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A series of mesoporous ZSM-5 zeolite supported cobalt-based catalysts with the cobalt crystal sizes in the range of 4.5–18.1 nm were prepared for syngas conversion. The highly selective synthesis of various liquid fuels including gasoline, jet fuel and diesel range hydrocarbons is achieved with different cobalt nanoparticle sizes.

Graphical abstract: The effect of the particle size on Fischer–Tropsch synthesis for ZSM-5 zeolite supported cobalt-based catalysts

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