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Abstract | Cited by

Translocation of a lead cation from the N-core of a porphyrin to a hanging carboxylate group is coupled to a transmetalation process with a second lead cation, leading to a dinuclear species. A novel hanging-atop coordination mode is responsible for the dynamic and stereocontrolled binding of lead to the porphyrin core.

Graphical abstract: Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode

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