A semiartificial cell constructed by one-pot self-assembly is designed to enables the enzyme to adopt an activated conformation with high activity and promotes the electron transport efficiency from the photo-antennas to FDH.
A semiartificial photosynthesis system containing a solid electron hyperchannel to cavity-confined enzymes with an activated conformation is constructed for enhanced photocatalytic CO2 reduction.
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
The PdIr nanoalloys with core–shell structure and Janus-structured PdAg nanoalloys exhibited the best FDR and FOR catalytic activity.
Heterogeneity benefits enzyme/MOF design. In this review, our perspective on the research challenges and future directions for biocatalytic CO2 conversion using MOF-based biocatalysts are discussed.