Design of a gold nanoparticles site in an engineered lipase: an artificial metalloenzyme with enantioselective reductase-like activity

Carla Garcia-Sanz, Blanca de las Rivas and Jose M. Palomo

Nanoscale, 2024, 16, 6999
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Computationally driven design of an artificial metalloenzyme using supramolecular anchoring strategies of iridium complexes to alcohol dehydrogenase

Floriane L. Martins, Anca Pordea and Christof M. Jäger

Faraday Discuss., 2022, 234, 315
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Co-immobilization of a rhodium catalyst and LDH on a carbon electrode using a covalent graft strategy for electrosynthesis of l-lactate in a bipolar electrochemical system

Chunhua Zhang, Bowen Li, Xiang Gao, Wei Xiao, Mingfang Chen and Qilong Bian

Phys. Chem. Chem. Phys., 2025
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A path to perpetual chemical synthesis via photocatalytic cofactor regeneration

Vanshika Jain and Pramod P. Pillai

Chem. Sci., 2025, 16, 11184
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Recent trends in synthetic enzymatic cascades promoted by alcohol dehydrogenases

Gonzalo de Gonzalo and Caroline E. Paul

Current Opinion in Green and Sustainable Chemistry, 2021, 32, 100548
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Artificial Manganese Metalloenzymes with Laccase-like Activity: Design, Synthesis, and Characterization

Carla Garcia-Sanz, Alicia Andreu, Mirosława Pawlyta, Ana Vukoičić, Ana Milivojević, Blanca de las Rivas, Dejan Bezbradica and Jose M. Palomo

ACS Appl. Bio Mater., 2024, 7, 4760
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Designer metalloenzymes for synthetic biology: Enzyme hybrids for catalysis

Amanda G. Jarvis

Current Opinion in Chemical Biology, 2020, 58, 63
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Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp2)–H Bond Functionalization

Shunsuke Kato, Akira Onoda, Alexander R. Grimm, Kengo Tachikawa, Ulrich Schwaneberg and Takashi Hayashi

Inorg. Chem., 2020, 59, 14457
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Bioorganometallic Chemistry at the Interface with Biocatalysis: Chemoselective Reduction of Biomimetic NAD+ Cofactors with [Cp*Rh(bpy)H]+, Tandem Catalysis with 1,4-NADH-Dependent Enzymes, Chiral Synthesis, Organotin Metabolites, and DFT Mechanism Studies

Alessandro Marrone and Richard H. Fish

Organometallics, 2023, 42, 288
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Exploring and Adapting the Molecular Selectivity of Artificial Metalloenzymes

Kenward Vong, Igor Nasibullin and Katsunori Tanaka

Bulletin of the Chemical Society of Japan, 2021, 94, 382
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Artificial Nanometalloenzymes for Cooperative Tandem Catalysis

Hui Li, Chenggang Qiu, Xun Cao, Yuanyuan Lu, Ganlu Li, Xun He, Qiuhao Lu, Kequan Chen, Pingkai Ouyang and Weimin Tan

ACS Appl. Mater. Interfaces, 2019, 11, 15718
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DFT Mechanism Studies: Biomimetic 1,4-NADH Chemoselective, Co-factor Regeneration with [Cp*Rh(bpy)H]+, in Tandem with the Biocatalysis Pathways of a Core Model of the (HLADH)-Zn(II) Mediated Enzyme, in the Enantioselective Reduction of Achiral Ketones to Chiral S-Alcohols

Alessandro Marrone and Richard H. Fish

Journal of Organometallic Chemistry, 2021, 943, 121810
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Artificial Metalloenzymes: From Selective Chemical Transformations to Biochemical Applications

Tomoki Himiyama and Yasunori Okamoto

Molecules, 2020, 25, 2989
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Redox Biocatalysis: Quantitative Comparisons of Nicotinamide Cofactor Regeneration Methods

Victor K. Sharma, Justin M. Hutchison and Alan M. Allgeier

ChemSusChem, 2022, 15
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MD-DFT Computational Studies on the Mechanistic and Conformational Parameters for the Chemoselective Tyrosine Residue Reactions of G-Protein-Coupled Receptor Peptides with [Cp*Rh(H2O)3](OTf)2in Water To Form Their [(η6-Cp*Rh-Tyr#)-GPCR peptide]2+Complexes: Noncovalent H-Bonding Interactions, Molecular Orbital Analysis, Thermodynamics, and Lowest Energy Conformations

Roberto Paciotti, Richard H. Fish and Alessandro Marrone

Organometallics, 2022, 41, 2252
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Catalytic recycling of NAD(P)H

Shunichi Fukuzumi, Yong-Min Lee and Wonwoo Nam

Journal of Inorganic Biochemistry, 2019, 199, 110777
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A host–guest approach to combining enzymatic and artificial catalysis for catalyzing biomimetic monooxygenation

Liang Zhao, Junkai Cai, Yanan Li, Jianwei Wei and Chunying Duan

Nat Commun, 2020, 11
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Artificial metalloenzymes: The powerful alliance between protein scaffolds and organometallic catalysts

Benjamin Large, Natalia G. Baranska, Rosalind L. Booth, Keith S. Wilson and Anne-Kathrin Duhme-Klair

Current Opinion in Green and Sustainable Chemistry, 2021, 28, 100420
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Degradation of a Main Plastic Pollutant Polyethylene Terephthalate by Two Distinct Proteases (Neprilysin and Cutinase-like Enzyme)

Qiaoyu Hu, Vindi M. Jayasinghe-Arachchige and Rajeev Prabhakar

J. Chem. Inf. Model., 2021, 61, 764
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A Dual Anchoring Strategy for the Directed Evolution of Improved Artificial Transfer Hydrogenases Based on Carbonic Anhydrase

Alina Stein, Dongping Chen, Nico V. Igareta, Yoann Cotelle, Johannes G. Rebelein and Thomas R. Ward

ACS Cent. Sci., 2021, 7, 1874
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Structural analysis of metal chelation of the metalloproteinase thermolysin by 1,10-phenanthroline

Ki Hyun Nam

Journal of Inorganic Biochemistry, 2021, 215, 111319
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Artificial enzymes with multiple active sites

Jose M. Palomo

Current Opinion in Green and Sustainable Chemistry, 2021, 29, 100452
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A host–guest semibiological photosynthesis system coupling artificial and natural enzymes for solar alcohol splitting

Junkai Cai, Liang Zhao, Cheng He, Yanan Li and Chunying Duan

Nat Commun, 2021, 12
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Design of artificial metalloenzymes for the reduction of nicotinamide cofactors

Mattias Basle, Henry A.W. Padley, Floriane L. Martins, Gerlof Sebastiaan Winkler, Christof M. Jäger and Anca Pordea

Journal of Inorganic Biochemistry, 2021, 220, 111446
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Unlocking the therapeutic potential of artificial metalloenzymes

Katsunori TANAKA and Kenward VONG

Proc. Jpn. Acad., Ser. B, 2020, 96, 79
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FhuA–Grubbs–Hoveyda Biohybrid Catalyst Embedded in a Polymer Film Enables Catalysis in Neat Substrates

Tayebeh Mirzaei Garakani, Daniel F. Sauer, M. A. Stephanie Mertens, Jaroslav Lazar, Julia Gehrmann, Marcus Arlt, Johannes Schiffels, Uwe Schnakenberg, Jun Okuda and Ulrich Schwaneberg

ACS Catal., 2020, 10, 10946
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Covalent Triazine Framework as an Efficient Photocatalyst for Regeneration of NAD(P)H and Selective Oxidation of Organic Sulfide

Surabhi Chaubey, Rajesh K. Yadav, Santosh K. Tripathi, Bal Chandra Yadav, Sudhir N. Singh and Tae Wu Kim

Photochem & Photobiology, 2022, 98, 150
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