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18O isotope labelling studies of the CO oxidation-assisted epoxidation of propene, catalyzed by a mixture of Au/TiO2 and TS-1, using a methanol–H2O solvent showed the O in the epoxide was exclusively from O2 and not H2O or methanol.

Graphical abstract: Isotope labelling study of CO oxidation-assisted epoxidation of propene. Implications for oxygen activation on Au catalysts

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