Issue 29, 2013

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

Abstract

An efficient metal free protocol has been developed for the synthesis of benzylic esters via a cross dehydrogenative coupling (CDC) involving alkylbenzene(s) as a self- or as a cross-coupling partner(s) via the intermediacy of Ar–COOH and the benzylic carbocation obtained from the other half of the alkylbenzene; both symmetrical as well as unsymmetrical esters can be prepared using Bu4NI and TBHP.

Graphical abstract: Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

Supplementary files

Article information

Article type
Communication
Submitted
31 jan 2013
Accepted
25 feb 2013
First published
25 feb 2013

Chem. Commun., 2013,49, 3031-3033

Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

G. Majji, S. Guin, A. Gogoi, S. K. Rout and B. K. Patel, Chem. Commun., 2013, 49, 3031 DOI: 10.1039/C3CC40832A

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