A mechanism review of metal phthalocyanines as single-atomic catalysts in electrochemical energy conversion

Zikang Li, Ziqi Zhou, Mingzi Sun, Tong Wu, Qiuyang Lu, Lu Lu, Baian Chen, Cheuk Hei Chan, Hon Ho Wong and Bolong Huang

Chem. Sci., 2025, 16, 14019
DOI: 10.1039/D5SC03210E

Insights into the electronic structure of Fe penta-coordinated complexes. Spectroscopic examination and electrochemical analysis for the oxygen reduction and oxygen evolution reactions

César Zúñiga Loyola, Gabriel Abarca, Soledad Ureta-Zañartu, Carolina Aliaga, Jose H. Zagal, Moulay Tahar Sougrati, Frédéric Jaouen, Walter Orellana and Federico Tasca

J. Mater. Chem. A, 2021, 9, 23802
DOI: 10.1039/D1TA05991B

In search of the most active MN4 catalyst for the oxygen reduction reaction. The case of perfluorinated Fe phthalocyanine

Gabriel Abarca, Marco Viera, Carolina Aliaga, José F. Marco, Walter Orellana, José H. Zagal and Federico Tasca

J. Mater. Chem. A, 2019, 7, 24776
DOI: 10.1039/C9TA09125D

Two-dimensional MoS2/Fe-phthalocyanine hybrid nanostructures as excellent electrocatalysts for hydrogen evolution and oxygen reduction reactions

Ik Seon Kwon, In Hye Kwak, Ju Yeon Kim, Hafiz Ghulam Abbas, Tekalign Terfa Debela, Jaemin Seo, Min Kyung Cho, Jae-Pyoung Ahn, Jeunghee Park and Hong Seok Kang

Nanoscale, 2019, 11, 14266
DOI: 10.1039/C9NR04156G

Rare-metal-free high-performance water-activated paper battery: a disposable energy source for wearable sensing devices

Kosuke Ishibashi, Shimpei Ono, Jun Kamei, Koju Ito and Hiroshi Yabu

RSC Appl. Interfaces, 2024, 1, 435
DOI: 10.1039/D4LF00039K

Oxygen reduction reaction on a 68-atom-gold cluster supported on carbon nanotubes: theoretical and experimental analysis

César Zúñiga Loyola, Angélica Gatica Caro, Joseph Govan, Gabriel Abarca, Walter Orellana and Federico Tasca

Mater. Chem. Front., 2021, 5, 7529
DOI: 10.1039/D1QM00918D

Insights into the Electrocatalytic Activity of Fe,N-Glucose/Carbon Nanotube Hybrids for the Oxygen Reduction Reaction

Rafael G. Morais, Natalia Rey-Raap, José L. Figueiredo and Manuel F. R. Pereira

C, 2024, 10, 47
DOI: 10.3390/c10020047

Enhancing oxygen reduction reaction performance via CNTs/graphene supported iron protoporphyrin IX: A hybrid nanoarchitecture electrocatalyst

Anuj Kumar, Ghulam Yasin, Vinod Kumar Vashistha, Deepak K. Das, Majeed Ur Rehman, Rashid Iqbal, Zhousheng Mo, Tuan Anh Nguyen, Y. Slimani, M. Tariq Nazir and Wei Zhao

Diamond and Related Materials, 2021, 113, 108272
DOI: 10.1016/j.diamond.2021.108272

A comparative study of iron phthalocyanine electrocatalysts supported on different nanocarbons for oxygen reduction reaction

Jun Yang, Jie Tao, Takenori Isomura, Horuyuki Yanagi, Isamu Moriguchi and Naotoshi Nakashima

Carbon, 2019, 145, 565
DOI: 10.1016/j.carbon.2019.01.022

Fe phthalocyanine stabilized on phosphorous-doped multi-defective carbon nanoribbons as oxygen reduction electrocatalysts

Qi Huang, Shaojie Xu, Jie Liu, Yuanyuan Guo, Dandan Chen, Qiuhong Sun, Linjie Zhang, Huagui Nie, Zhi Yang and Jinjie Qian

Applied Catalysis B: Environmental, 2023, 339, 123172
DOI: 10.1016/j.apcatb.2023.123172

Redox chemistry of N4-Fe2+ in iron phthalocyanines for oxygen reduction reaction

Anuj Kumar, Ying Zhang, Yin Jia, Wen Liu and Xiaoming Sun

Chinese Journal of Catalysis, 2021, 42, 1404
DOI: 10.1016/S1872-2067(20)63731-7

Wrapping Multiwalled Carbon Nanotubes with Anatase Titanium Oxide for the Electrosynthesis of Glycolic Acid

Jun Yang, Junfang Cheng, Jie Tao, Manabu Higashi, Miho Yamauchi and Naotoshi Nakashima

ACS Appl. Nano Mater., 2019, 2, 6360
DOI: 10.1021/acsanm.9b01357

Preparation of FePcNs@GO composites and boosting oxygen reduction reaction

Tingting Yu, Qingsong Liu, Changfei Gao, Tao Yang, Bing Yang, Huilin Guo, Wenbin Chen, Yu Zhang and Biming Song

Res Chem Intermed, 2022, 48, 3375
DOI: 10.1007/s11164-022-04751-4

Molecular catalyst of Fe phthalocyanine loaded into In-based MOF-derived defective carbon nanoflowers for oxygen reduction

Yi Wu, Jie Liu, Qiuhong Sun, Junliang Chen, Xiangou Zhu, Reza Abazari and Jinjie Qian

Chemical Engineering Journal, 2024, 483, 149243
DOI: 10.1016/j.cej.2024.149243

DNA-Anchored Single-Molecule Iron Phthalocyanine As an Efficient Electrocatalyst for Alkaline Fuel Cells

Yi Qin, Cheng-Hao Chuang, Xiaojing Liu, Xian Liang, Linfeng Xie, Kuan Wang, Chih-Wen Pao, Ying-Rui Lu, Yang Liu, Yawei Chen, Zhanwu Lei, Pengfei Yan, Liang Wu, Shuhong Jiao, Qing Li and Ruiguo Cao

ACS Catal., 2024, 14, 7514
DOI: 10.1021/acscatal.4c00795

Carbon matrix driving Fe2+/3+ redox enhancement in iron phthalocyanine for highly efficient oxygen reduction in Zn-air battery

Qianhui Wu, Xiaodian Yan, Wubo Wan, Qingrong Chen, Zhongzhi Yao, Zhaoyun Wang, Jianin Guo, Zhijian Liao and Shengkui Zhong

Journal of Alloys and Compounds, 2025, 1035, 181498
DOI: 10.1016/j.jallcom.2025.181498

In-Situ Formed Micropores as Footholds Enabling Well-Dispersed High-Density Fe-Nx Active Sites for Oxygen Reduction Reaction

Jin Luo, Menghui Chen, Zhoufan Zhang, Kangjun Wang, Shiming Zhang and Shengli Chen

J. Phys. Chem. C, 2021, 125, 24988
DOI: 10.1021/acs.jpcc.1c08470

Iron-Based Electrocatalysts for Energy Conversion: Effect of Ball Milling on Oxygen Reduction Activity

Maida Aysla Costa de Oliveira, Pedro Pablo Machado Pico, Williane da Silva Freitas, Alessandra D’Epifanio and Barbara Mecheri

Applied Sciences, 2020, 10, 5278
DOI: 10.3390/app10155278

PtRu nanoparticles embedded in nitrogen doped carbon with highly stable CO tolerance and durability

Ying Ling, Zehui Yang, Jun Yang, Yunfeng Zhang, Quan Zhang, Xinxin Yu and Weiwei Cai

Nanotechnology, 2018, 29, 055402
DOI: 10.1088/1361-6528/aa9d20

Heightening polyoxometalate encapsulation efficiency for biaxial strain-induced catalytic activity boosting

Sheng Zhu, Yating Wu, Lingtong Ding, Xuehuan Zhang, Lan Li, Xiao Wang and Gaoyi Han

Energy Storage Materials, 2024, 73, 103777
DOI: 10.1016/j.ensm.2024.103777

Totally organic electrical skin patch powered by flexible biobattery

Shotaro Yoshida, Hiroya Abe, Yuina Abe, Shinya Kusama, Kenichi Tsukada, Ryo Komatsubara and Matsuhiko Nishizawa

J. Phys. Energy, 2020, 2, 044004
DOI: 10.1088/2515-7655/abb873

Heterostructure Design in Bimetallic Phthalocyanine Boosts Oxygen Reduction Reaction Activity and Durability

Yao Ma, Jiantao Li, Xiaobin Liao, Wen Luo, Wenzhong Huang, Jiashen Meng, Qiang Chen, Shibo Xi, Ruohan Yu, Yan Zhao, Liang Zhou and Liqiang Mai

Adv Funct Materials, 2020, 30
DOI: 10.1002/adfm.202005000

Carbons for fuel cell energy generation

Natalia Rey-Raap, Lucía dos Santos-Gómez and Ana Arenillas

Carbon, 2024, 228, 119291
DOI: 10.1016/j.carbon.2024.119291

Advances in the general design of high-performance metal phthalocyanine-based catalysts

Yunze Wang, Yuan Pan, Xiansheng Zhang, Shanqing Tang, Xinyi Huang, Teng Li, Ruilin Cao, Jin Zeng, Xiuyu Duan and Zhifeng Liu

Coordination Chemistry Reviews, 2026, 548, 217233
DOI: 10.1016/j.ccr.2025.217233

Oxygen-catalyzed Reduction Reaction at Nitrogen-doped Carbon Synthesized by Post-synthesis Method Using Single-walled Carbon Nanotubes as a Substrate Electrode

Masato TOMINAGA and Takuya TAKATORI

BUNSEKI KAGAKU, 2021, 70, 557
DOI: 10.2116/bunsekikagaku.70.557

Identification and Understanding of Active Sites of Non‐Noble Iron‐Nitrogen‐Carbon Catalysts for Oxygen Reduction Electrocatalysis

Zhili Yang, Yizhe Chen, Shiming Zhang and Jiujun Zhang

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202215185

Solvothermally Synthesized Iron Phthalocyanine Nanostructure for High ORR Response: A Joint Experimental Investigation and DFT Analysis

Biswanath Mukherjee

J. Electrochem. Soc., 2020, 167, 116501
DOI: 10.1149/1945-7111/ab9e3a

Cr2O3 nanoparticles composited with MWCNTs as an efficient electrocatalyst for the oxygen reduction reaction

N. Sadeghi, A. Khorshidi and M. Ganjali

Inorganic Chemistry Communications, 2021, 126, 108489
DOI: 10.1016/j.inoche.2021.108489

Designing an FeIII-Doped Nickel Sulfide/Carbon Nanotube Hybrid Catalyst for Alkaline Electrolyte Membrane Water Electrolyzers and Zn–Air Battery Performances

Pandian Ganesan, Aleksandar Staykov, Hiroaki Shu, Mitsugu Uejima and Naotoshi Nakashima

ACS Appl. Energy Mater., 2020, 3, 10961
DOI: 10.1021/acsaem.0c01931

Adsorption of free-base phthalocyanine on Stone-Wales defect-containing carbon nanotubes: A DFT study

Vladimir A. Basiuk and Eduardo Chávez-Colorado

Diamond and Related Materials, 2019, 97, 107443
DOI: 10.1016/j.diamond.2019.107443

Novel Fe3O4 nanoparticles encapsulated in and loaded on hollow carbon nanotubes wrapped dendritic carbon layers architecture for water decomposition

Kun Shi, Man Zheng, Jiaxian Liu, Fangxun Liu, Tong Zhang, Yuxin Zhao, Yuena Sun, Yufan Zhang and Huan Wang

International Journal of Hydrogen Energy, 2024, 51, 1303
DOI: 10.1016/j.ijhydene.2023.09.184

Understanding the influence of bending on OER activity in metal phthalocyanines: A first-principles study

Zhong-Peng Zhou, Ning-Jing Hao, Qian-Kui Zhang, Xiao-Hui Deng, Hui Zhang, Zhen-Kun Tang and Chuan-Jia Tong

Applied Surface Science, 2023, 618, 156582
DOI: 10.1016/j.apsusc.2023.156582

Hybridization of iron phthalocyanine and MoS2 for high-efficiency and durable oxygen reduction reaction

Haibing Meng, Xiaolong Liu, Xiao Chen, Ying Han, Chenhui Zhou, Qinyuan Jiang, Ting Tan and Rufan Zhang

Journal of Energy Chemistry, 2022, 71, 528
DOI: 10.1016/j.jechem.2022.04.031

Fe azaphthalocyanine unimolecular layers (Fe AzULs) on carbon nanotubes for realizing highly active oxygen reduction reaction (ORR) catalytic electrodes

Hiroya Abe, Yutaro Hirai, Susumu Ikeda, Yasutaka Matsuo, Haruyuki Matsuyama, Jun Nakamura, Tomokazu Matsue and Hiroshi Yabu

NPG Asia Mater, 2019, 11
DOI: 10.1038/s41427-019-0154-6

Pyrolysis-Free Oxygen Reduction Reaction (ORR) Electrocatalysts Composed of Unimolecular Layer Metal Azaphthalocyanines Adsorbed onto Carbon Materials

Hiroshi Yabu, Koki Nakamura, Yasutaka Matsuo, Yutaro Umejima, Haruyuki Matsuyama, Jun Nakamura and Koju Ito

ACS Appl. Energy Mater., 2021, 4, 14380
DOI: 10.1021/acsaem.1c03054

Carbon Nanotube‐Based Non‐Precious Metal Electrode Catalysts for Fuel Cells, Water Splitting and Zinc‐Air Batteries

Jun Yang, Pandian Ganesan, Akimitsu Ishihara and Naotoshi Nakashima

ChemCatChem, 2019, 11, 5929
DOI: 10.1002/cctc.201901785

Electroreduction of oxygen in alkaline solution on iron phthalocyanine modified carbide-derived carbons

Reio Praats, Ivar Kruusenberg, Maike Käärik, Urmas Joost, Jaan Aruväli, Päärn Paiste, Rando Saar, Protima Rauwel, Mati Kook, Jaan Leis, José H. Zagal and Kaido Tammeveski

Electrochimica Acta, 2019, 299, 999
DOI: 10.1016/j.electacta.2019.01.062

Binary Nitrogen Precursor-Derived Porous Fe-N-S/C Catalyst for Efficient Oxygen Reduction Reaction in a Zn-Air Battery

Xiao Liu, Chi Chen, Qingqing Cheng, Liangliang Zou, Zhiqing Zou and Hui Yang

Catalysts, 2018, 8, 158
DOI: 10.3390/catal8040158

Highly electroactive N–Fe hydrothermal carbons and carbon nanotubes for the oxygen reduction reaction

R.G. Morais, N. Rey-Raap, J.L. Figueiredo and M.F.R. Pereira

Journal of Energy Chemistry, 2020, 50, 260
DOI: 10.1016/j.jechem.2020.03.039

Platinum Group Metal-Free Catalysts for Oxygen Reduction Reaction: Applications in Microbial Fuel Cells

Maida Aysla Costa de Oliveira, Alessandra D’Epifanio, Hitoshi Ohnuki and Barbara Mecheri

Catalysts, 2020, 10, 475
DOI: 10.3390/catal10050475

Influence of cyano substituents on the electron density and catalytic activity towards the oxygen reduction reaction for iron phthalocyanine. The case for Fe(II) 2,3,9,10,16,17,23,24-octa(cyano)phthalocyanine

Joseph Govan, Gabriel Abarca, Carolina Aliaga, Byran Sanhueza, Walter Orellana, Gloria Cárdenas-Jirón, José H. Zagal and Federico Tasca

Electrochemistry Communications, 2020, 118, 106784
DOI: 10.1016/j.elecom.2020.106784

Electroreduction of oxygen on cobalt phthalocyanine-modified carbide-derived carbon/carbon nanotube composite catalysts

Reio Praats, Maike Käärik, Arvo Kikas, Vambola Kisand, Jaan Aruväli, Päärn Paiste, Maido Merisalu, Ave Sarapuu, Jaan Leis, Väino Sammelselg, John C. Douglin, Dario R. Dekel and Kaido Tammeveski

J Solid State Electrochem, 2021, 25, 57
DOI: 10.1007/s10008-020-04543-z

Simple Method to Enhance the Oxidation–Reduction Reaction Activity of a Carbon Nanotube-Based Nickel–Iron Layered Double Hydroxide as a Bifunctional Electrocatalyst

Jin Nishida, Eiichi Kobayashi, Takeharu Sugiyama, Atsunori Matsuda, Shoichi Toh, Pandian Ganesan and Naotoshi Nakashima

J. Phys. Chem. C, 2023, 127, 19325
DOI: 10.1021/acs.jpcc.3c02321

Boosting oxygen reduction reaction activity by incorporating the iron phthalocyanine nanoparticles on carbon nanotubes network

Anuj Kumar, Ghulam Yasin, Rashid Mustafa Korai, Y. Slimani, Muhammad Furqan Ali, Mohammad Tabish, M. Tariq Nazir and Tuan Anh Nguyen

Inorganic Chemistry Communications, 2020, 120, 108160
DOI: 10.1016/j.inoche.2020.108160

SYNTHESIS, CHARACTERIZATION AND ORR ACTIVITY OF METAL-N4-NANOCOMPOSITES

VIVEK SHARMA and ANUJ KUMAR

Surf. Rev. Lett., 2021, 28, 2150051
DOI: 10.1142/S0218625X21500517

Efficient nitrate and oxygen electroreduction over pyrolysis-free mesoporous covalent Co-salophen coordination frameworks on carbon nanotubes

Jiaxin Liu, Tingting Cheng, Linqi Jiang, Hengqiang Zhang, Yongkui Shan and Aiguo Kong

Electrochimica Acta, 2020, 363, 137280
DOI: 10.1016/j.electacta.2020.137280

Bioinspired Transition‐Metal Complexes as Electrocatalysts for the Oxygen Reduction Reaction

Ye‐Min Zhao, Guo‐Qiang Yu, Fei‐Fei Wang, Ping‐Jie Wei and Jin‐Gang Liu

Chemistry A European J, 2019, 25, 3726
DOI: 10.1002/chem.201803764

Noncovalent functionalization of pristine CVD single-walled carbon nanotubes with 3d metal(II) phthalocyanines by adsorption from the gas phase

Vladimir A. Basiuk, Laura J. Flores-Sánchez, Victor Meza-Laguna, José Ocotlán Flores-Flores, Lauro Bucio-Galindo, Iván Puente-Lee and Elena V. Basiuk

Applied Surface Science, 2018, 436, 1123
DOI: 10.1016/j.apsusc.2017.12.122

Electrocatalytic oxygen reduction reaction on iron phthalocyanine-modified carbide-derived carbon/carbon nanotube composite electrocatalysts

Reio Praats, Maike Käärik, Arvo Kikas, Vambola Kisand, Jaan Aruväli, Päärn Paiste, Maido Merisalu, Jaan Leis, Väino Sammelselg, José H. Zagal, Steven Holdcroft, Naotoshi Nakashima and Kaido Tammeveski

Electrochimica Acta, 2020, 334, 135575
DOI: 10.1016/j.electacta.2019.135575

Optimization of cobalt on CNT towards the oxygen evolution reaction and its synergy with iron (II) phthalocyanine as bifunctional oxygen electrocatalyst

R.G. Morais, N. Rey-Raap, J.L. Figueiredo and M.F.R. Pereira

Catalysis Today, 2023, 418, 114057
DOI: 10.1016/j.cattod.2023.114057

Noncovalent bonding of 3d metal(II) phthalocyanines with single-walled carbon nanotubes: A combined DFT and XPS study

Elena V. Basiuk, Lazaro Huerta and Vladimir A. Basiuk

Applied Surface Science, 2019, 470, 622
DOI: 10.1016/j.apsusc.2018.11.159

Iron(II) phthalocyanine (FePc) over carbon support for oxygen reduction reaction electrocatalysts operating in alkaline electrolyte

Maida Aysla Costa de Oliveira, Valerio C. A. Ficca, Rohan Gokhale, Carlo Santoro, Barbara Mecheri, Alessandra D’Epifanio, Silvia Licoccia and Plamen Atanassov

J Solid State Electrochem, 2021, 25, 93
DOI: 10.1007/s10008-020-04537-x

Substituent Effects in Iron Porphyrin Catalysts for the Hydrogen Evolution Reaction**

Nils Heppe, Charlotte Gallenkamp, Stephen Paul, Nicole Segura‐Salas, Niklas von Rhein, Bernhard Kaiser, Wolfram Jaegermann, Atefeh Jafari, Ilya Sergueev, Vera Krewald and Ulrike I. Kramm

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202465

Advances and Challenges in Interfacial Binding Forces for Electrocatalysts

Xing Yan, Fengxia An, Yuxiang Li, Junliang Xie, Heng Du, Zhonghao Yu, Fang Jiang and Huan Chen

ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202400750

Ammonia Defective Etching and Nitrogen-Doping of Porous Carbon toward High Exposure of Heme-Derived Fe–Nx Site for Efficient Oxygen Reduction

Jiaoxing Xu, Chuxin Wu, Qiangmin Yu, Yi Zhao, Xun Li and Lunhui Guan

ACS Sustainable Chem. Eng., 2018, 6, 551
DOI: 10.1021/acssuschemeng.7b02841

Research progress of Fe-N-C catalysts for the electrocatalytic oxygen reduction reaction

Ying Wang, Lei Wang and Honggang Fu

Sci. China Mater., 2022, 65, 1701
DOI: 10.1007/s40843-022-2059-x

The pH-dependent catalytic activity of the oxygen reduction reaction of iron hexadecafluorophthalocyanine

Zonghua Yu, Xiaoning Zhan, Yucheng Jin, Wenping Liu, Wenbo Liu, Rong Jiang, Dongdong Qi, Kang Wang and Jianzhuang Jiang

Sci. Sin.-Chim, 2022, 52, 1400
DOI: 10.1360/SSC-2021-0260