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Chemical Communications

One-dimensional magnetic halide double perovskites [N(CH3)4]2MIMoCl6 (MI = Na, Ag) with large A-site cations

Devesh Chandra Binwal ORCID logo a  and  Pratap Vishnoi ORCID logo *a  

* Corresponding authors

a New Chemistry Unit, International Centre for Material Science & School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore-560064, India
E-mail: pvishnoi@jncasr.ac.in

Abstract

Halide double perovskite-derived one-dimensional compounds, [N(CH3)4]2MIMoCl6 (MI = Na, Ag), have been reported. [N(CH3)4]2NaMoCl6 shows a paramagnetic to antiferromagnetic transition at a low temperature of 3.1 K. This work expands the range of one-dimensional magnetic halide double perovskites by incorporating a bulky tetramethylammonium cation in the A-site.

Graphical abstract: One-dimensional magnetic halide double perovskites [N(CH3)4]2MIMoCl6 (MI = Na, Ag) with large A-site cations

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Article information

DOI
https://doi.org/10.1039/D5CC04751J
Article type
Communication
Submitted
17 Aug 2025
Accepted
16 Oct 2025
First published
16 Oct 2025

Chem. Commun., 2025, Advance Article

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One-dimensional magnetic halide double perovskites [N(CH3)4]2MIMoCl6 (MI = Na, Ag) with large A-site cations

D. C. Binwal and P. Vishnoi, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC04751J

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