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An efficient copper-catalyzed method for N-arylation of amines has been developed with part-per-million catalyst loadings at room temperature under air. Reactions of substituted (E)-1-(2-halophenyl)alkanone oximes with aliphatic amines or aromatic amines provided the N-arylation products in good to excellent yields.

Graphical abstract: Copper-catalyzed N-arylation of amines with part-per-million catalyst loadings under air at room temperature

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