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External ligand-free nickel-catalyzed atom-economical coupling of isatins with allyl alcohols via a redox-relay strategy

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Recent developments in nickel-catalyzed asymmetric cyclization and cycloaddition of carbonyl-alkynes, cyano-alkynes, and enynes

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Visible light induced deoxygenation of sulfoxides with isopropanol

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BIAN‐NHC Ligands in Transition‐Metal‐Catalysis: A Perfect Union of Sterically Encumbered, Electronically Tunable N‐Heterocyclic Carbenes?

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Enantioselective Synthesis of γ-Butyrolactones Bearing γ-Quaternary Stereocenters via Nickel-Catalyzed Reductive Coupling of Acrylates with Ketones

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Org. Lett., 2025, 27, 8059
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Nickel-Catalyzed Alkene–Imine Couplings via Nickelacycles

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Nickel-catalyzed hydrobivinylation of enones with 1,3-dienes

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Modular Synthesis of Chiral Tetrasubstituted Allylic Amines via Nickel-Catalyzed Enantioselective Difunctionalization of Alkynes with Imines and Arylboronic Acids

Xiruo Han, Xiaojuan Wang, Shuojia Li, Zhuojia Hou, Fang-Fang Feng, Haitao Yu and Yongbing Liu

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Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines

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Nat Commun, 2021, 12
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Integrating Fermentation Engineering and Organopalladium Chemocatalysis for the Production of Squalene from Biomass-Derived Carbohydrates as the Starting Material

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Catalysts, 2023, 13, 1392
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External-Ligand-Free, Nickel-Catalyzed Alkenylation of N-Sulfonylamines with Internal Alkynes

Jia-Yue Li, Lun Li, Yun-Zhi Lin and Hang Shi

Synthesis, 2022, 54, 3341
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Nickel-Catalyzed Intermolecular Reductive Coupling of Styrene and Its Derivatives with Imines Using Methanol as a Reductant

Biao Wang, Tianze Zhang, Li-Jun Xiao and Qi-Lin Zhou

ACS Catal., 2023, 13, 8692
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Nickel‐Catalyzed Domino Heck‐Type Reactions Using Methyl Esters as Cross‐Coupling Electrophiles

Yan‐Long Zheng and Stephen G. Newman

Angew Chem Int Ed, 2019, 58, 18159
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Regio‐ and enantioselective nickel-alkyl catalyzed hydroalkylation of alkynes

Qian Gao, Wei-Cheng Xu, Xuan Nie, Kang-Jie Bian, Hong-Rui Yuan, Wen Zhang, Bing-Bing Wu and Xi-Sheng Wang

Nat Commun, 2024, 15
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Catalytic Enantioselective Addition of Aromatic, Heteroaryl, and Alkenyl Halides to N-Boc and N-Cbz Aldimines: Entatic States in Transition Metal Catalysis

Xiuhua Wang, Bo Xiao, Tengfei Jiang, Jianchun Wang, Yonggui Robin Chi and Jianrong Steve Zhou

ACS Catal., 2026, 16, 6041
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Methanol-Mediated Nickel-Catalyzed Chemo- and Enantioselective Three-Component Alkenylative Coupling of Aldimines and Alkynes with Alkenyl Boronic Acids

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Synthesis of Indolo[2,1-a]isoquinolines by Nickel-Catalyzed Mizoroki–Heck/Amination Cascade Reaction

Chaoyi Wu, Jin Lin and Xu Tian

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Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Toolika Agrawal and Joshua D. Sieber

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Ni-catalyzed hydroaminoalkylation of alkynes with amines

Wei-Wei Yao, Ran Li, Hao Chen, Ming-Kai Chen, Yu-Xin Luan, Yi Wang, Zhi-Xiang Yu and Mengchun Ye

Nat Commun, 2021, 12
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Construction 7-membered ring via Ni–Al bimetal-enabled C–H cyclization for synthesis of tricyclic imidazoles

Jiang-Fei Li, Wei-Wei Xu, Rong-Hua Wang, Yue Li, Ge Yin and Mengchun Ye

Nat Commun, 2021, 12
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Nickel‐Catalyzed Reductive Coupling of Aldehydes with Alkynes Mediated by Alcohol†

Yan‐Long Zheng and Mengchun Ye

Chin. J. Chem., 2020, 38, 489
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Nickel-Catalyzed Enantioselective α-Alkenylation of N-Sulfonyl Amines: Modular Access to Chiral α-Branched Amines

Lun Li, Yu-Cheng Liu and Hang Shi

J. Am. Chem. Soc., 2021, 143, 4154
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Induced-Fit Chiral N-Heterocyclic Carbene Ligands for Asymmetric Catalysis

Zi-Chao Wang and Shi-Liang Shi

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Ni-Catalyzed (A + 2B)-Type Reductive Coupling of Electron-Deficient Alkenes and Alkynes through a Selective Trimerization/1,6-Reduction Cascade

Ming-Bai Gou, Deng-Yin Gou, Chun-Min Yang, Xing-Cui Wei, Bo Li, Jing Shi, Chong Zhao, Lei Tang and Rong-Hua Wang

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Acenaphthene-Based N-Heterocyclic Carbene Metal Complexes: Synthesis and Application in Catalysis

Paulina Baczewska, Katarzyna Śniady, Wioletta Kośnik and Michał Michalak

Catalysts, 2021, 11, 972
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Condensation of 4-Tert-butyl-2,6-dimethylbenzenesulfonamide with Glyoxal and Reaction Features: A New Process for Symmetric and Asymmetric Aromatic Sulfones

Artyom E. Paromov, Sergey V. Sysolyatin and Irina A. Shchurova

Molecules, 2022, 27, 7793
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Cobalt‐Catalyzed Regioselective Methylative Coupling of Internal Alkynes with Aldehydes/Aldimines

Jiwu Zhang, Zhikun Liang, Qinglei Chong and Fanke Meng

Chin. J. Chem., 2024, 42, 3248
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Nickel‐Catalyzed Domino Heck‐Type Reactions Using Methyl Esters as Cross‐Coupling Electrophiles

Yan‐Long Zheng and Stephen G. Newman

Angewandte Chemie, 2019, 131, 18327
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C2-Symmetric N-Heterocyclic Carbenes in Asymmetric Transition-Metal Catalysis

Chiara Costabile, Stefania Pragliola and Fabia Grisi

Symmetry, 2022, 14, 1615
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Nickel-Catalyzed Enantioselective Reductive Alkenylation of N-Pyridyl Aldimines via a Mechanism of Elementary 1,4-Addition

Mengxin Zhao, Bo Xiao, Lantian Sun and Jianrong Steve Zhou

Org. Lett., 2026, 28, 1720
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Cobalt‐Catalyzed Enantioselective Reductive Coupling of Imines and Internal Alkynes

Kakoli Maji, Angshuman Palai, Dibyendu Mallick and Biplab Maji

Angew Chem Int Ed, 2025, 64
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Catalytic Asymmetric Synthesis of Zinc Metallacycles

Hayden D. Bishop, Qiang Zhao and Christopher Uyeda

J. Am. Chem. Soc., 2023, 145, 20152
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Cobalt‐Catalyzed Enantioselective Reductive Coupling of Imines and Internal Alkynes

Kakoli Maji, Angshuman Palai, Dibyendu Mallick and Biplab Maji

Angewandte Chemie, 2025, 137
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