Advances and opportunities in Group 15 porphyrin chemistry

Prashanth K. Poddutoori

Dalton Trans., 2023, 52, 14287
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Solvent dependent triplet state delocalization in a co-facial porphyrin heterodimer

Susanna Ciuti, Jacopo Toninato, Antonio Barbon, Niloofar Zarrabi, Prashanth K. Poddutoori, Art van der Est and Marilena Di Valentin

Phys. Chem. Chem. Phys., 2022, 24, 30051
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Electron spin dynamics in excited state photochemistry: recent development in the study of intersystem crossing and charge transfer in organic compounds

Muhammad Imran, Xue Zhang, Zhijia Wang, Xi Chen, Jianzhang Zhao, Antonio Barbon and Violeta K. Voronkova

Phys. Chem. Chem. Phys., 2021, 23, 15835
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A long-lived charge-separated state of spiro compact electron donor–acceptor dyads based on rhodamine and naphthalenediimide chromophores

Xiao Xiao, Ivan Kurganskii, Partha Maity, Jianzhang Zhao, Xiao Jiang, Omar F. Mohammed and Matvey Fedin

Chem. Sci., 2022, 13, 13426
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The effect of thionation of the carbonyl group on the photophysics of compact spiro rhodamine-naphthalimide electron donor–acceptor dyads: intersystem crossing, charge separation, and electron spin dynamics

Xiao Xiao, Tong Mu, Andrey A. Sukhanov, Yihang Zhou, Peiran Yu, Fabiao Yu, Ayhan Elmali, Jianzhang Zhao, Ahmet Karatay and Violeta K. Voronkova

Phys. Chem. Chem. Phys., 2023, 25, 31667
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Photophysics and photochemistry of thermally activated delayed fluorescence emitters based on the multiple resonance effect: transient optical and electron paramagnetic resonance studies

Xi Chen, Lei Sun, Andrey A. Sukhanov, Sandra Doria, Laura Bussotti, Jianzhang Zhao, Haijun Xu, Bernhard Dick, Violeta K. Voronkova and Mariangela Di Donato

Chem. Sci., 2024, 15, 10867
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Charge separation and intersystem crossing in compact, orthogonal and sterically encumbered 6,12-diphenyl indolo[3,2-b]carbazole-naphthalimide electron donor–acceptor dyad

Xue Zhang, Ziqian Xu, Andrey A. Sukhanov, Xichuan Yang, Ayhan Elmali, Jianzhang Zhao, Bernhard Dick, Ahmet Karatay and Violeta K. Voronkova

Org. Chem. Front., 2025, 12, 3344
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Antimony(+5) ion induced tunable intramolecular charge transfer in hypervalent antimony(v) porphyrins

Noah Holzer, Jatan K. Sharma, Steven Peterson, Brandon J. Bayard, Vladimir N. Nesterov, Paul A. Karr, Francis D'Souza and Prashanth K. Poddutoori

Dalton Trans., 2022, 51, 5890
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Time-resolved transient optical and electron paramagnetic resonance spectroscopic studies of electron donor–acceptor thermally activated delayed fluorescence emitters based on naphthalimide–phenothiazine dyads

Kaiyue Ye, Andrey A. Sukhanov, Yu Pang, Aidar Mambetov, Minjie Li, Liyuan Cao, Jianzhang Zhao, Violeta K. Voronkova, Qian Peng and Yan Wan

Phys. Chem. Chem. Phys., 2025, 27, 813
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Long‐Lived Charge‐Transfer State in Spiro Compact Electron Donor–Acceptor Dyads Based on Pyromellitimide‐Derived Rhodamine: Charge Transfer Dynamics and Electron Spin Polarization

Xi Chen, Andrey A. Sukhanov, Yuxin Yan, Damla Bese, Cagri Bese, Jianzhang Zhao, Violeta K. Voronkova, Antonio Barbon and Halime Gul Yaglioglu

Angewandte Chemie, 2022, 134
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The OpenMolcas Web: A Community-Driven Approach to Advancing Computational Chemistry

Giovanni Li Manni, Ignacio Fdez. Galván, Ali Alavi, Flavia Aleotti, Francesco Aquilante, Jochen Autschbach, Davide Avagliano, Alberto Baiardi, Jie J. Bao, Stefano Battaglia, Letitia Birnoschi, Alejandro Blanco-González, Sergey I. Bokarev, Ria Broer, Roberto Cacciari, Paul B. Calio, Rebecca K. Carlson, Rafael Carvalho Couto, Luis Cerdán, Liviu F. Chibotaru, Nicholas F. Chilton, Jonathan Richard Church, Irene Conti, Sonia Coriani, Juliana Cuéllar-Zuquin, Razan E. Daoud, Nike Dattani, Piero Decleva, Coen de Graaf, Mickaël G. Delcey, Luca De Vico, Werner Dobrautz, Sijia S. Dong, Rulin Feng, Nicolas Ferré, Michael Filatov(Gulak), Laura Gagliardi, Marco Garavelli, Leticia González, Yafu Guan, Meiyuan Guo, Matthew R. Hennefarth, Matthew R. Hermes, Chad E. Hoyer, Miquel Huix-Rotllant, Vishal Kumar Jaiswal, Andy Kaiser, Danil S. Kaliakin, Marjan Khamesian, Daniel S. King, Vladislav Kochetov, Marek Krośnicki, Arpit Arun Kumaar, Ernst D. Larsson, Susi Lehtola, Marie-Bernadette Lepetit, Hans Lischka, Pablo López Ríos, Marcus Lundberg, Dongxia Ma, Sebastian Mai, Philipp Marquetand, Isabella C. D. Merritt, Francesco Montorsi, Maximilian Mörchen, Artur Nenov, Vu Ha Anh Nguyen, Yoshio Nishimoto, Meagan S. Oakley, Massimo Olivucci, Markus Oppel, Daniele Padula, Riddhish Pandharkar, Quan Manh Phung, Felix Plasser, Gerardo Raggi, Elisa Rebolini, Markus Reiher, Ivan Rivalta, Daniel Roca-Sanjuán, Thies Romig, Arta Anushirwan Safari, Aitor Sánchez-Mansilla, Andrew M. Sand, Igor Schapiro, Thais R. Scott, Javier Segarra-Martí, Francesco Segatta, Dumitru-Claudiu Sergentu, Prachi Sharma, Ron Shepard, Yinan Shu, Jakob K. Staab, Tjerk P. Straatsma, Lasse Kragh Sørensen, Bruno Nunes Cabral Tenorio, Donald G. Truhlar, Liviu Ungur, Morgane Vacher, Valera Veryazov, Torben Arne Voß, Oskar Weser, Dihua Wu, Xuchun Yang, David Yarkony, Chen Zhou, J. Patrick Zobel and Roland Lindh

J. Chem. Theory Comput., 2023, 19, 6933
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Temperature Tunable Optical Properties of Tetraheptylaluminum(III) Porphyrin Toward Molecular Thermometer

Stefan Charon, Niloofar Zarrabi, Jatan K. Sharma, Paul A. Karr, Francis D’Souza and Prashanth K. Poddutoori

ChemPhysChem, 2025, 26
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Charge Transfer and Intersystem Crossing in Compact Naphthalenediimide–Phenothiazine Triads: Synthesis and Study of the Photophysical Property with Transient Optical and Electron Paramagnetic Resonance Spectroscopic Methods

Lezhang Liu, Xi Liu, Ivan Kurganskii, Xi Chen, Gagik G. Gurzadyan, Jianzhang Zhao, Yan Wan and Matvey Fedin

J. Phys. Chem. B, 2024, 128, 7237
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Long-Lived Triplet Charge Separated State and Thermally Activated Delayed Fluorescence in a Compact Orthogonal Anthraquinone–Phenothiazine Electron Donor–Acceptor Dyad

Xiaoyu Zhao, Andrey A. Sukhanov, Xiao Jiang, Jianzhang Zhao and Violeta K. Voronkova

J. Phys. Chem. Lett., 2022, 13, 2533
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Multiconfigurational Excitonic Couplings in Homo- and Heterodimer Stacks of Azobenzene-Derived Dyes

Razan E. Daoud, Roberto Cacciari and Luca De Vico

J. Phys. Chem. A, 2024, 128, 9398
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Hypervalent Phosphorus(V) Porphyrins with meso-Methoxyphenyl Substituents: Significance of the Number and Position of Methoxy Groups in Promoting Intramolecular Charge Transfer

Jatan K. Sharma, Brandon J. Bayard, Nick Zosel, Syeda S. Ali, Noah Holzer, Vladimir N. Nesterov, Paul A. Karr, Francis D’Souza and Prashanth K. Poddutoori

Inorg. Chem., 2022, 61, 16573
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The electronic structure and dynamics of the excited triplet state of octaethylaluminum(III)-porphyrin investigated with advanced EPR methods

Angelo Carella, Susanna Ciuti, Haakon T.A. Wiedemann, Christopher W.M. Kay, Arthur van der Est, Donatella Carbonera, Antonio Barbon, Prashanth K. Poddutoori and Marilena Di Valentin

Journal of Magnetic Resonance, 2023, 353, 107515
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Red Light‐Emitting Thermally‐Activated Delayed Fluorescence of Naphthalimide‐Phenoxazine Electron Donor‐Acceptor Dyad: Time‐Resolved Optical and Magnetic Spectroscopic Studies

Xue Zhang, Xiao Liu, Maria Taddei, Laura Bussotti, Ivan Kurganskii, Minjie Li, Xiao Jiang, Longjiang Xing, Shaomin Ji, Yanping Huo, Jianzhang Zhao, Mariangela Di Donato, Yan Wan, Zujin Zhao and Matvey V. Fedin

Chemistry A European J, 2022, 28
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Excited state dynamics and electron transfer in a phosphorus(V) porphyrin – TEMPO conjugate

PRASHANTH K PODDUTOORI, NOAH HOLZER, BRANDON J BAYARD, YURI E KANDRASHKIN, GARY LIM, FRANCIS D’SOUZA and ART VAN DER EST

J Chem Sci, 2021, 133
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Long‐Lived Charge Separated States in Anthraquinone‐Phenothiazine Dyads: Synthesis and Study of the Photophysical Property by Using Transient Optical and Magnetic Resonance Spectroscopies

Haiqing Wang, Andrey A. Sukhanov, Alessandro Iagatti, Laura Bussotti, Xiaoyu Zhao, Jianzhang Zhao, Violeta K. Voronkova and Mariangela Di Donato

Chemistry A European J, 2023, 29
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Fluorinated Antimony(V) Tetraarylporphyrins as High-Valent Electron Acceptors with Unparalleled Reduction Potentials

Noah Holzer, Jiacheng Jin, Vladimir N. Nesterov, Jatan K. Sharma, Niloofar Zarrabi, Francis D’Souza and Prashanth K. Poddutoori

Inorg. Chem., 2023, 62, 7097
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Intersystem Crossing, Photo‐Induced Charge Separation and Regioisomer‐Specific Excited State Dynamics in Fully Rigid Spiro Rhodammine‐Naphthalene/Anthraquinone Electron Donor‐Acceptor Dyads

Kaiyue Ye, Andrey A. Sukhanov, Jiayu Li, Lishan Liu, Xi Chen, Jianzhang Zhao, Violeta K. Voronkova and Ming De Li

Chemistry A European J, 2025, 31
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Recent Developments on Understanding Charge Transfer in Molecular Electron Donor‐Acceptor Systems

Xi Chen, Xue Zhang, Xiao Xiao, Zhijia Wang and Jianzhang Zhao

Angew Chem Int Ed, 2023, 62
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Electron spin polarization in the triplet state of methoxy-substituted phosphorus(V) tetraphenyl porphyrins

D. Panariti, B.J. Bayard, A. Barbon, Y.E. Kandrashkin, P.K. Poddutoori, A. van der Est and M. Di Valentin

Journal of Magnetic Resonance Open, 2024, 21, 100169
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Tuning redox potentials of phosphorus(V) tetraarylporphyrins without altering their optical properties

Noah Holzer, Jatan K. Sharma, Niloofar Zarrabi, Vladimir N. Nesterov, Francis D’Souza and Prashanth K. Poddutoori

J. Porphyrins Phthalocyanines, 2025, 29, 173
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Recent Developments on Understanding Charge Transfer in Molecular Electron Donor‐Acceptor Systems

Xi Chen, Xue Zhang, Xiao Xiao, Zhijia Wang and Jianzhang Zhao

Angewandte Chemie, 2023, 135
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Detection of the Dark States in Thermally Activated Delayed Fluorescence (TADF) Process of Electron Donor‐Acceptor Dyads: Insights from Optical Transient Absorption Spectroscopy

Xue Zhang, Xiaoyu Zhao, Kaiyue Ye and Jianzhang Zhao

Chemistry A European J, 2023, 29
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Observation of Long-Lived Charge-Separated States in Anthraquinone–Phenothiazine Electron Donor–Acceptor Dyads: Transient Optical and Electron Paramagnetic Resonance Spectroscopic Studies

Zhibin Yu, Andrey A. Sukhanov, Xiao Xiao, Alessandro Iagatti, Sandra Doria, Valeria Butera, Jianzhang Zhao, Violeta K. Voronkova, Mariangela Di Donato and Gloria Mazzone

J. Phys. Chem. B, 2023, 127, 5905
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Rational Design and Synthesis of OEP and TPP Centered Phosphorus(V) Porphyrin–Naphthalene Conjugates: Triplet Formation via Rapid Charge Recombination

Prashanth K. Poddutoori, Brandon J. Bayard, Noah Holzer, Sairaman Seetharaman, Niloofar Zarrabi, Nathan Weidner, Paul A. Karr and Francis D’Souza

Inorg. Chem., 2021, 60, 17952
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Intramolecular Charge Transfer and Spin–Orbit Coupled Intersystem Crossing in Hypervalent Phosphorus(V) and Antimony(V) Porphyrin Black Dyes

Jam Riyan Hamza, Jatan K. Sharma, Paul A. Karr, Art van der Est, Francis D’Souza and Prashanth K. Poddutoori

J. Am. Chem. Soc., 2024, 146, 25403
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Intersystem Crossing and Electron Spin Dynamics of Photoexcited Bodipy Dimers

Huaiman Cao, Andrey A. Sukhanov, Marcel M. Bakirov, Yuri E. Kandrashkin, Jianzhang Zhao and Violeta K. Voronkova

J. Phys. Chem. C, 2022, 126, 5473
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Photoinduced energy and electron transfer in a cofacial aluminum(III) porphyrin – Phosphorus(V) porphyrin heterodimer

Brandon J. Bayard, Niloofar Zarrabi, Sairaman Seetharaman, Paul Karr, Art van der Est, Francis D'Souza and Prashanth K. Poddutoori

Journal of Photochemistry and Photobiology, 2021, 8, 100069
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Long‐Lived Charge‐Transfer State in Spiro Compact Electron Donor–Acceptor Dyads Based on Pyromellitimide‐Derived Rhodamine: Charge Transfer Dynamics and Electron Spin Polarization

Xi Chen, Andrey A. Sukhanov, Yuxin Yan, Damla Bese, Cagri Bese, Jianzhang Zhao, Violeta K. Voronkova, Antonio Barbon and Halime Gul Yaglioglu

Angew Chem Int Ed, 2022, 61
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The Photophysics of Naphthalimide‐Phenoselenazine Electron Donor‐Acceptor Dyads: Revisiting the Heavy‐Atom Effect in Thermally Activated Delayed Fluorescence

Yuying Pei, Andrey A. Sukhanov, Xi Chen, Alessandro Iagatti, Sandra Doria, Xin Dong, Jianzhang Zhao, Yanqin Li, Weijie Chi, Violeta K. Voronkova, Mariangela Di Donato and Bernhard Dick

Chemistry A European J, 2025, 31
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High-Potential Hypervalent Antimony(V) Porphyrin–C60 Conjugates: Excitation Energy Transfer Dominates over Reductive Electron Transfer

Niloofar Zarrabi, Jatan K. Sharma, Katya Andzelevich, Paul A. Karr, Art van der Est, Francis D’Souza and Prashanth K. Poddutoori

Inorg. Chem., 2025, 64, 8958
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Highly Coupled Heterobicycle‐Fused Porphyrin Dimers: Excitonic Coupling and Charge Separation with Coordinated Fullerene, C60

Austen Moss, Youngwoo Jang, Jacob Arvidson, Hong Wang and Francis D'Souza

ChemSusChem, 2023, 16
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Introducing Pyridone[α]-Fused BOPHYs as Red-Shifted Bright Fluorophore Potentially Useful as Non-fullerene Acceptors in Donor–Acceptor Dyads

Dijo Prasannan and Victor N. Nemykin

Inorg. Chem., 2025, 64, 2468
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Porphyrin-based covalently bonded nanoarchitectonics of organic donor-acceptor system for artificial photosynthesis: A review

Harshad A. Mirgane, Kerba S. More, Naveena S. Veeranagaiah and Sheshanath V. Bhosale

Dyes and Pigments, 2024, 225, 112113
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