Issue 9, 2016

Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

Abstract

A novel supramolecular polymer Q[14]-TBPyP was successfully constructed from a host twisted cucurbit[14] (Q[14]) molecule and a four-arm 5,10,15,20-tetrakis(N-butyl-4-pyridinium)porphyrin tetrabromide (TBPyP) guest molecule depending on the host–guest interactions and characterized by NMR, ITC, DLS, electronic absorption, and fluorescence spectroscopy, representing the first cucurbit[14]uril-involved host–guest supramolecular polymer.

Graphical abstract: Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

Supplementary files

Article information

Article type
Research Article
Submitted
28 Wax 2016
Accepted
20 Ado 2016
First published
21 Ado 2016

Org. Chem. Front., 2016,3, 1144-1148

Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

Z. Gao, J. Zhang, N. Sun, Y. Huang, Z. Tao, X. Xiao and J. Jiang, Org. Chem. Front., 2016, 3, 1144 DOI: 10.1039/C6QO00310A

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