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A hierarchically porous π-conjugated polyHIPE was used as a heterogeneous visible light photoinitiator for the radical polymerization of methyl methacrylate (MMA) under a household energy saving light bulb at room temperature. The heterogeneous nature of the porous polymer ensures easy separation and reusability.

Graphical abstract: Hierarchically porous π-conjugated polyHIPE as a heterogeneous photoinitiator for free radical polymerization under visible light

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