Issue 79, 2013
From the journal:

Chemical Communications

Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control†

Atanu Jana,a   Masatoshi Ishida,ab   Kevin Cho,a   Sudip Kumar Ghosh,a   Kyuju Kwak,a   Kei Ohkubo,c   Young Mo Sung,a   Christina M. Davis,d   Vincent M. Lynch,d   Dongil Lee,*a   Shunichi Fukuzumi,*ce   Dongho Kim*a  and  Jonathan L. Sessler*ad  

* Corresponding authors

a Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr, dongil@yonsei.ac.kr

b Education Center for Global Leaders in Molecular Systems for Devices, Kyushu University, Fukuoka 819-0395, Japan

c Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp

d Department of Chemistry and Biochemistry, The University of Texas at Austin, Texas 78712-0156, USA
E-mail: sessler@cm.utexas.edu

e Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea

Abstract

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

Graphical abstract: Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

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Article information

DOI
https://doi.org/10.1039/C3CC44934C
Article type
Communication
Submitted
02 Jul 2013
Accepted
13 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 8937-8939

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Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

A. Jana, M. Ishida, K. Cho, S. K. Ghosh, K. Kwak, K. Ohkubo, Y. M. Sung, C. M. Davis, V. M. Lynch, D. Lee, S. Fukuzumi, D. Kim and J. L. Sessler, Chem. Commun., 2013, 49, 8937 DOI: 10.1039/C3CC44934C

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