Issue 40, 2009
From the journal:

Chemical Communications

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts†‡

Takushi Shiomi,a   Takahiro Adachi,a   Kenji Toribatake,a   Li Zhoua  and  Hisao Nishiyama*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan
E-mail: hnishi@apchem.nagoya-u.ac.jp
Fax: +81-52-789-3209

Abstract

Chiral rhodium–bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.

Graphical abstract: Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

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Article information

DOI
https://doi.org/10.1039/B915759J
Article type
Communication
Submitted
31 Jul 2009
Accepted
09 Sep 2009
First published
16 Sep 2009

Chem. Commun., 2009, 5987-5989

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Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

T. Shiomi, T. Adachi, K. Toribatake, L. Zhou and H. Nishiyama, Chem. Commun., 2009, 5987 DOI: 10.1039/B915759J

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