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The electrochemical trifluoromethylarylation of N-arylacrylamides catalyzed by bromide is described. The synthetic utility of this methodology is demonstrated by transition metal-free and external oxidant-free conditions, and low catalyst loading.

Graphical abstract: Bromide-catalyzed electrochemical trifluoromethylation/cyclization of N-arylacrylamides with low catalyst loading

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