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Kinetics and thermodynamics of CO2 binding to a metal centre promotes CO2 reduction
Liliang Huang, Shuanglin He, Fang Huang, Ping Zhang, Ying Xiong, Rong Zhang, Fei Li and Lin Chen
Chem. Commun., 2025, 61, 11465
DOI: 10.1039/D5CC01007A

A look at periodic trends in d-block molecular electrocatalysts for CO2 reduction
Changcheng Jiang, Asa W. Nichols and Charles W. Machan
Dalton Trans., 2019, 48, 9454
DOI: 10.1039/C9DT00491B

Regulating nonmetallic species beyond the first coordination shell of single-atom catalysts for high-performance electrocatalysis
Wenpeng Ni, Houjun Chen, Junfeng Zeng, Yan Zhang, Hussein A. Younus, Zhouliangzi Zeng, Minyang Dai, Wei Zhang and Shiguo Zhang
Energy Environ. Sci., 2023, 16, 3679
DOI: 10.1039/D3EE02090H

A flexible cofacial Fe porphyrin dimer as an extremely efficient and selective electrocatalyst for the CO2 to CO conversion in non-aqueous and aqueous media
Eman A. Mohamed, Zaki N. Zahran and Yoshinori Naruta
J. Mater. Chem. A, 2021, 9, 18213
DOI: 10.1039/D1TA04176B

Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding
John J. Kiernicki, Emily E. Norwine, Myles A. Lovasz, Matthias Zeller and Nathaniel K. Szymczak
Chem. Commun., 2020, 56, 13105
DOI: 10.1039/D0CC05121G

Homogeneous catalysis of dioxygen reduction by molecular Mn complexes
Emma N. Cook and Charles W. Machan
Chem. Commun., 2022, 58, 11746
DOI: 10.1039/D2CC04628H

A local proton source from carboxylic acid functionalized metal porphyrins for enhanced electrocatalytic CO2 reduction
Yiwei Zhou, Yunheng Xiao and Jian Zhao
New J. Chem., 2020, 44, 16062
DOI: 10.1039/D0NJ02900A

Copper(ii) tetrakis(pentafluorophenyl)porphyrin: highly active copper-based molecular catalysts for electrochemical CO2 reduction
Kento Kosugi, Hina Kashima, Mio Kondo and Shigeyuki Masaoka
Chem. Commun., 2022, 58, 2975
DOI: 10.1039/D1CC05880K

Electrocatalysis with molecules and molecular assemblies within gas diffusion electrodes
Hossein Bemana, Morgan McKee and Nikolay Kornienko
Chem. Sci., 2023, 14, 13696
DOI: 10.1039/D3SC05362H

Rhenium bipyridine catalysts with hydrogen bonding pendant amines for CO2 reduction
Ashley N. Hellman, Ralf Haiges and Smaranda C. Marinescu
Dalton Trans., 2019, 48, 14251
DOI: 10.1039/C9DT02689D

Pre-equilibrium reactions involving pendent relays improve CO2 reduction mediated by molecular Cr-based electrocatalysts
Megan E. Moberg, Amelia G. Reid, Diane A. Dickie and Charles W. Machan
Dalton Trans., 2024, 53, 16849
DOI: 10.1039/D4DT01981D

Hydrogen-bonded nickel(i) complexes
Jessica R. Wilson, Matthias Zeller and Nathaniel K. Szymczak
Chem. Commun., 2021, 57, 753
DOI: 10.1039/D0CC07216H

Role of 2nd sphere H-bonding residues in tuning the kinetics of CO2 reduction to CO by iron porphyrin complexes
Pritha Sen, Biswajit Mondal, Dibyajyoti Saha, Atanu Rana and Abhishek Dey
Dalton Trans., 2019, 48, 5965
DOI: 10.1039/C8DT03850C

Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures
Philipp Gotico, Zakaria Halime and Ally Aukauloo
Dalton Trans., 2020, 49, 2381
DOI: 10.1039/C9DT04709C

Mechanistic insights of electrocatalytic CO2 reduction by Mn complexes: synergistic effects of the ligands
Haitao Sun, Xueqing Liu, Yafeng Li, Fang Zhang, Xiuxiu Huang, Chuanzhi Sun and Fang Huang
Dalton Trans., 2024, 53, 1663
DOI: 10.1039/D3DT03453D

Molecularly dispersed nickel complexes on N-doped graphene for electrochemical CO2reduction
Methasit Juthathan, Teera Chantarojsiri, Kittipong Chainok, Teera Butburee, Patchanita Thamyongkit, Thawatchai Tuntulani and Pannee Leeladee
Dalton Trans., 2023, 52, 11407
DOI: 10.1039/D3DT00878A

Evaluation of attractive interactions in the second coordination sphere of iron complexes containing pendant amines
Qian Liao, Tianbiao Liu, Samantha I. Johnson, Christina M. Klug, Eric S. Wiedner, R. Morris Bullock and Daniel L. DuBois
Dalton Trans., 2019, 48, 4867
DOI: 10.1039/C9DT00708C

Strategies for breaking molecular scaling relationships for the electrochemical CO2 reduction reaction
Weixuan Nie and Charles C. L. McCrory
Dalton Trans., 2022, 51, 6993
DOI: 10.1039/D2DT00333C

Electrocatalytic reduction of CO2 to CO by Fe(iii) carbazole–porphyrins in homogeneous molecular systems
Hai Sun, Jiahui Wu, Fengkun Tian, Guodong Zhang, Zixiang Xia, Jiaxin Rong, Jun-Sheng Qin and Heng Rao
Catal. Sci. Technol., 2024, 14, 660
DOI: 10.1039/D3CY01618H

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2ndsphere interactions in catalysis
Sk Amanullah, Paramita Saha, Abhijit Nayek, Md Estak Ahmed and Abhishek Dey
Chem. Soc. Rev., 2021, 50, 3755
DOI: 10.1039/D0CS01405B

Metal–ligand cooperativity in the soluble hydrogenase-1 fromPyrococcus furiosus
Gregory E. Vansuch, Chang-Hao Wu, Dominik K. Haja, Soshawn A. Blair, Bryant Chica, Michael K. Johnson, Michael W. W. Adams and R. Brian Dyer
Chem. Sci., 2020, 11, 8572
DOI: 10.1039/D0SC00628A

Beyond immobilization: critical roles of support materials in modulating heterogeneous molecular electrocatalysis
Xin Xu, Ye Zhou and Jiong Wang
Phys. Chem. Chem. Phys., 2025, 27, 20967
DOI: 10.1039/D5CP02584B

Molecular engineering of metalloporphyrins and phthalocyanines for homogeneous and heterogeneous CO2 electroreduction
Aakash Santra, Arnab Ghatak, Zhiyuan Chen, Jing Shen, Joost Helsen, Yuvraj Birdja, Ally Aukauloo and Chanjuan Zhang
Chem. Sci., 2026
DOI: 10.1039/D5SC07983G

A guide to secondary coordination sphere editing
Marcus W. Drover
Chem. Soc. Rev., 2022, 51, 1861
DOI: 10.1039/D2CS00022A

The impact of second coordination sphere functional group extension on product selectivity for manganese bipyridyl CO2 reduction electrocatalysts
Lisa Suntrup, Vanna Blasczak, Roonak Saeedi, Mehmed Z. Ertem and Jonathan Rochford
Dalton Trans., 2025, 54, 9494
DOI: 10.1039/D5DT00157A

Promoting selective electrochemical CO2 reduction under unconventionally acidic conditions through secondary coordination sphere positioning
Kaeden Teindl, Jolene P. Reid and Eva M. Nichols
Chem. Sci., 2025, 16, 19226
DOI: 10.1039/D5SC04700E

Beyond scaling relations in electrocatalysis: unifying concepts from molecular systems and metallic surfaces
Kirstine Nygaard Kolding, Kristian Torbensen and Alonso Rosas-Hernández
Chem. Sci., 2025, 16, 6136
DOI: 10.1039/D4SC07864K

Inverse potential scaling in co-electrocatalytic activity for CO2reduction through redox mediator tuning and catalyst design
Amelia G. Reid, Juan J. Moreno, Shelby L. Hooe, Kira R. Baugh, Isobel H. Thomas, Diane A. Dickie and Charles W. Machan
Chem. Sci., 2022, 13, 9595
DOI: 10.1039/D2SC03258A

Long-range electrostatic effects from intramolecular Lewis acid binding influence the redox properties of cobalt–porphyrin complexes
Jose L. Alvarez-Hernandez, Xiaowei Zhang, Kai Cui, Anthony P. Deziel, Sharon Hammes-Schiffer, Nilay Hazari, Nicole Piekut and Mingjiang Zhong
Chem. Sci., 2024, 15, 6800
DOI: 10.1039/D3SC06177A

Electrocatalytic syngas generation with a redox non-innocent cobalt 2-phosphinobenzenethiolate complex
Nicholas M. Orchanian, Lorena E. Hong, David A. Velazquez and Smaranda C. Marinescu
Dalton Trans., 2021, 50, 10779
DOI: 10.1039/D0DT03270K

Consistent inclusion of continuum solvation in energy decomposition analysis: theory and application to molecular CO2 reduction catalysts
Yuezhi Mao, Matthias Loipersberger, Kareesa J. Kron, Jeffrey S. Derrick, Christopher J. Chang, Shaama Mallikarjun Sharada and Martin Head-Gordon
Chem. Sci., 2021, 12, 1398
DOI: 10.1039/D0SC05327A

Bio-inspired benzimidazole-functionalized manganese terpyridine complexes for electrochemical CO2 reduction
Runqi Mo, Rui Li, Ping Zhang, Ying Xiong and Lin Chen
RSC Adv., 2025, 15, 25620
DOI: 10.1039/D5RA01621E

A secondary-sphere proton channel accelerating metal–hydride formation in Mn(i) catalysts for selective CO2-to-formate conversion
Min-Jong Bong, Wonjung Lee, Daehan Lee, Hyunuk Kim, Junhyeok Seo and Ho-Jin Son
Chem. Sci., 2026
DOI: 10.1039/D5SC09412G

Highly sensitive and low-power consumption metalloporphyrin-based junctions for COx detection with excellent recovery
Azar Ostovan, Nick Papior and S. Shahab Naghavi
Phys. Chem. Chem. Phys., 2022, 24, 14866
DOI: 10.1039/D2CP00408A

Ni(i)–TPA stabilization by hydrogen bond formation on the second coordination sphere: a DFT characterization
Sergio Posada-Pérez, Silvia Escayola, Jordi Poater, Miquel Solà and Albert Poater
Dalton Trans., 2022, 51, 12585
DOI: 10.1039/D2DT01355J

Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water
Asma Khadhraoui, Philipp Gotico, Bernard Boitrel, Winfried Leibl, Zakaria Halime and Ally Aukauloo
Chem. Commun., 2018, 54, 11630
DOI: 10.1039/C8CC06475J

Support-based modulation strategies in single-atom catalysts for electrochemical CO2 reduction: graphene and conjugated macrocyclic complexes
Zhanzhao Fu, Mingliang Wu, Yipeng Zhou, Zhiyang Lyu, Yixin Ouyang, Qiang Li and Jinlan Wang
J. Mater. Chem. A, 2022, 10, 5699
DOI: 10.1039/D1TA09069K

The meso-substituent electronic effect of Fe porphyrins on the electrocatalytic CO2 reduction reaction
Hongyuan He, Zi-Yang Qiu, Zhiyuan Yin, Jiafan Kong, Jing-Shuang Dang, Haitao Lei, Wei Zhang and Rui Cao
Chem. Commun., 2024, 60, 5916
DOI: 10.1039/D4CC01630K

Introducing proton/electron mediators enhances the catalytic ability of an iron porphyrin complex for photochemical CO2 reduction
Maho Imai, Kento Kosugi, Yutaka Saga, Mio Kondo and Shigeyuki Masaoka
Chem. Commun., 2023, 59, 10741
DOI: 10.1039/D3CC01862H

Second-sphere hydrogen-bonding enhances heterogeneous electrocatalytic CO2 to CO reduction by iron porphyrins in water
Chanjuan Zhang, Diana Dragoe, François Brisset, Bernard Boitrel, Benedikt Lassalle-Kaiser, Winfried Leibl, Zakaria Halime and Ally Aukauloo
Green Chem., 2021, 23, 8979
DOI: 10.1039/D1GC02546E

Reaction mechanism of the selective reduction of CO2 to CO by a tetraaza [CoIIN4H]2+ complex in the presence of protons
Alejandro J. Garza, Srimanta Pakhira, Alexis T. Bell, Jose L. Mendoza-Cortes and Martin Head-Gordon
Phys. Chem. Chem. Phys., 2018, 20, 24058
DOI: 10.1039/C8CP01963K

Effects of proton tunneling distance on CO2 reduction by Mn terpyridine species
Yuhang Qing, Qianqian Wu, Shuanglin He, Ping Zhang, Ying Xiong, Yaping Zhang, Fang Huang, Fei Li and Lin Chen
Dalton Trans., 2023, 52, 14309
DOI: 10.1039/D3DT02081A

Catalytic reduction of dinitrogen to ammonia using molybdenum porphyrin complexes
Alexander S. Hegg, Brandon Q. Mercado, Alexander J. M. Miller and Patrick L. Holland
Faraday Discuss., 2023, 243, 429
DOI: 10.1039/D2FD00166G

CO2 reduction to CO on an iron-porphyrin complex with crown-ether appended cation-binding site
Chengxu Zhu, Adarsh Koovakattil Surendran, Carmine D'Agostino, Jana Roithová and Sam P. de Visser
Dalton Trans., 2025, 54, 4918
DOI: 10.1039/D5DT00119F

Computational study on the reactivity of imidazolium-functionalized manganese bipyridyl tricarbonyl electrocatalysts [Mn[bpyMe(Im-R)](CO)3Br]+ (R = Me, Me2 and Me4) for CO2-to-CO conversion over H2 formation
Xiaohui Li and Julien A. Panetier
Phys. Chem. Chem. Phys., 2021, 23, 14940
DOI: 10.1039/D1CP01576A

Repurposing a supramolecular iridium catalyst via secondary Zn⋯OC weak interactions between the ligand and substrate leads to ortho-selective C(sp2)–H borylation of benzamides with unusual kinetics
Jonathan Trouvé, Vanessa Delahaye, Michele Tomasini, Purushothaman Rajeshwaran, Thierry Roisnel, Albert Poater and Rafael Gramage-Doria
Chem. Sci., 2024, 15, 11794
DOI: 10.1039/D4SC01515K

Transition metal-based catalysts for the electrochemical CO2reduction: from atoms and molecules to nanostructured materials
Federico Franco, Clara Rettenmaier, Hyo Sang Jeon and Beatriz Roldan Cuenya
Chem. Soc. Rev., 2020, 49, 6884
DOI: 10.1039/D0CS00835D

Recent developments in the synthesis of bio-inspired iron porphyrins for small molecule activation
Sk Amanullah, Paramita Saha and Abhishek Dey
Chem. Commun., 2022, 58, 5808
DOI: 10.1039/D2CC00430E

Mechanistic insights on CO2 fixation via electrochemical and photocatalytic reduction
Sawaira Altaf, Tanveer Hussain Bokhari and Muhammad Bilal
RSC Adv., 2025, 15, 36179
DOI: 10.1039/D5RA04681E

Synergism between iron porphyrin and dicationic ionic liquids: tandem CO2 electroreduction–carbonylation reactions
Roger Miró, Emma Fernández-Llamazares, Cyril Godard, Miriam Díaz de los Bernardos and Aitor Gual
Chem. Commun., 2022, 58, 10552
DOI: 10.1039/D2CC03641J

Peptidic Scaffolds Enable Rapid and Multivariate Secondary Sphere Evolution for an Abiotic Metallocatalyst
Sabari Ghosh, Phuong Nguyen Tran, Dan McElheny, Juan J. Perez and Andy I. Nguyen
Inorg. Chem., 2022, 61, 6679
DOI: 10.1021/acs.inorgchem.2c00901

Secondary Coordination Sphere Design to Modify Transport of Protons and CO2
Natalia D. Loewen and Louise A. Berben
Inorg. Chem., 2019, 58, 16849
DOI: 10.1021/acs.inorgchem.9b03102

Assembling CdSe Quantum Dots into Polymeric Micelles Formed by a Polyethylenimine-Based Amphiphilic Polymer to Enhance Efficiency and Selectivity of CO2-to-CO Photoreduction in Water
Jin Wu, Bo-Yi Deng, Jing Liu, Si-Rui Yang, Ming-De Li, Jing Li and Feng Wang
ACS Appl. Mater. Interfaces, 2022, 14, 29945
DOI: 10.1021/acsami.2c07656

From Biomimicking to Bioinspired Design of Electrocatalysts for CO2 Reduction to C1 Products
Panagiotis Trogadas, Linlin Xu and Marc‐Olivier Coppens
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202314446

RhI‐Catalyzed PIII‐Directed C−H Bond Alkylation: Design of Multifunctional Phosphines for Carboxylation of Aryl Bromides with Carbon Dioxide
Zhuan Zhang, Thierry Roisnel, Pierre H. Dixneuf and Jean‐François Soulé
Angewandte Chemie, 2019, 131, 14248
DOI: 10.1002/ange.201906913

Host–Guest Chemistry Meets Electrocatalysis: Cucurbit[6]uril on a Au Surface as a Hybrid System in CO2 Reduction
Andreas Wagner, Khoa H. Ly, Nina Heidary, István Szabó, Tamás Földes, Khaleel I. Assaf, Steven J. Barrow, Kamil Sokołowski, Mohamed Al-Hada, Nikolay Kornienko, Moritz F. Kuehnel, Edina Rosta, Ingo Zebger, Werner M. Nau, Oren A. Scherman and Erwin Reisner
ACS Catal., 2020, 10, 751
DOI: 10.1021/acscatal.9b04221

Pushing the Ag-loading of CO2 electrolyzers to the minimum via molecularly tuned environments
Kevinjeorjios Pellumbi, Dominik Krisch, Clara Rettenmaier, Houssein Awada, He Sun, Luyang Song, Sebastian A. Sanden, Lucas Hoof, Leonard Messing, Kai junge Puring, Daniel Siegmund, Beatriz Roldan Cuenya, Wolfgang Schöfberger and Ulf-Peter Apfel
Cell Reports Physical Science, 2023, 4, 101746
DOI: 10.1016/j.xcrp.2023.101746

Urea-Based Multipoint Hydrogen-Bond Donor Additive Promotes Electrochemical CO2 Reduction Catalyzed by Nickel Cyclam
Eva M. Nichols and Christopher J. Chang
Organometallics, 2019, 38, 1213
DOI: 10.1021/acs.organomet.8b00308

Multifunctional Charge and Hydrogen‐Bond Effects of Second‐Sphere Imidazolium Pendants Promote Capture and Electrochemical Reduction of CO2in Water Catalyzed by Iron Porphyrins**
Mina R. Narouz, Patricia De La Torre, Lun An and Christopher J. Chang
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202207666

Polymeric Unimolecular CO Dehydrogenase Mimic with both Inner and Outer Spheres for Enhanced Photocatalytic CO2 Reduction in Aqueous Solution
Haojie Dai, Rui Cui, Chuanshuang Chen, Jiatian Song, Jinghan Li, Lize Dong, Chunyang Yu, Wenfeng Jiang and Yongfeng Zhou
Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300879

Second‐Sphere Biomimetic Multipoint Hydrogen‐Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins
Philipp Gotico, Bernard Boitrel, Régis Guillot, Marie Sircoglou, Annamaria Quaranta, Zakaria Halime, Winfried Leibl and Ally Aukauloo
Angew Chem Int Ed, 2019, 58, 4504
DOI: 10.1002/anie.201814339

Boosting Electroreduction of CO2over Cationic Covalent Organic Frameworks: Hydrogen Bonding Effects of Halogen Ions
Qiu‐Jin Wu, Duan‐Hui Si, Qiao Wu, Yu‐Liang Dong, Rong Cao and Yuan‐Biao Huang
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202215687

How Do Amides Affect the Electronic Properties of Pyrene?
Eli M. Espinoza, John A. Clark, James B. Derr, Duoduo Bao, Boriana Georgieva, Frank H. Quina and Valentine I. Vullev
ACS Omega, 2018, 3, 12857
DOI: 10.1021/acsomega.8b01581

Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts
Ramato Ashu Tufa, Debabrata Chanda, Ming Ma, David Aili, Taye Beyene Demissie, Jan Vaes, Qingfeng Li, Shanhu Liu and Deepak Pant
Applied Energy, 2020, 277, 115557
DOI: 10.1016/j.apenergy.2020.115557

Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect
Jean‐Michel Savéant
Angewandte Chemie, 2019, 131, 2147
DOI: 10.1002/ange.201812375

Revealing a Decisive Role for Secondary Coordination Sphere Nucleophiles on Methane Activation
Mary E. Anderson, Benoît Braïda, Philippe C. Hiberty and Thomas R. Cundari
J. Am. Chem. Soc., 2020, 142, 3125
DOI: 10.1021/jacs.9b12644

An Iron Pyridyl-Carbene Electrocatalyst for Low Overpotential CO2Reduction to CO
Sergio Gonell, Julio Lloret-Fillol and Alexander J. M. Miller
ACS Catal., 2021, 11, 615
DOI: 10.1021/acscatal.0c03798

Engineering an Oxygen‐Binding Protein for Photocatalytic CO2Reductions in Water
Yunling Deng, Sudharsan Dwaraknath, Wenhao O. Ouyang, Cory J. Matsumoto, Stephanie Ouchida and Yi Lu
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202215719

Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization
Zhi‐Wen Yang, Jin‐Mei Chen, Li‐Qi Qiu, Wen‐Jun Xie and Liang‐Nian He
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205301

Intramolecular electrostatic effects on reduction of CO2 to CO by iron porphyrin complexes: Insights from DFT calculations
Yaqing Wang and Wenzhen Lai
Molecular Catalysis, 2024, 553, 113797
DOI: 10.1016/j.mcat.2023.113797

Molecular Electrochemical Mediator for Oxidative Multi-Site Proton Coupled Electron Transfer
Tarisha Gupta, Yati, Sanyam, Anirban Mondal and Biswajit Mondal
ACS Catal., 2024, 14, 17690
DOI: 10.1021/acscatal.4c05832

Standard Electrode Potentials for Electrochemical Hydrogen Production, Carbon Dioxide Reduction, and Oxygen Reduction Reactions in N,N-Dimethylacetamide
Yasuo Matsubara
Chem. Lett., 2020, 49, 915
DOI: 10.1246/cl.200220

Heterogeneous electrocatalytic reduction of carbon dioxide with transition metal complexes
Ariel Friedman and Lior Elbaz
Journal of Catalysis, 2021, 395, 23
DOI: 10.1016/j.jcat.2020.12.004

Unexpected Effect of Intramolecular Phenolic Group on Electrocatalytic CO2 Reduction
Kai Guo, Xialiang Li, Haitao Lei, Wei Zhang and Rui Cao
ChemCatChem, 2020, 12, 1591
DOI: 10.1002/cctc.201902034

CO binding at Iron porphyrins: Reflecting on Heme model complexes to guide future electrocatalyst design
Daelin Peel-Smith, Connor S. Durfy and Eva M. Nichols
Journal of Inorganic Biochemistry, 2026, 113326
DOI: 10.1016/j.jinorgbio.2026.113326

Recent Progress in (Photo-)-Electrochemical Conversion of CO2 With Metal Porphyrinoid-Systems
Dženeta Dedić, Adrian Dorniak, Uwe Rinner and Wolfgang Schöfberger
Front. Chem., 2021, 9
DOI: 10.3389/fchem.2021.685619

Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins
Jeffrey S. Derrick, Matthias Loipersberger, Sepand K. Nistanaki, Aila V. Rothweiler, Martin Head-Gordon, Eva M. Nichols and Christopher J. Chang
J. Am. Chem. Soc., 2022, 144, 11656
DOI: 10.1021/jacs.2c02972

Alkali metal cation effects on electrocatalytic CO2 reduction with iron porphyrins
Kai Guo, Haitao Lei, Xialiang Li, Zongyao Zhang, Yabo Wang, Hongbo Guo, Wei Zhang and Rui Cao
Chinese Journal of Catalysis, 2021, 42, 1439
DOI: 10.1016/S1872-2067(20)63762-7

Electrocatalytic CO2 Reduction with Re‐Based Spiro Bipyridine Complexes: Effects of the Local Proton in the Second Coordination Sphere†
Yong Yang, Ziyun Zhang, Zhenyu Zhang, Chao Tang, Xiaoyong Chang and Lele Duan
Chin. J. Chem., 2021, 39, 1281
DOI: 10.1002/cjoc.202000667

Multifunctional Charge and Hydrogen‐Bond Effects of Second‐Sphere Imidazolium Pendants Promote Capture and Electrochemical Reduction of CO2in Water Catalyzed by Iron Porphyrins**
Mina R. Narouz, Patricia De La Torre, Lun An and Christopher J. Chang
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202207666

Non-negligible Axial Ligand Effect on Electrocatalytic CO2 Reduction with Iron Porphyrin Complexes
Jiancong Zheng, Dexia Zhou, Jinxiu Han, Jing Liu, Rui Cao, Haitao Lei, Hongtao Bian and Yu Fang
J. Phys. Chem. Lett., 2022, 13, 11811
DOI: 10.1021/acs.jpclett.2c03235

Effects of Appended Poly(ethylene glycol) on Electrochemical CO2 Reduction by an Iron Porphyrin Complex
Ashwin Chaturvedi, Caroline K. Williams, Nilakshi Devi and Jianbing “Jimmy” Jiang
Inorg. Chem., 2021, 60, 3843
DOI: 10.1021/acs.inorgchem.0c03612

Reduction of CO2 to CO by an Iron Porphyrin Catalyst in the Presence of Oxygen
Biswajit Mondal, Pritha Sen, Atanu Rana, Dibyajyoti Saha, Purusottom Das and Abhishek Dey
ACS Catal., 2019, 9, 3895
DOI: 10.1021/acscatal.9b00529

Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction
Asa W. Nichols and Charles W. Machan
Front. Chem., 2019, 7
DOI: 10.3389/fchem.2019.00397

Redox-Active Ligand Assisted Multielectron Catalysis: A Case of Electrocatalyzed CO2-to-CO Conversion
Wen-Wen Yong, Hong-Tao Zhang, Yu-Hua Guo, Fei Xie and Ming-Tian Zhang
ACS Org. Inorg. Au, 2023, 3, 384
DOI: 10.1021/acsorginorgau.3c00027

Selective conversion of CO2 to C2H6 in pure water photocatalyzed by fluorobenzene-linked perylene diimide
Yin Xiao, Guixiang Ding, Jiayu Tao, Zhaoqiang Wang, Zihe Chen, Lihui Chen, Li Shuai and Guangfu Liao
Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-62369-7

Recent advances in the rational designing of metalloporphyrinoid-based CO2 reduction catalysts: From molecular structural tuning to the application in catalysis
Beatriu Domingo-Tafalla, Tamal Chatterjee and Emilio Palomares
J. Porphyrins Phthalocyanines, 2023, 27, 23
DOI: 10.1142/S1088424623300033

Boosting Electroreduction of CO2over Cationic Covalent Organic Frameworks: Hydrogen Bonding Effects of Halogen Ions
Qiu‐Jin Wu, Duan‐Hui Si, Qiao Wu, Yu‐Liang Dong, Rong Cao and Yuan‐Biao Huang
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202215687

Emerging opportunities with metal-organic framework electrosynthetic platforms
Kiran Kuruvinashetti, Junnan Li, Yuxuan Zhang, Hossein Bemana, Morgan McKee and Nikolay Kornienko
Chemical Physics Reviews, 2022, 3
DOI: 10.1063/5.0090147

Quick and Easy Method to Dramatically Improve the Electrochemical CO2 Reduction Activity of an Iron Porphyrin Complex
Kento Kosugi, Mio Kondo and Shigeyuki Masaoka
Angew Chem Int Ed, 2021, 60, 22070
DOI: 10.1002/anie.202110190

Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)–COOH Intermediate(s)
Sk Amanullah, Paramita Saha and Abhishek Dey
J. Am. Chem. Soc., 2021, 143, 13579
DOI: 10.1021/jacs.1c04392

The Pattern of Hydroxyphenyl-Substitution Influences CO2 Reduction More Strongly than the Number of Hydroxyphenyl Groups in Iron-Porphyrin Electrocatalysts
Ana Sonea, Kaitlin L. Branch and Jeffrey J. Warren
ACS Catal., 2023, 13, 3902
DOI: 10.1021/acscatal.2c06275

Selectivity in Electrochemical CO2 Reduction
Paramita Saha, Sk Amanullah and Abhishek Dey
Acc. Chem. Res., 2022, 55, 134
DOI: 10.1021/acs.accounts.1c00678

Catalytic CO2 Reduction with Heptacoordinated Polypyridine Complexes: Switching the Selectivity via Metal Replacement
Federico Droghetti, Agnese Amati, Fabien Pascale, Aurélien Crochet, Mariachiara Pastore, Albert Ruggi and Mirco Natali
ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202300737

Inspiration from Nature: Influence of Engineered Ligand Scaffolds and Auxiliary Factors on the Reactivity of Biomimetic Oxidants
Gourab Mukherjee, Jagnyesh K. Satpathy, Umesh K. Bagha, M. Qadri E. Mubarak, Chivukula V. Sastri and Sam P. de Visser
ACS Catal., 2021, 11, 9761
DOI: 10.1021/acscatal.1c01993

Axial Modification of Cobalt Complexes on Heterogeneous Surface with Enhanced Electron Transfer for Carbon Dioxide Reduction
Jiong Wang, Xiang Huang, Shibo Xi, Hu Xu and Xin Wang
Angewandte Chemie, 2020, 132, 19324
DOI: 10.1002/ange.202008759

Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction
Sarmistha Bhunia, Atanu Rana, Shabnam Hematian, Kenneth D. Karlin and Abhishek Dey
Inorg. Chem., 2021, 60, 13876
DOI: 10.1021/acs.inorgchem.1c01079

Heterogenization of Molecular Electrocatalytic Active Sites through Reticular Chemistry
Minseok Kim, Jaekyung Yi, Seong‐Hyeon Park and Sarah S. Park
Advanced Materials, 2023, 35
DOI: 10.1002/adma.202203791

Microenvironment modulation of amide-bonded Metalloporphyrins functionalized gold electrodes for accelerating Electrocatalyzed hydrogen evolutions
Yong Liu, Yue Wang, Ning Feng, Minzhi Li, Shakhola E. Sekeleme, John Mack, Tebello Nyokong, Xifeng Zhang, Weihua Zhu and Xu Liang
Molecular Catalysis, 2025, 582, 115173
DOI: 10.1016/j.mcat.2025.115173

Feinabstimmung der Redoxeigenschaften von heteroleptischen Molybdän‐Komplexen mittels Ligand‐Ligand‐Kooperativität
Benedict J. Elvers, Sebastian Pätsch, Siva S. M. Bandaru, Vera Krewald, Carola Schulzke and Christian Fischer
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202303151

Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization
Zhi‐Wen Yang, Jin‐Mei Chen, Li‐Qi Qiu, Wen‐Jun Xie and Liang‐Nian He
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205301

Metal-Organic framework catalysts: A versatile platform for bioinspired electrochemical conversion of carbon dioxide
Devina Thasia Wijaya and Chan Woo Lee
Chemical Engineering Journal, 2022, 446, 137311
DOI: 10.1016/j.cej.2022.137311

Controlled Potential Electrolysis: Transition from Fast to Slow Regimes in Homogeneous Molecular Catalysis. Application to the Electroreduction of CO2 Catalyzed by Iron Porphyrin
Rana Deeba, Alexandra Collard, Camille Rollin, Florian Molton, Sylvie Chardon‐Noblat and Cyrille Costentin
ChemElectroChem, 2023, 10
DOI: 10.1002/celc.202300350

Tuning Second Coordination Sphere Interactions in Polypyridyl–Iron Complexes to Achieve Selective Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide
David Z. Zee, Michael Nippe, Amanda E. King, Christopher J. Chang and Jeffrey R. Long
Inorg. Chem., 2020, 59, 5206
DOI: 10.1021/acs.inorgchem.0c00455

Cobalt(III) Corrolato Complexes with Tailored Secondary Spheres: Catalytic Implications for Water Oxidation
Subhajit Kar, Suman Maity, Rwiddhi Chakraborty, Sahanwaj Khan, Abhishek Saini, Tanmoy Pain, Arnab Dutta and Sanjib Kar
Inorg. Chem., 2026, 65, 2374
DOI: 10.1021/acs.inorgchem.5c05209

Polysaccharide/Fe(III)-porphyrin hybrid film as catalyst for oxidative decolorization of toxic azo dyes: An approach for wastewater treatment
Henrique P. Mota, Rafael F.N. Quadrado, Thiago A.L. Burgo, Bernardo A. Iglesias and André R. Fajardo
Arabian Journal of Chemistry, 2020, 13, 5923
DOI: 10.1016/j.arabjc.2020.04.021

Synthesis of Metal (Pd, Cu)/Nitrogen doped Asphalt Based Porous Carbon and Its Application for Electrochemical Carbon Dioxide Reduction
Xiaoli Zhu and Chusheng Wang
International Journal of Electrochemical Science, 2022, 17, 221141
DOI: 10.20964/2022.11.42

Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol
Poe Ei Phyu Win, Xin Xu, Lilong Zhang, Song Yang, Shibin Ren, Yu Chen and Jiong Wang
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202517033

Iron-Complex-Based Supramolecular Framework Catalyst for Visible-Light-Driven CO2Reduction
Kento Kosugi, Chiharu Akatsuka, Hikaru Iwami, Mio Kondo and Shigeyuki Masaoka
J. Am. Chem. Soc., 2023, 145, 10451
DOI: 10.1021/jacs.3c00783

Effects of Protonation State on Electrocatalytic CO2 Reduction by a Cobalt Aminopyridine Macrocyclic Complex
Jeffrey J. Liu, Alon Chapovetsky, Ralf Haiges and Smaranda C. Marinescu
Inorg. Chem., 2021, 60, 17517
DOI: 10.1021/acs.inorgchem.1c01977

Single-Ni Sites Embedded in Multilayer Nitrogen-Doped Graphene Derived from Amino-Functionalized MOF for Highly Selective CO2 Electroreduction
Haojing Wang, Guanyu Liu, Chunping Chen, Wenguang Tu, Yan Lu, Shuyang Wu, Dermot O’Hare and Rong Xu
ACS Sustainable Chem. Eng., 2021, 9, 3792
DOI: 10.1021/acssuschemeng.0c08749

Graphite Conjugation Eliminates Redox Intermediates in Molecular Electrocatalysis
Megan N. Jackson, Corey J. Kaminsky, Seokjoon Oh, Jonathan F. Melville and Yogesh Surendranath
J. Am. Chem. Soc., 2019, 141, 14160
DOI: 10.1021/jacs.9b04981

Double Hangman Iron Porphyrin and the Effect of Electrostatic Nonbonding Interactions on Carbon Dioxide Reduction
Charles G. Margarit, Naomi G. Asimow, Miguel I. Gonzalez and Daniel G. Nocera
J. Phys. Chem. Lett., 2020, 11, 1890
DOI: 10.1021/acs.jpclett.9b03897

Calix[8]arene‐Based Manganese Complexes for Electrocatalytic CO2 Reduction
Armando Berlanga‐Vázquez and Ivan Castillo
Israel Journal of Chemistry, 2024, 64
DOI: 10.1002/ijch.202300083

Porphyrin Aggregation under Homogeneous Conditions Inhibits Electrocatalysis: A Case Study on CO2 Reduction
Kaitlin L. Branch, Erin R. Johnson and Eva M. Nichols
ACS Cent. Sci., 2024, 10, 1251
DOI: 10.1021/acscentsci.4c00121

Molecular catalysts design: Intramolecular supporting site assisting to metal center for efficient CO2 photo- and electroreduction
Wu Xia and Feng Wang
Molecular Catalysis, 2023, 535, 112884
DOI: 10.1016/j.mcat.2022.112884

Through‐Space Electrostatic Interactions Surpass Classical Through‐Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins
Asma Khadhraoui, Philipp Gotico, Winfried Leibl, Zakaria Halime and Ally Aukauloo
ChemSusChem, 2021, 14, 1308
DOI: 10.1002/cssc.202002718

Metal–Organic Frameworks for Electrocatalytic CO2 Reduction: Developments and Prospects
Shae Patel, Kim McKelvey and Lujia Liu
Chem. Mater., 2024, 36, 10054
DOI: 10.1021/acs.chemmater.4c01137

Unified Benchmarking of Electrocatalysts in Noninnocent Second Coordination Spheres for CO2 Reduction
Yasuo Matsubara
ACS Energy Lett., 2019, 4, 1999
DOI: 10.1021/acsenergylett.9b01180

Second Coordination Sphere Effect Shifts CO2 to CO Reduction by Iron Porphyrin from Fe0 to FeI
Sk Amanullah, Philipp Gotico, Marie Sircoglou, Winfried Leibl, Manuel J. Llansola‐Portoles, Tania Tibiletti, Annamaria Quaranta, Zakaria Halime and Ally Aukauloo
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202314439

Selective CO2 Reduction by Bis(bipyridine)cobalt(II) Catalysts: The Role of Pendant Pyridine as a Proton Acceptor
Zhu-Lin Xie, Wenhui Hu, Nikita Gupta, Lars Kohler, Jens Niklas, Oleg G. Poluektov, Toby J. Woods, Peter Zapol, Amy A. Cordones, Ksenija D. Glusac and Karen L. Mulfort
ACS Catal., 2026, 16, 2293
DOI: 10.1021/acscatal.5c07052

Selective CO2 Electrochemical Reduction Enabled by a Tricomponent Copolymer Modifier on a Copper Surface
Jianchun Wang, Tao Cheng, Aidan Q. Fenwick, Turki N. Baroud, Alonso Rosas-Hernández, Jeong Hoon Ko, Quan Gan, William A. Goddard III and Robert H. Grubbs
J. Am. Chem. Soc., 2021, 143, 2857
DOI: 10.1021/jacs.0c12478

Computational Study of an Iron(II) Polypyridine Electrocatalyst for CO2 Reduction: Key Roles for Intramolecular Interactions in CO2 Binding and Proton Transfer
Matthias Loipersberger, David Z. Zee, Julien A. Panetier, Christopher J. Chang, Jeffrey R. Long and Martin Head-Gordon
Inorg. Chem., 2020, 59, 8146
DOI: 10.1021/acs.inorgchem.0c00454

Quick and Easy Method to Dramatically Improve the Electrochemical CO2 Reduction Activity of an Iron Porphyrin Complex
Kento Kosugi, Mio Kondo and Shigeyuki Masaoka
Angewandte Chemie, 2021, 133, 22241
DOI: 10.1002/ange.202110190

Highly Acidic Second Coordination Spheres Promote In Situ Formation of Iron Phlorins Exhibiting Fast and Selective CO2 Reduction
Kaeden Teindl, Daniel Jacobs, Julien A. Panetier and Eva M. Nichols
J. Am. Chem. Soc., 2026, 148, 809
DOI: 10.1021/jacs.5c16378

Investigation of Iron(III) Tetraphenylporphyrin as a Redox Flow Battery Anolyte: Unexpected Side Reactivity with the Electrolyte
Nathan H. Mitchell and Noémie Elgrishi
J. Phys. Chem. C, 2023, 127, 10938
DOI: 10.1021/acs.jpcc.3c01763

Enhanced Molecular CO2 Electroreduction Enabled by a Flexible Hydrophilic Channel for Relay Proton Shuttling
Caroline K. Williams, Amir Lashgari, Jingchao Chai and Jianbing “Jimmy” Jiang
ChemSusChem, 2020, 13, 3412
DOI: 10.1002/cssc.202001037

Understanding the role of negative charge in the scaffold of an artificial enzyme for CO2 hydrogenation on catalysis
Regina E. Trevino, Jack T. Fuller, Deseree J. Reid, Joseph A. Laureanti, Bojana Ginovska, John C. Linehan and Wendy J. Shaw
J Biol Inorg Chem, 2024, 29, 625
DOI: 10.1007/s00775-024-02070-0

Highly Efficient Photocatalytic Reduction of CO2 to CO by In Situ Formation of a Hybrid Catalytic System Based on Molecular Iron Quaterpyridine Covalently Linked to Carbon Nitride
Yue Wei, Lingjing Chen, Huan Chen, Lirong Cai, Guiping Tan, Yongfu Qiu, Quanjun Xiang, Gui Chen, Tai‐Chu Lau and Marc Robert
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202116832

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective
Niklas W. Kinzel, Christophe Werlé and Walter Leitner
Angew Chem Int Ed, 2021, 60, 11628
DOI: 10.1002/anie.202006988

Controlling the Oxygen Reduction Selectivity of Asymmetric Cobalt Porphyrins by Using Local Electrostatic Interactions
Rui Zhang and Jeffrey J. Warren
J. Am. Chem. Soc., 2020, 142, 13426
DOI: 10.1021/jacs.0c03861

Engineering an Oxygen‐Binding Protein for Photocatalytic CO2Reductions in Water
Yunling Deng, Sudharsan Dwaraknath, Wenhao O. Ouyang, Cory J. Matsumoto, Stephanie Ouchida and Yi Lu
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202215719

Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential
Adrien Smith, Philipp Gotico, Régis Guillot, Stéphane Le Gac, Winfried Leibl, Ally Aukauloo, Bernard Boitrel, Marie Sircoglou and Zakaria Halime
Advanced Science, 2025, 12
DOI: 10.1002/advs.202500482

Electronically Modified Cobalt Aminopyridine Complexes Reveal an Orthogonal Axis for Catalytic Optimization for CO2 Reduction
Alon Chapovetsky, Jeffrey J. Liu, Matthew Welborn, John M. Luna, Thomas Do, Ralf Haiges, Thomas F. Miller III and Smaranda C. Marinescu
Inorg. Chem., 2020, 59, 13709
DOI: 10.1021/acs.inorgchem.0c02086

Connecting Biological and Synthetic Approaches for Electrocatalytic CO2 Reduction
Samuel J. Cobb, Santiago Rodríguez‐Jiménez and Erwin Reisner
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202310547

Enhanced Electrocatalytic Activity of a Zinc Porphyrin for CO2 Reduction: Cooperative Effects of Triazole Units in the Second Coordination Sphere
Amir Lashgari, Caroline K. Williams, Jenna L. Glover, Yueshen Wu, Jingchao Chai and Jianbing “Jimmy” Jiang
Chemistry A European J, 2020, 26, 16774
DOI: 10.1002/chem.202002813

Low Overpotential CO2 Activation by a Graphite-Adsorbed Cobalt Porphyrin
Soumalya Sinha, Rui Zhang and Jeffrey J. Warren
ACS Catal., 2020, 10, 12284
DOI: 10.1021/acscatal.0c01367

Bimetallic Cooperativity and Hydrogen Bonding Allow Efficient Reduction of CO2
Abhishek Dey
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301760

Influence of Intermolecular Hydrogen Bonding Interactions on the Electrocatalytic Reduction of CO2 to CO by 6,6′‐Amine Substituted Rhenium Bipyridine Complexes
Ashley N. Hellman, Ralf Haiges and Smaranda C. Marinescu
ChemElectroChem, 2021, 8, 1864
DOI: 10.1002/celc.202100306

Methane Generation from CO2 with a Molecular Rhenium Catalyst
John K. Nganga, Lucienna M. Wolf, Kankana Mullick, Eric Reinheimer, Cesar Saucedo, Megan E. Wilson, Kyle A. Grice, Mehmed Z. Ertem and Alfredo M. Angeles-Boza
Inorg. Chem., 2021, 60, 3572
DOI: 10.1021/acs.inorgchem.0c02579

Iron porphyrin with appended guanidyl group for significantly improved electrocatalytic carbon dioxide reduction activity and selectivity in aqueous solutions
Hongbo Guo, Zuozhong Liang, Kai Guo, Haitao Lei, Yabo Wang, Wei Zhang and Rui Cao
Chinese Journal of Catalysis, 2022, 43, 3089
DOI: 10.1016/S1872-2067(21)63957-8

From Biomimicking to Bioinspired Design of Electrocatalysts for CO2 Reduction to C1 Products
Panagiotis Trogadas, Linlin Xu and Marc‐Olivier Coppens
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202314446

Are Amines the Holy Grail for Facilitating CO2 Reduction?
Joakim B. Jakobsen, Magnus H. Rønne, Kim Daasbjerg and Troels Skrydstrup
Angewandte Chemie, 2021, 133, 9258
DOI: 10.1002/ange.202014255

Are Amines the Holy Grail for Facilitating CO2 Reduction?
Joakim B. Jakobsen, Magnus H. Rønne, Kim Daasbjerg and Troels Skrydstrup
Angew Chem Int Ed, 2021, 60, 9174
DOI: 10.1002/anie.202014255

Reductively Stable Hydrogen-Bonding Ligands Featuring Appended CF2–H Units
James P. Shanahan, Danielle M. Mullis, Matthias Zeller and Nathaniel K. Szymczak
J. Am. Chem. Soc., 2020, 142, 8809
DOI: 10.1021/jacs.0c01718

Electrochemical Reduction of CO2 to CH3OH Catalyzed by an Iron Porphyrinoid
Paramita Saha, Sk Amanullah, Sudip Barman and Abhishek Dey
J. Am. Chem. Soc., 2025, 147, 1497
DOI: 10.1021/jacs.4c08922

Can the CO2 Reduction Reaction Be Improved on Cu: Selectivity and Intrinsic Activity of Functionalized Cu Surfaces
Oliver Christensen, Siqi Zhao, Zhaozong Sun, Alexander Bagger, Jeppe Vang Lauritsen, Steen Uttrup Pedersen, Kim Daasbjerg and Jan Rossmeisl
ACS Catal., 2022, 12, 15737
DOI: 10.1021/acscatal.2c04200

Switching Catalyst Selectivity via the Introduction of a Pendant Nitrophenyl Group
Eric M. Johnson, Jeffrey J. Liu, Adam D. Samuel, Ralf Haiges and Smaranda C. Marinescu
Inorg. Chem., 2022, 61, 1316
DOI: 10.1021/acs.inorgchem.1c02636

Axial Modification of Cobalt Complexes on Heterogeneous Surface with Enhanced Electron Transfer for Carbon Dioxide Reduction
Jiong Wang, Xiang Huang, Shibo Xi, Hu Xu and Xin Wang
Angew Chem Int Ed, 2020, 59, 19162
DOI: 10.1002/anie.202008759

Construction of secondary coordination sphere boosts electrochemical CO2 reduction of iron porphyrins
Guiyu Liu, Ying-Jie Fan and Jun-Long Zhang
J. Porphyrins Phthalocyanines, 2020, 24, 465
DOI: 10.1142/S1088424619501608

An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin
Peter T. Smith, Sophia Weng and Christopher J. Chang
Inorg. Chem., 2020, 59, 9270
DOI: 10.1021/acs.inorgchem.0c01162

Recent Developments in Metalloporphyrin Electrocatalysts for Reduction of Small Molecules: Strategies for Managing Electron and Proton Transfer Reactions
Rui Zhang and Jeffrey J. Warren
ChemSusChem, 2021, 14, 293
DOI: 10.1002/cssc.202001914

Electrocatalytic carbon dioxide reduction in acid
Junnan Li and Nikolay Kornienko
Chem Catalysis, 2022, 2, 29
DOI: 10.1016/j.checat.2021.10.016

Homogeneous Electrocatalytic CO2Reduction Using a Porphyrin Complex with Flexible Triazole Units in the Second Coordination Sphere
Nilakshi Devi, Caroline K. Williams, Ashwin Chaturvedi and Jianbing “Jimmy” Jiang
ACS Appl. Energy Mater., 2021, 4, 3604
DOI: 10.1021/acsaem.1c00027

CO2 Reduction by Transition‐Metal Complex Systems: Effect of Hydrogen Bonding on the Second Coordination Sphere
Xiang‐Ming Liang, Zhi‐Jun Ruan, Gui‐Quan Guo, Jun‐Qi Lin and Di‐Chang Zhong
ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202401394

Quantitative Structure–Electrochemistry Relationship (QSER) Studies on Metal–Amino–Porphyrins for the Rational Design of CO2 Reduction Catalysts
Furong Chen, Amphawan Wiriyarattanakul, Wanting Xie, Liyi Shi, Thanyada Rungrotmongkol, Rongrong Jia and Phornphimon Maitarad
Molecules, 2023, 28, 3105
DOI: 10.3390/molecules28073105

Electrochemical conversion of CO2 to C2 oxygenates on Pb(II)-salen catalysts-coated graphite electrodes: Role of salen ligand and appended ligand-substituents to the production
Paulomi Bose, Chandan Mukherjee and Animes Kumar Golder
Chemical Engineering Journal, 2022, 431, 134092
DOI: 10.1016/j.cej.2021.134092

Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect
Jean‐Michel Savéant
Angew Chem Int Ed, 2019, 58, 2125
DOI: 10.1002/anie.201812375

Connecting Biological and Synthetic Approaches for Electrocatalytic CO2 Reduction
Samuel J. Cobb, Santiago Rodríguez‐Jiménez and Erwin Reisner
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202310547

Synthesis and Electrocatalytic CO2 Reduction Activity of an Iron Porphyrin Complex Bearing a Hydroquinone Moiety
Kento Kosugi, Maho Imai, Mio Kondo and Shigeyuki Masaoka
Chemistry Letters, 2022, 51, 224
DOI: 10.1246/cl.210734

Ligand-Bound CO2 as a Nonclassical Route toward Efficient Photocatalytic CO2 Reduction with a Ni N-Confused Porphyrin
Huihong Yuan, Akash Krishna, Zhihe Wei, Yanhui Su, Jinzhou Chen, Wei Hua, Zhangyi Zheng, Daqi Song, Qiaoqiao Mu, Weiyi Pan, Long Xiao, Jin Yan, Guanna Li, Wenjun Yang, Zhao Deng and Yang Peng
J. Am. Chem. Soc., 2024, 146, 10550
DOI: 10.1021/jacs.3c14717

Proton Activation in the Presence of a Weak Acid Facilitated by Second Coordination Sphere Effects in Iron Porphyrins**
Anthony R. Ramuglia, Vishal Budhija, Khoa H. Ly, Matthias Schwalbe and Inez M. Weidinger
ChemElectroChem, 2023, 10
DOI: 10.1002/celc.202300369

Mechanistic Insights into Co and Fe Quaterpyridine-Based CO2 Reduction Catalysts: Metal–Ligand Orbital Interaction as the Key Driving Force for Distinct Pathways
Matthias Loipersberger, Delmar G. A. Cabral, Daniel B. K. Chu and Martin Head-Gordon
J. Am. Chem. Soc., 2021, 143, 744
DOI: 10.1021/jacs.0c09380

Investigation of the electrochemical behaviors of fibers containing new pyrazolo[5,1-c][1,2,4]triazine derivatives
Neslihan Nohut Maslakci, Esin Eren, Cigdem Dulgerbaki, Fati Yıldırım and Aysegul Uygun Oksuz
Polymer-Plastics Technology and Materials, 2023, 62, 877
DOI: 10.1080/25740881.2023.2169159

Design and Implementation of a CO2 Reduction Catalyst with an Internal Electron Transfer Mediator: Improving Turnover Frequency by More than 10-Fold
Bach Xuan Nguyen, Xiaohan Li and Jeffrey J. Warren
ACS Catal., 2024, 14, 12260
DOI: 10.1021/acscatal.4c01791

A Robust Hydrogel Embed A Hangman Porphyrin for Scalable Electrochemical Nitrate to Ammonia Conversion
Yuxuan Wei, Yan You, Xinjie Shen, Yingying Jin, Meilan Pan and Jiong Wang
Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202516637

Co(III), Co(II), Co(I): Tuning Single Cobalt Metal Atom Oxidation States in a 2D Coordination Network
Francesco Armillotta, Davide Bidoggia, Stefania Baronio, Alessandro Sala, Roberto Costantini, Martina dell'Angela, Iulia Cojocariu, Vitaliy Feyer, Alberto Morgante, Maria Peressi and Erik Vesselli
Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202408200

Hydrogen-Bonding Secondary Coordination Sphere Effect on CO2 Reduction
Anamarija Briš and Davor Margetić
Organics, 2023, 4, 277
DOI: 10.3390/org4020022

Atropisomeric Hydrogen Bonding Control for CO2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins
Philipp Gotico, Loïc Roupnel, Regis Guillot, Marie Sircoglou, Winfried Leibl, Zakaria Halime and Ally Aukauloo
Angew Chem Int Ed, 2020, 59, 22451
DOI: 10.1002/anie.202010859

Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide
Suman Patra, Sarmistha Bhunia, Soumili Ghosh and Abhishek Dey
ACS Catal., 2024, 14, 7299
DOI: 10.1021/acscatal.3c06112

Underevaluated Solvent Effects in Electrocatalytic CO2 Reduction by FeIII Chloride Tetrakis(pentafluorophenyl)porphyrin
Bin Zhao, Haitao Lei, Ni Wang, Gelun Xu, Wei Zhang and Rui Cao
Chemistry A European J, 2020, 26, 4007
DOI: 10.1002/chem.201903064

Bioinspiration in light harvesting and catalysis
Andrew H. Proppe, Yuguang C. Li, Alán Aspuru-Guzik, Curtis P. Berlinguette, Christopher J. Chang, Richard Cogdell, Abigail G. Doyle, Johannes Flick, Nathaniel M. Gabor, Rienk van Grondelle, Sharon Hammes-Schiffer, Shaffiq A. Jaffer, Shana O. Kelley, Mario Leclerc, Karl Leo, Thomas E. Mallouk, Prineha Narang, Gabriela S. Schlau-Cohen, Gregory D. Scholes, Aleksandra Vojvodic, Vivian Wing-Wah Yam, Jenny Y. Yang and Edward H. Sargent
Nat Rev Mater, 2020, 5, 828
DOI: 10.1038/s41578-020-0222-0

Linear Free Energy Relationships and Transition State Analysis of CO2 Reduction Catalysts Bearing Second Coordination Spheres with Tunable Acidity
Kaeden Teindl, Brian O. Patrick and Eva M. Nichols
J. Am. Chem. Soc., 2023, 145, 17176
DOI: 10.1021/jacs.3c03919

Electro‐ and Photochemical Reduction of CO2 by Molecular Manganese Catalysts: Exploring the Positional Effect of Second‐Sphere Hydrogen‐Bond Donors
Sayontani Sinha Roy, Kallol Talukdar and Jonah W. Jurss
ChemSusChem, 2021, 14, 662
DOI: 10.1002/cssc.202001940

Second Coordination Sphere Effect Shifts CO2 to CO Reduction by Iron Porphyrin from Fe0 to FeI
Sk Amanullah, Philipp Gotico, Marie Sircoglou, Winfried Leibl, Manuel J. Llansola‐Portoles, Tania Tibiletti, Annamaria Quaranta, Zakaria Halime and Ally Aukauloo
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202314439

Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction
Daniel J. Martin, Catherine F. Wise, Michael L. Pegis and James M. Mayer
Acc. Chem. Res., 2020, 53, 1056
DOI: 10.1021/acs.accounts.0c00044

Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic CO2Reduction**
Lun An, Patricia De La Torre, Peter T. Smith, Mina R. Narouz and Christopher J. Chang
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202209396

Experiment–Theory Synergy: Connecting the Kinetics of the Molecular Catalysis of Electrochemical Reactions with Calculated Energy Landscapes
Gabriel Durin and Cyrille Costentin
ACS Catal., 2025, 15, 2504
DOI: 10.1021/acscatal.4c06976

Alkali Metal Ion Tuning of a Crown Ether‐Appended Porphyrin for Electrocatalytic CO2 Reduction
Adarsh Koovakattil Surendran, Elija Veenman and Jana Roithová
Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400259

Enhanced Electrochemical CO2 Reduction by a Series of Molecular Rhenium Catalysts Decorated with Second-Sphere Hydrogen-Bond Donors
Kallol Talukdar, Sayontani Sinha Roy, Eva Amatya, Elizabeth A. Sleeper, Pierre Le Magueres and Jonah W. Jurss
Inorg. Chem., 2020, 59, 6087
DOI: 10.1021/acs.inorgchem.0c00154

Mechanistic insight into electrocatalytic CO2 reduction to formate by the iron(I) porphyrin complex: A DFT study
Yaqing Wang and Wenzhen Lai
Molecular Catalysis, 2024, 566, 114430
DOI: 10.1016/j.mcat.2024.114430

Carbon Dioxide Reduction by Iron Hangman Porphyrins
Charles G. Margarit, Christoph Schnedermann, Naomi G. Asimow and Daniel G. Nocera
Organometallics, 2019, 38, 1219
DOI: 10.1021/acs.organomet.8b00334

Redox Mediators in Homogeneous Co-electrocatalysis
Amelia G. Reid and Charles W. Machan
J. Am. Chem. Soc., 2023, 145, 2013
DOI: 10.1021/jacs.2c10033

Cyano‐Capped Porphyrins Embedded With First‐Row Transition Metals and Evaluation for Electrocatalytic Syngas Production
Inderpal Yadav, Adrien Smith, Naba Abuhafez, Zakaria Halime and Rafael Gramage‐Doria
ChemistrySelect, 2026, 11
DOI: 10.1002/slct.202507497

Unexpected Solvent Effect in Electrocatalytic CO2 to CO Conversion Revealed Using Asymmetric Metalloporphyrins
Soumalya Sinha and Jeffrey J. Warren
Inorg. Chem., 2018, 57, 12650
DOI: 10.1021/acs.inorgchem.8b01814

Highly selective and efficient electroreduction of CO2 in water by quaterpyridine derivative‐based molecular catalyst noncovalently tethered to carbon nanotubes
Vikas Reddu, Libo Sun, Xiaogang Li, Huile Jin, Shun Wang and Xin Wang
SmartMat, 2022, 3, 151
DOI: 10.1002/smm2.1081

Polymer-encapsulated metal complex catalysts: An emerging and efficient platform for electrochemical CO2 reduction
Yingshuo Liu, Shuaishuai Lyu, Fuli Wen, Weixuan Nie and Shuqing Wang
Journal of Materials Science & Technology, 2024, 172, 33
DOI: 10.1016/j.jmst.2023.08.002

Tertiary Amine-Assisted Electroreduction of Carbon Dioxide to Formate Catalyzed by Iron Tetraphenylporphyrin
Charles G. Margarit, Naomi G. Asimow, Cyrille Costentin and Daniel G. Nocera
ACS Energy Lett., 2020, 5, 72
DOI: 10.1021/acsenergylett.9b02093

All Four Atropisomers of Iron Tetra(o-N,N,N-trimethylanilinium)porphyrin in Both the Ferric and Ferrous States
Daniel J. Martin, Brandon Q. Mercado and James M. Mayer
Inorg. Chem., 2021, 60, 5240
DOI: 10.1021/acs.inorgchem.1c00236

Bioinspired iron porphyrins with appended poly-pyridine/amine units for boosted electrocatalytic CO2 reduction reaction
Jinxiu Han, Ni Wang, Xialiang Li, Haitao Lei, Yabo Wang, Hongbo Guo, Xiaotong Jin, Qingxin Zhang, Xinyang Peng, Xue-Peng Zhang, Wei Zhang, Ulf-Peter Apfel and Rui Cao
eScience, 2022, 2, 623
DOI: 10.1016/j.esci.2022.06.003

Selective Convergence to Atropisomers of a Porphyrin Derivative Having Bulky Substituents at the Periphery
Tomoya Ishizuka, Shogo Tanaka, Sayaka Uchida, Lianyu Wei and Takahiko Kojima
J. Org. Chem., 2020, 85, 12856
DOI: 10.1021/acs.joc.0c01876

Secondary Coordination Effect on Monobipyridyl Ru(II) Catalysts in Photochemical CO2 Reduction: Effective Proton Shuttle of Pendant Brønsted Acid/Base Sites (OH and N(CH3)2) and Its Mechanistic Investigation
Changhyun Back, Yunjeong Seo, Sunghan Choi, Min Su Choe, Daehan Lee, Jin-Ook Baeg, Ho-Jin Son and Sang Ook Kang
Inorg. Chem., 2021, 60, 14151
DOI: 10.1021/acs.inorgchem.1c01559

Corrolato(oxo)antimony(V) Dimer with Hydrogen-Bond Donor Groups in Secondary Coordination Sphere as a Catalyst for Hydrogen Evolution Reaction
Rwiddhi Chakraborty, Belarani Ojha, Tanmoy Pain, Tilahun Wubalem Tsega, Arup Tarai, Narayan Ch Jana, Chen-Hsiung Hung and Sanjib Kar
Inorg. Chem., 2024, 63, 21462
DOI: 10.1021/acs.inorgchem.4c03442

Computational Modeling of Electrocatalysts for CO2 Reduction: Probing the Role of Primary, Secondary, and Outer Coordination Spheres
Christina M. Zeng and Julien A. Panetier
Acc. Chem. Res., 2025, 58, 342
DOI: 10.1021/acs.accounts.4c00631

Proton Tunneling Distances for Metal Hydrides Formation Manage the Selectivity of Electrochemical CO2 Reduction Reaction
Shuanglin He, Yuhang Qing, Ping Zhang, Ying Xiong, Qianqian Wu, Yaping Zhang, Lin Chen, Fang Huang and Fei Li
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202216082

A Bio‐Inspired Bimetallic Fe−M Catalyst for Electro‐ and Photochemical CO2 Reduction
Yuhang Yao, Jia‐Hui Wu, Guiyu Liu, Ruijing Zhang, Zi‐Shu Yang, Song Gao, Tai‐Chu Lau and Jun‐Long Zhang
ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301705

Bimetallic Cooperativity and Hydrogen Bonding Allow Efficient Reduction of CO2
Abhishek Dey
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301760

Enhanced Electrochemical Reduction of CO2 to CO upon Immobilization onto Carbon Nanotubes Using an Iron‐Porphyrin Dimer
Maryam Abdinejad, Caitlin Dao, Billy Deng, Maegan E. Sweeney, Fabian Dielmann, Xiao‐an Zhang and Heinz Bernhard Kraatz
ChemistrySelect, 2020, 5, 979
DOI: 10.1002/slct.201904580

Enhanced CO2 Electroreduction Through Electrostatic Functionalization of Iron Porphyrin
Adrien Smith, Zakaria Halime, Christian Herrero and Ally Aukauloo
ChemCatChem, 2026, 18
DOI: 10.1002/cctc.202501217

RhI‐Catalyzed PIII‐Directed C−H Bond Alkylation: Design of Multifunctional Phosphines for Carboxylation of Aryl Bromides with Carbon Dioxide
Zhuan Zhang, Thierry Roisnel, Pierre H. Dixneuf and Jean‐François Soulé
Angew Chem Int Ed, 2019, 58, 14110
DOI: 10.1002/anie.201906913

Function Provision to Fe–Porphyrin Complexes for CO2 Reduction
Maho Imai, Shigeyuki Masaoka and Mio Kondo
JACS Au, 2025, 5, 3716
DOI: 10.1021/jacsau.5c00564

Artificial photosynthesis with metal and covalent organic frameworks (MOFs and COFs): challenges and prospects in fuel‐forming electrocatalysis
Nina Heidary, Tomos G.A.A. Harris, Khoa H. Ly and Nikolay Kornienko
Physiologia Plantarum, 2019, 166, 460
DOI: 10.1111/ppl.12935

Redox Mediated Molecular Chemical Catalysis of Electrochemical Reactions: A Co-Catalytic Boosting Effect in CO2 Electroreduction Catalyzed by an Iron Porphyrin
Catherine M. Harvey and Cyrille Costentin
ACS Catal., 2025, 15, 14927
DOI: 10.1021/acscatal.5c03381

Asymmetric Porphyrinoids with Proton and Electron Relays Immobilized on Carbon Materials as Efficient Catalysts for Electrochemical CO2 Reduction
Kharu Nisa, Ishfaq Ahmad Lone, Waseem Arif, AttaUllah Kaleem, Shive M. S. Chauhan and Ravi Kumar
ACS Appl. Energy Mater., 2026
DOI: 10.1021/acsaem.6c00259

Metal–Ligand Cooperativity via Exchange Coupling Promotes Iron- Catalyzed Electrochemical CO2 Reduction at Low Overpotentials
Jeffrey S. Derrick, Matthias Loipersberger, Ruchira Chatterjee, Diana A. Iovan, Peter T. Smith, Khetpakorn Chakarawet, Junko Yano, Jeffrey R. Long, Martin Head-Gordon and Christopher J. Chang
J. Am. Chem. Soc., 2020, 142, 20489
DOI: 10.1021/jacs.0c10664

Applicability of conventional protocols for benchmarking of unidirectional and bidirectional multi-electron homogeneous molecular catalysts beyond the pure kinetic regime
A. Molina, J. González and E. Laborda
Electrochimica Acta, 2022, 428, 140934
DOI: 10.1016/j.electacta.2022.140934

Graphite-Conjugated Acids Reveal a Molecular Framework for Proton-Coupled Electron Transfer at Electrode Surfaces
Megan N. Jackson, Michael L. Pegis and Yogesh Surendranath
ACS Cent. Sci., 2019, 5, 831
DOI: 10.1021/acscentsci.9b00114

Spiro-linked hanging group cobalt phthalocyanine for CO2-to-methanol electrocatalysis unveiled by grand canonical density functional theory
Beibei Tang, Chao Ma, Zhiyuan Xu and Qi Zhang
Molecular Catalysis, 2025, 570, 114689
DOI: 10.1016/j.mcat.2024.114689

Porosity as a Design Element for Developing Catalytic Molecular Materials for Electrochemical and Photochemical Carbon Dioxide Reduction
Patricia De La Torre, Lun An and Christopher J. Chang
Advanced Materials, 2023, 35
DOI: 10.1002/adma.202302122

Electrochemical CO2 Reduction by Urea Hangman Mn Terpyridine species
Minghong Li, Fang Huang, Ping Zhang, Ying Xiong, Yaping Zhang, Fei Li and Lin Chen
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304218

Hybrid Catalysts for Artificial Photosynthesis: Merging Approaches from Molecular, Materials, and Biological Catalysis
Peter T. Smith, Eva M. Nichols, Zhi Cao and Christopher J. Chang
Acc. Chem. Res., 2020, 53, 575
DOI: 10.1021/acs.accounts.9b00619

Highly Efficient Photocatalytic Reduction of CO2 to CO by In Situ Formation of a Hybrid Catalytic System Based on Molecular Iron Quaterpyridine Covalently Linked to Carbon Nitride
Yue Wei, Lingjing Chen, Huan Chen, Lirong Cai, Guiping Tan, Yongfu Qiu, Quanjun Xiang, Gui Chen, Tai‐Chu Lau and Marc Robert
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202116832

Multiconfiguration Pair-Density Functional Theory Calculations of Iron(II) Porphyrin: Effects of Hybrid Pair-Density Functionals and Expanded RAS and DMRG Active Spaces on Spin-State Orderings
Gautam D. Stroscio, Chen Zhou, Donald G. Truhlar and Laura Gagliardi
J. Phys. Chem. A, 2022, 126, 3957
DOI: 10.1021/acs.jpca.2c02347

The Effect of Exogenous Acid Identity on Iron Tetraphenylporphyrin-Catalyzed CO2 Reduction
Kaeden Teindl and Eva M. Nichols
Inorg. Chem., 2026, 65, 5339
DOI: 10.1021/acs.inorgchem.5c05122

Electrocatalysis in CO2-Binding Organic Liquids with an Iron Porphyrin
Sophie B. Rubashkin, Manh-Thuong Nguyen, Ying Chen, Deepika Malhotra, Aaron M. Appel and Eric S. Wiedner
ACS Electrochem., 2025, 1, 689
DOI: 10.1021/acselectrochem.4c00170

Enhancing Electrochemical CO2 Reduction via Redox Non‐Innocent Spheres in Copper‐Coordinated Covalent Organic Frameworks
Chang Liu, Yunxuan Ding, Yilong Zhao, Hao Yang, Tao Song, Peili Zhang, Fei Li, Licheng Sun and Fusheng Li
Small, 2025, 21
DOI: 10.1002/smll.202409932

Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction
Siyoung Sung, Xiaohui Li, Lucienna M. Wolf, Jeremy R. Meeder, Nattamai S. Bhuvanesh, Kyle A. Grice, Julien A. Panetier and Michael Nippe
J. Am. Chem. Soc., 2019, 141, 6569
DOI: 10.1021/jacs.8b13657

Pendent Relay Enhances H2O2Selectivity during Dioxygen Reduction Mediated by Bipyridine-Based Co–N2O2Complexes
Asa W. Nichols, Emma N. Cook, Yunqiao J. Gan, Peter R. Miedaner, Julia M. Dressel, Diane A. Dickie, Hannah S. Shafaat and Charles W. Machan
J. Am. Chem. Soc., 2021, 143, 13065
DOI: 10.1021/jacs.1c03381

Understanding the Interplay of the Brønsted Acidity of Catalyst Ancillary Groups and the Solution Components in Iron-porphyrin-Mediated Carbon Dioxide Reduction
Ana Sonea, Nicholas R. Crudo and Jeffrey J. Warren
J. Am. Chem. Soc., 2024, 146, 3721
DOI: 10.1021/jacs.3c10127

A Survey of Reaction Energetics for Diverse Small Molecule Activation: Where Do Molecular Electrocatalysts Go From Here?
Ana Sonea and Jeffrey J. Warren
ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400517

Atropisomeric Effects of Second Coordination Spheres on Electrocatalytic CO2 Reduction
Caroline K. Williams, Amir Lashgari, Jenny A. Tomb, Jingchao Chai and Jianbing Jimmy Jiang
ChemCatChem, 2020, 12, 4886
DOI: 10.1002/cctc.202000909

Fine‐Tuning Redox Properties of Heteroleptic Molybdenum Complexes through Ligand‐Ligand‐Cooperativity
Benedict J. Elvers, Sebastian Pätsch, Siva S. M. Bandaru, Vera Krewald, Carola Schulzke and Christian Fischer
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202303151

Role‐Specialized Division of Labor in CO2Reduction with Doubly‐Functionalized Iron Porphyrin Atropisomers
Kai Guo, Xialiang Li, Haitao Lei, Hongbo Guo, Xiaotong Jin, Xue‐Peng Zhang, Wei Zhang, Ulf‐Peter Apfel and Rui Cao
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202209602

An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects
Anthony R. Ramuglia, Vishal Budhija, Khoa H. Ly, Michael Marquardt, Matthias Schwalbe and Inez M. Weidinger
ChemCatChem, 2021, 13, 3934
DOI: 10.1002/cctc.202100625

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Kristian E. Dalle, Julien Warnan, Jane J. Leung, Bertrand Reuillard, Isabell S. Karmel and Erwin Reisner
Chem. Rev., 2019, 119, 2752
DOI: 10.1021/acs.chemrev.8b00392

CO2 Reduction on an Iron-Porphyrin Center: A Computational Study
Paul A. Davethu and Sam P. de Visser
J. Phys. Chem. A, 2019, 123, 6527
DOI: 10.1021/acs.jpca.9b05102

Structural tuning of heterogeneous molecular catalysts for electrochemical energy conversion
Jiong Wang, Shuo Dou and Xin Wang
Sci. Adv., 2021, 7
DOI: 10.1126/sciadv.abf3989

A Supramolecular Porous Organic Cage Platform Promotes Electrochemical Hydrogen Evolution from Water Catalyzed by Cobalt Porphyrins
Peter T. Smith, Bahiru Punja Benke, Lun An, Younghoon Kim, Kimoon Kim and Christopher J. Chang
ChemElectroChem, 2021, 8, 1653
DOI: 10.1002/celc.202100331

Übergangsmetallkomplexe als Katalysatoren für die elektrische Umwandlung von CO2 – eine metallorganische Perspektive
Niklas W. Kinzel, Christophe Werlé and Walter Leitner
Angewandte Chemie, 2021, 133, 11732
DOI: 10.1002/ange.202006988

Mechanism of CO2 Electroreduction to Multicarbon Products over Iron Phthalocyanine Single-Atom Catalysts
Reza Khakpour, Kaveh Farshadfar, Si-Thanh Dong, Benedikt Lassalle-Kaiser, Kari Laasonen and Michael Busch
J. Phys. Chem. C, 2024, 128, 5867
DOI: 10.1021/acs.jpcc.3c08347

Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol
Poe Ei Phyu Win, Xin Xu, Lilong Zhang, Song Yang, Shibin Ren, Yu Chen and Jiong Wang
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202517033

Integrated Capture and Electrocatalytic Conversion of CO2: A Molecular Electrocatalysts Perspective
Neha Gupta and Sudipta Chatterjee
Chemistry — An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401611

Electrocatalytic Reduction of CO2 to CO by Molecular Cobalt–Polypyridine Diamine Complexes
Yong Yang, Fang Xie, Jiahui Chen, Si Qiu, Na Qiang, Ming Lu, Zhongli Peng, Jing Yang and Guocong Liu
Molecules, 2024, 29, 1694
DOI: 10.3390/molecules29081694

Enhancing photocatalytic CO2-to-CO conversion by iron complexes through 8-hydroxyquinoline ligand regulation
Zhichao Xu, Xin Huang, Liyan Zhang, Duojun Cao, Dongdong Liu and Guozan Yuan
Journal of Molecular Structure, 2025, 1335, 142039
DOI: 10.1016/j.molstruc.2025.142039

Design and Optimization of Catalysts Based on Mechanistic Insights Derived from Quantum Chemical Reaction Modeling
Seihwan Ahn, Mannkyu Hong, Mahesh Sundararajan, Daniel H. Ess and Mu-Hyun Baik
Chem. Rev., 2019, 119, 6509
DOI: 10.1021/acs.chemrev.9b00073

CO2 Reduction on a Manganese‐Porphyrin System. How Does Manganese Compare to Iron?
Chengxu Zhu, Peter Pio Marcel James Jerald, Chivukula V. Sastri and Sam P. de Visser
Zeitschrift anorg allge chemie, 2025, 651
DOI: 10.1002/zaac.202500073

Role‐Specialized Division of Labor in CO2Reduction with Doubly‐Functionalized Iron Porphyrin Atropisomers
Kai Guo, Xialiang Li, Haitao Lei, Hongbo Guo, Xiaotong Jin, Xue‐Peng Zhang, Wei Zhang, Ulf‐Peter Apfel and Rui Cao
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202209602

Chemical Versatility of [FeFe]-Hydrogenase Models: Distinctive Activity of [μ-C6H4-1,2-(κ2-S)2][Fe2(CO)6] for Electrocatalytic CO2 Reduction
Minglun Cheng, Yang Yu, Xin Zhou, Yi Luo and Mei Wang
ACS Catal., 2019, 9, 768
DOI: 10.1021/acscatal.8b03921

Atropisomeric Hydrogen Bonding Control for CO2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins
Philipp Gotico, Loïc Roupnel, Regis Guillot, Marie Sircoglou, Winfried Leibl, Zakaria Halime and Ally Aukauloo
Angewandte Chemie, 2020, 132, 22637
DOI: 10.1002/ange.202010859

Advances in the electrochemical catalytic reduction of CO2 with metal complexes
Federico Franco, Sergio Fernández and Julio Lloret-Fillol
Current Opinion in Electrochemistry, 2019, 15, 109
DOI: 10.1016/j.coelec.2019.04.002

Quantum Dot-Sensitized Photoreduction of CO2 in Water with Turnover Number > 80,000
Francesca Arcudi, Luka Đorđević, Benjamin Nagasing, Samuel I. Stupp and Emily A. Weiss
J. Am. Chem. Soc., 2021, 143, 18131
DOI: 10.1021/jacs.1c06961

Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic CO2Reduction**
Lun An, Patricia De La Torre, Peter T. Smith, Mina R. Narouz and Christopher J. Chang
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202209396

Fast Catalysis at Low Overpotential: Designing Efficient Dicationic Re(bpy2+)(CO)3I Electrocatalysts for CO2 Reduction
Laura Rotundo, Shahbaz Ahmad, Chiara Cappuccino, Adam J. Pearce, Hannah Nedzbala, Samuel R. Bottum, James M. Mayer, James F. Cahoon, David C. Grills, Mehmed Z. Ertem and Gerald F. Manbeck
J. Am. Chem. Soc., 2024, 146, 24742
DOI: 10.1021/jacs.4c08084

Pendant Catechol Group Improves the Performance of Iron Porphyrin CO2 Reduction Catalysts
Ana Sonea and Jeffrey J. Warren
ACS Catal., 2025, 15, 1444
DOI: 10.1021/acscatal.4c05531

Proton Tunneling Distances for Metal Hydrides Formation Manage the Selectivity of Electrochemical CO2 Reduction Reaction
Shuanglin He, Yuhang Qing, Ping Zhang, Ying Xiong, Qianqian Wu, Yaping Zhang, Lin Chen, Fang Huang and Fei Li
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202216082

Noncovalent Construction of Hangman Cobalt Phthalocyanine for Enhanced Electrochemical Carbon Dioxide Reduction
Ye Zhou, Xiaoyue Duan, Xin Xu, Poe Ei Phyu Win, Shi-Bin Ren and Jiong Wang
Chem. Mater., 2025, 37, 360
DOI: 10.1021/acs.chemmater.4c02697

CO2 Reduction by an Iron(I) Porphyrinate System: Effect of Hydrogen Bonding on the Second Coordination Sphere
Chengxu Zhu, Carmine D’Agostino and Sam P. de Visser
Inorg. Chem., 2024, 63, 4474
DOI: 10.1021/acs.inorgchem.3c04246

Second sphere control of CO2 reduction selectivity by iron porphyrins: The role of spin state
Suman Patra, Soumili Ghosh, Soumya Samanta, Abhijit Nayek and Abhishek Dey
Journal of Organometallic Chemistry, 2025, 1023, 123439
DOI: 10.1016/j.jorganchem.2024.123439

Second‐Sphere Biomimetic Multipoint Hydrogen‐Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins
Philipp Gotico, Bernard Boitrel, Régis Guillot, Marie Sircoglou, Annamaria Quaranta, Zakaria Halime, Winfried Leibl and Ally Aukauloo
Angewandte Chemie, 2019, 131, 4552
DOI: 10.1002/ange.201814339

Force Decomposition Analysis: A Method to Decompose Intermolecular Forces into Physically Relevant Component Contributions
Abdulrahman Aldossary, Martí Gimferrer, Yuezhi Mao, Hongxia Hao, Akshaya K. Das, Pedro Salvador, Teresa Head-Gordon and Martin Head-Gordon
J. Phys. Chem. A, 2023, 127, 1760
DOI: 10.1021/acs.jpca.2c08061

Contemporary Strategies for Immobilizing Metallophthalocyanines for Electrochemical Transformations of Carbon Dioxide
Scheryn E. Lawson, Daniel B. Leznoff and Jeffrey J. Warren
Molecules, 2023, 28, 5878
DOI: 10.3390/molecules28155878