Issue 7, 2017

Accessing multiple polyethylene grades via a single redox-active olefin polymerization catalyst

Abstract

The ability to control catalytic activity via redox-activity has had a significant impact on the field of polymerization catalysis. Herein, we describe the synthesis of three unique Ni-based olefin polymerization catalysts bearing redox-active α-diimine ligands. We will demonstrate that catalysts bearing butanedione- or glyoxal-derived ligands display little to no differentiation as a function of redox-state. However, in stark contrast we will show that the catalyst bearing an acenaphthenequinone-derived ligand is capable of producing either medium-density or very-low-density polyethylene based purely on its ligand-based redox-state. This ability to access more than one polyethylene grade via a single redox-active catalyst is unprecedented.

Graphical abstract: Accessing multiple polyethylene grades via a single redox-active olefin polymerization catalyst

Supplementary files

Article information

Article type
Research Article
Submitted
06 Gur 2017
Accepted
07 Elb 2017
First published
10 Elb 2017

Inorg. Chem. Front., 2017,4, 1108-1112

Accessing multiple polyethylene grades via a single redox-active olefin polymerization catalyst

W. C. Anderson, S. H. Park, L. A. Brown, J. M. Kaiser and B. K. Long, Inorg. Chem. Front., 2017, 4, 1108 DOI: 10.1039/C7QI00079K

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