Issue 21, 2024

Catalytic asymmetric carbenoid α-C–H insertion of ether

Abstract

Significant advancements have been made in catalytic asymmetric α-C–H bond functionalization of ethers via carbenoid insertion over the past decade. Effective asymmetric catalytic systems, featuring a range of chiral metal catalysts, have been established for the enantioselective synthesis of diverse ether substrates. This has led to the generation of various enantioenriched, highly functionalized oxygen-containing structural motifs, facilitating their application in the asymmetric synthesis of bioactive natural products.

Graphical abstract: Catalytic asymmetric carbenoid α-C–H insertion of ether

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Article information

Article type
Review Article
Submitted
22 mar 2024
Accepted
02 mai 2024
First published
13 mai 2024
This article is Open Access
Creative Commons BY license

RSC Adv., 2024,14, 15167-15177

Catalytic asymmetric carbenoid α-C–H insertion of ether

X. Li, S. Yue, Z. Tan, S. Liu, D. Luo, Y. Zhou and X. Liang, RSC Adv., 2024, 14, 15167 DOI: 10.1039/D4RA02206H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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