We present, to our knowledge, the first library synthesised from on-demand Grignard reagents: a 76-member library. We also present a matrix library of 21 Negishi products, both libraries giving a success rate of >90% at the organometallic step.
Metal-catalysed cross-coupling reactions are amongst the most widely used methods to directly construct new bonds.
The review is on synthesis of different classes of isoflavonoids that include isoflavones, isoflavanones, isoflavans, isoflavenes, pterocarpans, rotenoids, coumaronochromones, and coumestans.
This review presents various new strategies for the functionalization of 5 and 6-membered fused heteroaromatics. These synthetic strategies enable rapid access to complex heterocyclic compounds.
In this review, we provide a brief sketch of silver cluster-assembled materials research with crucial insights into atomic-level structural correlations with the phenomena at the nanoscale.