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In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds. Related works from other laboratories will be cited where suitable, aiming to give the readers a flavor of this field. Special emphasis is placed on the reaction design and development.

Graphical abstract: From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

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