Issue 31, 2018

Coordination polymers built up from an s-tetrazine derived ligand and rare-earth ions: from a sequential dimensional expansion to organic–inorganic energy transfer

Abstract

Coordination polymers were prepared from a luminescent s-tetrazine ligand (OTz) and various rare-earth ions. Both the radii of the Ln ions and the synthetic conditions (especially pH) drive the formation of the product, and three crystalline phases were finally identified. Using a two-step process, it was possible to increase the dimensionality of one of these compounds from 1-D (MIL-165) to 2-D (MIL-166). The luminescence properties of these coordination polymers were studied. Whereas for Ln = La, Pr, Eu, Tb, the emission characteristic of the s-tetrazine core was observed, such emission was not detected for Ln = Nd, while the emission typical for the Nd ion was present, due to energy transfer from the tetrazine ligand to the Nd3+ ion.

Graphical abstract: Coordination polymers built up from an s-tetrazine derived ligand and rare-earth ions: from a sequential dimensional expansion to organic–inorganic energy transfer

Supplementary files

Article information

Article type
Paper
Submitted
31 mar 2018
Accepted
05 jun 2018
First published
21 jun 2018

Dalton Trans., 2018,47, 10715-10720

Coordination polymers built up from an s-tetrazine derived ligand and rare-earth ions: from a sequential dimensional expansion to organic–inorganic energy transfer

P. Rouschmeyer, N. Guillou, C. Serre, G. Clavier, C. Allain and T. Devic, Dalton Trans., 2018, 47, 10715 DOI: 10.1039/C8DT01268G

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