Issue 22, 2014

Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand

Abstract

The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) varies from 259 K when X = BPh4 to 277 K when X = Br, at 10 mM concentrations in an acetone–water solvent mixture.

Graphical abstract: Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand

Supplementary files

Article information

Article type
Communication
Submitted
09 jan 2014
Accepted
11 feb 2014
First published
12 feb 2014

RSC Adv., 2014,4, 11240-11243

Anion-dependent spin crossover in solution for an iron(II) complex of a 1H-pyrazolyl ligand

S. A. Barrett and M. A. Halcrow, RSC Adv., 2014, 4, 11240 DOI: 10.1039/C4RA00230J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements