Photoinduced direct electron transfer between azauracils and cycloketone oxime esters for C–H cyanoalkylation through a transiently assembled chromophore activation was developed.
An innovative and eco-friendly method has been developed for synthesizing 6-arylated or 6-alkylated 1,2,4-triazine-3,5(2H,4H)-diones, utilizing a photoinduced cross-dehydrogenative coupling reaction with hydrazines.
Herein, we have developed an organophotocatalytic trifluoromethylation of 6-azauracils using inexpensive Langlois reagent to prepare a variety of trifluoromethylated azauracil derivatives under ambient air condition.
This study presents a gentle and effective decatungstate ([W10O32]4−)-photocatalyzed method for the hydroalkylation of azauracils using a wide range of primary, secondary, and tertiary unreactive C–H bonds of alkanes as the alkylating reagents.
Visible light-induced perfluoroalkylation of [1.1.1]propellane provides a sustainable way to incorporate perfluoroalkyl-substituted BCPs into various heterocycles.