Vanadyl β-tetrabromoporphyrin: synthesis, crystal structure and its use as an efficient and selective catalyst for olefin epoxidation in aqueous medium

Tawseef Ahmad Dar, Reshu Tomar, Rasel Mohammad Mian, Muniappan Sankar and Mannar Ram Maurya

RSC Adv., 2019, 9, 10405
DOI: 10.1039/C8RA09825E

Dioxygen reactivity of iron(ii)–gentisate/1,4-dihydroxy-2-naphthoate complexes of N4 ligands: oxidative coupling of 1,4-dihydroxy-2-naphthoate

Rubina Rahaman, Sandip Munshi, Sridhar Banerjee, Biswarup Chakraborty, Sarmistha Bhunia and Tapan Kanti Paine

Dalton Trans., 2019, 48, 16993
DOI: 10.1039/C9DT03493E

Mononuclear iron complexes relevant to nonheme iron oxygenases. Synthesis, characterizations and reactivity of Fe-Oxo and Fe-Peroxo intermediates

Aurore Thibon, Jean-François Bartoli, Sophie Bourcier and Frédéric Banse

Dalton Trans., 2009, 9587
DOI: 10.1039/b913470k

Direct hydroxylation of benzene and aromatics with H2O2catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism

Giorgio Capocasa, Giorgio Olivo, Alessia Barbieri, Osvaldo Lanzalunga and Stefano Di Stefano

Catal. Sci. Technol., 2017, 7, 5677
DOI: 10.1039/C7CY01895A

Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies

Pieter C. A. Bruijnincx, Gerard van Koten and Robertus J. M. Klein Gebbink

Chem. Soc. Rev., 2008, 37, 2716
DOI: 10.1039/b707179p

Alcohol oxidation with H2O2 catalyzed by a cheap and promptly available imine based iron complex

Giorgio Olivo, Simone Giosia, Alessia Barbieri, Osvaldo Lanzalunga and Stefano Di Stefano

Org. Biomol. Chem., 2016, 14, 10630
DOI: 10.1039/C6OB01984F

New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(iii) complexes with dinucleating ligands

Mio Sekino, Hideki Furutachi, Kyosuke Tasaki, Takanao Ishikawa, Shigeki Mori, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Takashi Nomura, Takashi Ogura, Teizo Kitagawa and Masatatsu Suzuki

Dalton Trans., 2016, 45, 469
DOI: 10.1039/C5DT04088D

ortho-Hydroxylation of aromatic acids by a non-heme FeVO species: how important is the ligand design?

Azaj Ansari and Gopalan Rajaraman

Phys. Chem. Chem. Phys., 2014, 16, 14601
DOI: 10.1039/C3CP55430A

H2O2activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore

Olga V. Makhlynets, Williamson N. Oloo, Yurii S. Moroz, Irina G. Belaya, Taryn D. Palluccio, Alexander S. Filatov, Peter Müller, Matthew A. Cranswick, Lawrence Que and Elena V. Rybak-Akimova

Chem. Commun., 2014, 50, 645
DOI: 10.1039/C3CC47632D

Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

Ramona Turcas, Dóra Lakk-Bogáth, Gábor Speier and József Kaizer

Dalton Trans., 2018, 47, 3248
DOI: 10.1039/C7DT03727A

Biomimetic oxidation of aromatic xenobiotics: synthesis of the phenolic metabolites from the anti-HIV drug efavirenz

Riccardo Wanke, David A. Novais, Shrika G. Harjivan, M. Matilde Marques and Alexandra M. M. Antunes

Org. Biomol. Chem., 2012, 10, 4554
DOI: 10.1039/c2ob25212k

μ-Oxo-bridged diiron(iii) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation

Mani Balamurugan, Eringathodi Suresh and Mallayan Palaniandavar

RSC Adv., 2021, 11, 21514
DOI: 10.1039/D1RA03135J

Catalytic oxidation of cyclohexene by aqueous iron(III)/H2O2 in mildly acidic solution: Epoxidation versus allylic oxidation

Ben McAteer, Nicola Beattie and David T. Richens

Inorganic Chemistry Communications, 2013, 35, 284
DOI: 10.1016/j.inoche.2013.06.018

X-ray crystallographic structure and physical properties of the pentacoordinated [TPAFeCl]+ complex

Mihyang Kim, Yong-Ung Kim and Jaehong Han

Polyhedron, 2007, 26, 4003
DOI: 10.1016/j.poly.2007.04.041

Secondary Coordination Sphere Influence on the Reactivity of Nonheme Iron(II) Complexes: An Experimental and DFT Approach

Sumit Sahu, Leland R. Widger, Matthew G. Quesne, Sam P. de Visser, Hirotoshi Matsumura, Pierre Moënne-Loccoz, Maxime A. Siegler and David P. Goldberg

J. Am. Chem. Soc., 2013, 135, 10590
DOI: 10.1021/ja402688t

Iron Coordination Chemistry of N2Py2 Ligands Substituted by Carboxylic Moieties and Their Impact on Alkene Oxidation Catalysis

Frédéric Oddon, Elodie Girgenti, Colette Lebrun, Caroline Marchi‐Delapierre, Jacques Pécaut and Stéphane Ménage

Eur J Inorg Chem, 2012, 2012, 85
DOI: 10.1002/ejic.201100785

Direct Evaluation of the Reactivity of Nonheme Iron(V)–Oxo Intermediates toward Arenes

Oleg Y. Lyakin, Alexandra M. Zima, Nikolay V. Tkachenko, Konstantin P. Bryliakov and Evgenii P. Talsi

ACS Catal., 2018, 8, 5255
DOI: 10.1021/acscatal.8b00661

Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

Konstantin P. Bryliakov and Evgenii P. Talsi

Coordination Chemistry Reviews, 2014, 276, 73
DOI: 10.1016/j.ccr.2014.06.009

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

Oleg Y. Lyakin, Konstantin P. Bryliakov, George J. P. Britovsek and Evgenii P. Talsi

J. Am. Chem. Soc., 2009, 131, 10798
DOI: 10.1021/ja902659c

Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations

Sumit Sahu, Bo Zhang, Christopher J. Pollock, Maximilian Dürr, Casey G. Davies, Alex M. Confer, Ivana Ivanović-Burmazović, Maxime A. Siegler, Guy N. L. Jameson, Carsten Krebs and David P. Goldberg

J. Am. Chem. Soc., 2016, 138, 12791
DOI: 10.1021/jacs.6b03346

Iron‐Promoted ortho‐ and/or ipso‐Hydroxylation of Benzoic Acids with H2O2

Olga V. Makhlynets, Parthapratim Das, Sonia Taktak, Margaret Flook, Rubén Mas‐Ballesté, Elena V. Rybak‐Akimova and Lawrence Que

Chemistry A European J, 2009, 15, 13171
DOI: 10.1002/chem.200901296

Selective epoxidation of olefins by vanadylporphyrin [VIVO(TPP)] and electron deficient nonplanar β-octabromovanadylporphyrin [VIVO(TPPBr8)]

Mannar R. Maurya, Ved Prakash and Muniappan Sankar

J. Porphyrins Phthalocyanines, 2022, 26, 187
DOI: 10.1142/S108842462250002X

An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+

Kallol Ray, Jason England, Adam T. Fiedler, Marlène Martinho, Eckard Münck and Lawrence Que

Angewandte Chemie, 2008, 120, 8188
DOI: 10.1002/ange.200802219

Tailoring RuII Pyridine/Triazole Oxygenation Catalysts and Using Photoreactivity to Probe their Electronic Properties

Fritz Weisser, Hendrik Stevens, Johannes Klein, Margarethe van der Meer, Stephan Hohloch and Biprajit Sarkar

Chemistry A European J, 2015, 21, 8926
DOI: 10.1002/chem.201406441

A Mononuclear Peracetatoiron(III) Complex: Structural and Spectroscopic Characterization, and Oxidation Reactivity

Xi Zhang, Hideki Furutachi, Tomonori Tojo, Tomohiro Tsugawa, Shuhei Fujinami, Takeshi Sakurai and Masatatsu Suzuki

Chemistry Letters, 2011, 40, 515
DOI: 10.1246/cl.2011.515

Elusive Active Intermediates and Reaction Mechanisms of ortho-/ipso-Hydroxylation of Benzoic Acid by Hydrogen Peroxide Mediated by Bioinspired Iron(II) Catalysts

Zhimin Wu, Xuan Zhang, Lanping Gao, Dongru Sun, Yufen Zhao, Wonwoo Nam and Yong Wang

Inorg. Chem., 2023, 62, 14261
DOI: 10.1021/acs.inorgchem.3c01576

Direct Observation of a Nonheme Iron(IV)–Oxo Complex That Mediates Aromatic C–F Hydroxylation

Sumit Sahu, Matthew G. Quesne, Casey G. Davies, Maximilian Dürr, Ivana Ivanović-Burmazović, Maxime A. Siegler, Guy N. L. Jameson, Sam P. de Visser and David P. Goldberg

J. Am. Chem. Soc., 2014, 136, 13542
DOI: 10.1021/ja507346t

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

Aidan R. McDonald and Lawrence Que

Coordination Chemistry Reviews, 2013, 257, 414
DOI: 10.1016/j.ccr.2012.08.002

Biomimetic Hydrocarbon Oxidation Catalyzed by Nonheme Iron(III) Complexes with Peracids: Evidence for an FeVO Species

Sun Hwa Lee, Jung Hee Han, Han Kwak, Sung Jea Lee, Eun Yong Lee, Hee Jin Kim, Jung Hwan Lee, Cheolbeom Bae, Soo No Lee, Youngmee Kim and Cheal Kim

Chemistry A European J, 2007, 13, 9393
DOI: 10.1002/chem.200700513

EPR, 1H and 2H NMR, and Reactivity Studies of the Iron–Oxygen Intermediates in Bioinspired Catalyst Systems

Oleg Y. Lyakin, Konstantin P. Bryliakov and Evgenii P. Talsi

Inorg. Chem., 2011, 50, 5526
DOI: 10.1021/ic200088e

EPR detection of Fe(V)=O active species in nonheme iron-catalyzed oxidations

Oleg Y. Lyakin, Irene Prat, Konstantin P. Bryliakov, Miquel Costas and Evgenii P. Talsi

Catalysis Communications, 2012, 29, 105
DOI: 10.1016/j.catcom.2012.09.029

Oxo complexes of high-valence iron in oxidation catalysis

O. Y. Lyakin and A. A. Shteinman

Kinet Catal, 2012, 53, 694
DOI: 10.1134/S0023158412050084

Non-Noble Metal Aromatic Oxidation Catalysis: From Metalloenzymes to Synthetic Complexes

Eduard Masferrer-Rius and Robertus J. M. Klein Gebbink

Catalysts, 2023, 13, 773
DOI: 10.3390/catal13040773

Catalytic Electrophilic Halogenations and Haloalkoxylations by Non‐Heme Iron Halides

Sujoy Rana, Sukdev Bag, Tuhin Patra and Debabrata Maiti

Adv Synth Catal, 2014, 356, 2453
DOI: 10.1002/adsc.201400316

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

Jihae Yoon, Samuel A. Wilson, Yu Kyeong Jang, Mi Sook Seo, Kasi Nehru, Britt Hedman, Keith O. Hodgson, Eckhard Bill, Edward I. Solomon and Wonwoo Nam

Angew Chem Int Ed, 2009, 48, 1257
DOI: 10.1002/anie.200802672

On the nature of the active intermediates in iron-catalyzed oxidation of cycloalkanes with hydrogen peroxide and peracids

Alexandra M. Zima, Oleg Y. Lyakin, Konstantin P. Bryliakov and Evgenii P. Talsi

Molecular Catalysis, 2018, 455, 6
DOI: 10.1016/j.mcat.2018.05.024

Iron-oxidation-state-dependent O–O bond cleavage of meta-chloroperbenzoic acid to form an iron(IV)-oxo complex

Kallol Ray, Sang Mok Lee and Lawrence Que

Inorganica Chimica Acta, 2008, 361, 1066
DOI: 10.1016/j.ica.2007.07.039

Mn(II) Polypyridyl Complexes: Precursors to High Valent Mn(V)=O Species and Inhibitors of Cancer Cell Proliferation

Pragya Arora, Sikha Gupta, Sai Kumari Vechalapu, Rakesh Kumar, Ayushi Awasthi, Sathyapriya Senthil, Shweta Khanna, Dharmaraja Allimuthu and Apparao Draksharapu

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301506

Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes

Diego A. Alonso, Carmen Nájera, Isidro M. Pastor and Miguel Yus

Chemistry A European J, 2010, 16, 5274
DOI: 10.1002/chem.201000470

Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes

Eduard Masferrer‐Rius, Margarida Borrell, Martin Lutz, Miquel Costas and Robertus J. M. Klein Gebbink

Adv Synth Catal, 2021, 363, 3783
DOI: 10.1002/adsc.202001590

Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations

Williamson N. Oloo, Katlyn K. Meier, Yong Wang, Sason Shaik, Eckard Münck and Lawrence Que

Nat Commun, 2014, 5
DOI: 10.1038/ncomms4046

Synthesis and Structural Characterization of Iron(II) Complexes with Tris(imidazolyl)phosphane Ligands: A Platform for Modeling the 3‐Histidine Facial Triad of Nonheme Iron Dioxygenases

Michael M. Bittner, Jacob S. Baus, Sergey V. Lindeman and Adam T. Fiedler

Eur J Inorg Chem, 2012, 2012, 1848
DOI: 10.1002/ejic.201101282

Iron Catalyzed Competitive Olefin Oxidation and ipso-Hydroxylation of Benzoic Acids: Further Evidence for an FeV═O Oxidant

Parthapratim Das and Lawrence Que

Inorg. Chem., 2010, 49, 9479
DOI: 10.1021/ic101144s

Origins of Catalyst Inhibition in the Manganese‐Catalysed Oxidation of Lignin Model Compounds with H2O2

Alessia Barbieri, Johann B. Kasper, Francesco Mecozzi, Osvaldo Lanzalunga and Wesley R. Browne

ChemSusChem, 2019, 12, 3126
DOI: 10.1002/cssc.201900689

An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+

Kallol Ray, Jason England, Adam T. Fiedler, Marlène Martinho, Eckard Münck and Lawrence Que

Angew Chem Int Ed, 2008, 47, 8068
DOI: 10.1002/anie.200802219

Selectivity of C−H versus C−F Bond Oxygenation by Homo‐ and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters

Graham de Ruiter, Kurtis M. Carsch, Michael K. Takase and Theodor Agapie

Chemistry A European J, 2017, 23, 10744
DOI: 10.1002/chem.201702302

Ruthenium(II)-Catalyzed Synthesis of Hydroxylated Arenes with Ester as an Effective Directing Group

Yiqing Yang, Yun Lin and Yu Rao

Org. Lett., 2012, 14, 2874
DOI: 10.1021/ol301104n

Highly Efficient Aromatic C−H Oxidation with H2O2 in the Presence of Iron Complexes of the PDP Family

Nikolay V. Tkachenko, Roman V. Ottenbacher, Oleg Y. Lyakin, Alexandra M. Zima, Denis G. Samsonenko, Evgenii P. Talsi and Konstantin P. Bryliakov

ChemCatChem, 2018, 10, 4052
DOI: 10.1002/cctc.201800832

Alkane oxidation reactivity of homogeneous and heterogeneous metal complex catalysts with mesoporous silica-immobilized (2-pyridylmethyl)amine type ligands

Jun Nakazawa, Yuma Doi and Shiro Hikichi

Molecular Catalysis, 2017, 443, 14
DOI: 10.1016/j.mcat.2017.09.027

A Transient, Highly Reactive Fe(IV)═O Species Revealed Through the Interference by O2 in the Activation of Organic Peracids by [(N4Py)Fe(II)]2+

Marika Di Berto Mancini, C. Maurits de Roo, Andy S. Sardjan, Ronald Hage, Giorgio Olivo, Osvaldo Lanzalunga, Marcel Swart and Wesley R. Browne

ACS Catal., 2025, 15, 7482
DOI: 10.1021/acscatal.5c00706

Low temperature reaction of [Fe(TPA)(CH3CN)2]2+ with excess 3-chloroperoxybenzoic acid in semi-frozen acetonitrile; EPR detection of an acylperoxo iron(III) adduct

Gregorio Guisado-Barrios, Yiteng Zhang, Andrew M. Harkins and David T. Richens

Inorganic Chemistry Communications, 2012, 20, 81
DOI: 10.1016/j.inoche.2012.02.022

Aromatic Hydroxylation at a Non‐Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

Olga V. Makhlynets and Elena V. Rybak‐Akimova

Chemistry A European J, 2010, 16, 13995
DOI: 10.1002/chem.201002577

Kinetic Studies on the Oxoiron(IV) Complex with Tetradentate Aminopyridine Ligand PDP*: Restoration of Catalytic Activity by Reduction with H2O2

Marc C. Piquette, Sergiy V. Kryatov and Elena V. Rybak-Akimova

Inorg. Chem., 2019, 58, 13382
DOI: 10.1021/acs.inorgchem.9b02269

Copper(II)‐Mediated Aromatic ortho‐Hydroxylation: A Hybrid DFT and Ab Initio Exploration

Peter Comba, Stefan Knoppe, Bodo Martin, Gopalan Rajaraman, Claudio Rolli, Brett Shapiro and Timon Stork

Chemistry A European J, 2008, 14, 344
DOI: 10.1002/chem.200700865

Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins

Yumi Suh, Mi Sook Seo, Kwan Mook Kim, Youn Sang Kim, Ho G. Jang, Takehiko Tosha, Teizo Kitagawa, Jinheung Kim and Wonwoo Nam

Journal of Inorganic Biochemistry, 2006, 100, 627
DOI: 10.1016/j.jinorgbio.2005.12.013

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

Jihae Yoon, Samuel A. Wilson, Yu Kyeong Jang, Mi Sook Seo, Kasi Nehru, Britt Hedman, Keith O. Hodgson, Eckhard Bill, Edward I. Solomon and Wonwoo Nam

Angewandte Chemie, 2009, 121, 1283
DOI: 10.1002/ange.200802672

Iron-Catalyzed Olefin Epoxidation in the Presence of Acetic Acid: Insights into the Nature of the Metal-Based Oxidant

Rubén Mas-Ballesté and Lawrence Que

J. Am. Chem. Soc., 2007, 129, 15964
DOI: 10.1021/ja075115i