radical Approach for the Synthesis of Isothiocyanates by Pyridinium 1,4-Zwitterionic Thiolates as a Sulfur Source

Fatemeh Abdiyan Mobarakeh, Hormoz Khosravi, Alireza Akbari, Frank Rominger and Saeed Balalaie

J. Org. Chem., 2025, 90, 1912
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Cyrene Dimethyl Acetal: Potential Alternative Solvent for Pd‐Catalyzed Homogeneous Aminocarbonylation of Iodo(hetero)arene Compounds

Attila Takács, Nuray Uzunlu Ince, Zoltán Medgyesi, Huda Hamed, László Kollár, Bence Mihalovics and László T. Mika

ChemPlusChem, 2026, 91
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Cyrene: a very reactive bio-based chiral ketone in diastereoselective Passerini reactions

Luan A. Martinho, Thaissa P. F. Rosalba, Gustavo G. Sousa, Claudia C. Gatto, José Roberto S. Politi and Carlos Kleber Z. Andrade

Mol Divers, 2024, 28, 111
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Reactivity of Biomass‐Derived Olefins with Elemental Sulfur: Mechanistic Insight

Nawoda L. Kapuge Dona, Charini P. Maladeniya and Rhett C. Smith

Eur J Org Chem, 2024, 27
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Polymer Modification of Asphalt with Recycling By-Products of Polyurethane Foam as Asphalt Extender

Jiao Lin, Zepeng Fan, Jiazhu Wang, Junfu Liu, Jiaqiu Xu, Dong Liang and Dawei Wang

J. Mater. Civ. Eng., 2026, 38
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Polythiosemicarbazones by Condensation of Dithiosemicarbazides and Dialdehydes

Roman Nickisch, Peter Conen and Michael A. R. Meier

Macromolecules, 2022, 55, 3267
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Synthesis of highly substituted alkenes by sulfur-mediated olefination of N-tosylhydrazones

Peter Conen, Roman Nickisch and Michael A. R. Meier

Commun Chem, 2023, 6
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Recent Advances in the Synthesis and Applications of Isothiocyanates

Zunqi Liu, Jahangir Khan, Muhammad Akram and Yasir Mumtaz

Chinese Journal of Organic Chemistry, 2025, 45, 2350
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Recent Advances in the Synthesis of Isothiocyanates Using Elemental Sulfur

András Németh and Péter Ábrányi-Balogh

Catalysts, 2021, 11, 1081
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High-Sulfur-Content Materials Derived from Postconsumer Polystyrene Wastes: Thermomechanical Properties, Environmental Impacts, and Microstructural Insights

Shalini K. Wijeyatunga, Andrew G. Tennyson and Rhett C. Smith

ACS Sustainable Resour. Manage., 2024, 1, 2173
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One‐Pot Synthesis of Thiocarbamates

Kevin A. Waibel, Dennis Barther, Triantafillia Malliaridou, Dafni Moatsou and Michael A. R. Meier

Eur J Org Chem, 2021, 2021, 4508
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Sustainable Domino C−N/C−C Bond Formation with Outstanding E Factors and High Volume Productivity

Jih Ru Hwu, Nitesh K. Gupta, Avijit Panja, Chin‐Hwa Chang, Wen‐Chieh Huang, Yu‐Ran Tsai, Kau‐Shu Chung, Kui‐Thong Tan, Chun‐Cheng Lin, Kuo‐Chu Hwang and Shwu‐Chen Tsay

Eur J Org Chem, 2024, 27
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Bacterial Isothiocyanate Biosynthesis by Rhodanese‐Catalyzed Sulfur Transfer onto Isonitriles

Mandy D. Mlotek, Benjamin Dose and Christian Hertweck

ChemBioChem, 2024, 25
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Recent Advances in the Synthesis and Applications of Thiocarbonyl Compounds

Jayshree Nandkumar Solanke, Deepika Sharma, Nalinikant Patra, Rambabu Dandela and Vasudevan Dhayalan

Eur J Org Chem, 2025, 28
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A Cost-effective and Green Synthesis of Isothiocyanates

Qinsheng Li, Junhao Xiong, Jiahao Liao, Qinghua Huang, Zhongyu Hu, Yuping Yang, Zhenhua Xiong and Chuanjie Cheng

LOC, 2023, 20, 1004
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Synthesis of Novel Vegetable Oil-Derived Polythiols and Their Thermosets

Peter Conen, F. Clara M. Scheelje, Ramon Häusl and Michael A. R. Meier

ACS Sustainable Chem. Eng., 2025, 13, 19899
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Characterization and Application of Cyrene as a Biomass‐Based Solvent for Homogeneous Heck‐Coupling Reaction

Zoltán Medgyesi and László T. Mika

ChemPlusChem, 2024, 89
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Sodium Carbonate-Promoted Formation of 5-Amino-1,2,4-thiadiazoles and 5-Amino-1,2,4-selenadiazoles with Elemental Sulfur and Selenium

Jun-Xu Lin, Guo-Hui Liu, Li-Qiu Liu, Ying-Chun Wang and Yan He

J. Org. Chem., 2024, 89, 101
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Thiocracking of Multi-Materials: High-Strength Composites from Post-Consumer Food Packaging Jars

Katelyn M. Derr and Rhett C. Smith

Sustainability, 2024, 16, 7023
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Convenient Multicomponent One‐Pot Synthesis of 2‐Iminothiazolines and 2‐Aminothiazoles Using Elemental Sulfur Under Aqueous Conditions

András Gy. Németh, Bence Marlok, Attila Domján, Qinghe Gao, Xinya Han, György M. Keserű and Péter Ábrányi‐Balogh

Eur J Org Chem, 2021, 2021, 3587
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Cyrene: A bio-based sustainable solvent for organic synthesis

Dickson Kong and Anton V. Dolzhenko

Sustainable Chemistry and Pharmacy, 2022, 25, 100591
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Sustainable One-Pot Cellulose Dissolution and Derivatization via a Tandem Reaction in the DMSO/DBU/CO2 Switchable Solvent System

Jonas Wolfs, Roman Nickisch, Lisa Wanner and Michael A. R. Meier

J. Am. Chem. Soc., 2021, 143, 18693
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Extraordinary catalytic performance of lycopene in the conversion of amino acid like aspartic acid to aspartic thioamide using catalytic transfer sulfurization process

Martha Ramesh, B. Venugopal Rao, M. Ravi Chander and Nabanita Pal

Journal of the Indian Chemical Society, 2025, 102, 101812
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